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Journal of Materials Science
Published in: Journal of Materials Science 20/2022

18-05-2022 | Ceramics

Performance of high temperature phase-stable high entropy oxide (MgCuMnCoFe)Ox in catalytic wet air oxidation of chloroquine phosphate

Authors: Yuzhi Liu, Donglei Zou, Yu Gao

Published in: Journal of Materials Science | Issue 20/2022

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Abstract

With the continuous spread of COVID-19, the water pollution problems caused by the abuse of chloroquine phosphate (CQP) as an antiviral drug have attracted wide attention. The cubic Fm-3m spinel high entropy oxide (HEO)—(MgCuMnCoFe)Ox was prepared by coprecipitation method as the catalytic wet air oxidation (CWAO) catalyst to treat CQP simulated wastewater. Through electron spin resonance (ESR) analysis, HEO will stimulate the production of superoxide radical (·O2−) and hydroxyl radical (·OH) in the wet air oxidation (WAO) process, which accelerates the degradation and mineralization of CQP. Through response surface method (RSM) optimization, the optimal degradation conditions of CQP in CWAO were proposed: initial oxygen pressure of 15 bar, catalyst dosage of 1.4 g/L and temperature of 230 °C. The advantages of HEO in CWAO were analyzed by principal component analysis (PCA). The degradation mechanism of CQP in CWAO by (MgCuMnCoFe)Ox were explored. This work provides a new idea for the rapid development of HEO in the field of environmental catalysis.
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Appendix
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Metadata
Title
Performance of high temperature phase-stable high entropy oxide (MgCuMnCoFe)Ox in catalytic wet air oxidation of chloroquine phosphate
Authors
Yuzhi Liu
Donglei Zou
Yu Gao
Publication date
18-05-2022
Publisher
Springer US
Published in
Journal of Materials Science / Issue 20/2022
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-022-07271-z

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