Skip to main content
Top
Published in: Colloid and Polymer Science 3/2015

01-03-2015 | Original Contribution

Photoluminescent hybrid materials of lanthanide (Eu3+, Sm3+) polyoxometalates and polymer resin through ionic liquid linker

Authors: Ying Mei, Bing Yan

Published in: Colloid and Polymer Science | Issue 3/2015

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

We achieve luminescent soft hybrid materials with lanthanide polyoxometalates and polymer resin (Merrifield resin (MR) or Wang resin (WR)) through ionic liquid compound (3-(2-(2-mercaptoacetoxy)ethyl)-1-methyl-1H-imidazol-3-ium bromide (SHIL)) as chemical linker, which are designated as LnW10-SHIL-MR(WR) (Ln = Eu, Sm). The photoluminescent properties of these hybrids are characterized, and it is found that they present excitation both in the ultraviolet and visible regions. Under the excitation at the visible region, the yellow-orange emission is obtained for the LnW10 unit. Subsequently, the white luminescence for the excitation at the visible region can be observed. This provides the useful data to prepare the white luminescent soft hybrids of polymer and lanthanide polyoxometalates through an ionic liquid linker.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Appendix
Available only for authorised users
Literature
1.
go back to reference Miao WS, Chan TH (2006) Ionic-liquid-supported synthesis: a novel liquid-phase strategy for organic synthesis. Acc Chem Res 39:897–908CrossRef Miao WS, Chan TH (2006) Ionic-liquid-supported synthesis: a novel liquid-phase strategy for organic synthesis. Acc Chem Res 39:897–908CrossRef
2.
go back to reference Olivier-Bourbigou H, Magna L (2002) Ionic liquids: perspectives for organic and catalytic reactions. J Mol Catal A-Chem 182:419–437CrossRef Olivier-Bourbigou H, Magna L (2002) Ionic liquids: perspectives for organic and catalytic reactions. J Mol Catal A-Chem 182:419–437CrossRef
3.
go back to reference Plechkova NV, Seddon KR (2008) Applications of ionic liquids in the chemical industry. Chem Soc Rev 37:123–150CrossRef Plechkova NV, Seddon KR (2008) Applications of ionic liquids in the chemical industry. Chem Soc Rev 37:123–150CrossRef
4.
go back to reference Mallick B, Balke B, Felser C, Mudring AV (2008) Dysprosium room-temperature ionic liquids with strong luminescence and response to magnetic fields. Angew Chem Int Edit 47:7635–7638CrossRef Mallick B, Balke B, Felser C, Mudring AV (2008) Dysprosium room-temperature ionic liquids with strong luminescence and response to magnetic fields. Angew Chem Int Edit 47:7635–7638CrossRef
5.
go back to reference Nakashima T, Nonoguchi Y, Kawai T (2008) Ionic liquid-based luminescent composite materials. Polym Adv Technol 19:1401–1405CrossRef Nakashima T, Nonoguchi Y, Kawai T (2008) Ionic liquid-based luminescent composite materials. Polym Adv Technol 19:1401–1405CrossRef
6.
go back to reference Li M, Pham PJ, Pittman CU, Li TY (2009) SBA-15-supported ionic liquid compounds containing silver salts: novel mesoporous π-complexing sorbents for separating polyunsaturated fatty acid methyl esters. Microp Mesop Mater 117:436–443CrossRef Li M, Pham PJ, Pittman CU, Li TY (2009) SBA-15-supported ionic liquid compounds containing silver salts: novel mesoporous π-complexing sorbents for separating polyunsaturated fatty acid methyl esters. Microp Mesop Mater 117:436–443CrossRef
7.
go back to reference Huddleston JG, Willauer HD, Swatloski RP, Visser AE, Rogers RD (1998) Room temperature ionic liquids as novel media for ‘clean’ liquid-liquid extraction. Chem Commun 1765–1766 Huddleston JG, Willauer HD, Swatloski RP, Visser AE, Rogers RD (1998) Room temperature ionic liquids as novel media for ‘clean’ liquid-liquid extraction. Chem Commun 1765–1766
8.
go back to reference Firestone MA, Rickert PG, Seifert S, Dietz ML (2004) Anion effects on ionogel formation in N N’-dialkylimidazolium-based ionic liquids. Inorg Chim Acta 357:3991–3998CrossRef Firestone MA, Rickert PG, Seifert S, Dietz ML (2004) Anion effects on ionogel formation in N N’-dialkylimidazolium-based ionic liquids. Inorg Chim Acta 357:3991–3998CrossRef
9.
go back to reference Hallett JP, Welton T (2011) Room-temperature ionic liquids: solvents for synthesis and catalysis. Chem Rev 111:3508–3576CrossRef Hallett JP, Welton T (2011) Room-temperature ionic liquids: solvents for synthesis and catalysis. Chem Rev 111:3508–3576CrossRef
10.
go back to reference Tang SF, Mudring AV (2009) Terbium β-diketonate based highly luminescent soft materials. Eur J Inorg Chem 2769–2775 Tang SF, Mudring AV (2009) Terbium β-diketonate based highly luminescent soft materials. Eur J Inorg Chem 2769–2775
11.
go back to reference Lunstroot K, Driesen K, Nockemann P, Viau L, Mutin PH, Vioux A, Binnemans K (2010) Ionic liquid as plasticizer for europium(III)-doped luminescent poly(methyl methacrylate) films. Phys Chem Chem Phys 12:1879–1885CrossRef Lunstroot K, Driesen K, Nockemann P, Viau L, Mutin PH, Vioux A, Binnemans K (2010) Ionic liquid as plasticizer for europium(III)-doped luminescent poly(methyl methacrylate) films. Phys Chem Chem Phys 12:1879–1885CrossRef
12.
go back to reference Lunstroot K, Driesen K, Nockemann P, Van Hecke K, Van Meervelt L, Gorller-Walrand C, Binnemans K, Bellayer S, Viau L, Le Bideau J, Vioux A (2009) Lanthanide-doped luminescent ionogels. Dalton Trans 298–306 Lunstroot K, Driesen K, Nockemann P, Van Hecke K, Van Meervelt L, Gorller-Walrand C, Binnemans K, Bellayer S, Viau L, Le Bideau J, Vioux A (2009) Lanthanide-doped luminescent ionogels. Dalton Trans 298–306
13.
go back to reference Bruno SM, Ferreira RAS, Paz FAA, Carlos LD, Pillinger M, Ribeiro-Claro P, Goncalves IS (2009) Structural and photoluminescence studies of a europium(III) tetrakis (beta-diketonate) complex with tetrabutylammonium, imidazolium, pyridinium and silica-supported imidazolium counterions. Inorg Chem 4882–4895 Bruno SM, Ferreira RAS, Paz FAA, Carlos LD, Pillinger M, Ribeiro-Claro P, Goncalves IS (2009) Structural and photoluminescence studies of a europium(III) tetrakis (beta-diketonate) complex with tetrabutylammonium, imidazolium, pyridinium and silica-supported imidazolium counterions. Inorg Chem 4882–4895
14.
go back to reference Liu YH, Sun XQ, Luo F, Chen J (2007) The preparation of sol–gel materials doped with ionic liquids and trialkyl phosphine oxides for yttrium (III) uptake. Anal Chim Acta 604:107–113CrossRef Liu YH, Sun XQ, Luo F, Chen J (2007) The preparation of sol–gel materials doped with ionic liquids and trialkyl phosphine oxides for yttrium (III) uptake. Anal Chim Acta 604:107–113CrossRef
15.
go back to reference Neouze MA, Le Bideau J, Leroux F, Vioux A (2005) A route to heat resistant solid membranes with performances of liquid electrolytes. Chem Commun 1082–1084 Neouze MA, Le Bideau J, Leroux F, Vioux A (2005) A route to heat resistant solid membranes with performances of liquid electrolytes. Chem Commun 1082–1084
16.
go back to reference Neouze MA, Le Bideau J, Gaveau P, Bellayer S, Vioux A (2006) Ionogels, new materials arising from the confinement of ionic liquids within silica-derived networks. Chem Mater 18:3931–3936CrossRef Neouze MA, Le Bideau J, Gaveau P, Bellayer S, Vioux A (2006) Ionogels, new materials arising from the confinement of ionic liquids within silica-derived networks. Chem Mater 18:3931–3936CrossRef
17.
go back to reference Kimizuka N, Nakashima T (2001) Spontaneous self-assembly of glycolipid bilayer membranes in sugar-philic ionic liquids and formation of ionogels. Langmuir 17:6759–6561CrossRef Kimizuka N, Nakashima T (2001) Spontaneous self-assembly of glycolipid bilayer membranes in sugar-philic ionic liquids and formation of ionogels. Langmuir 17:6759–6561CrossRef
18.
go back to reference Nockemann P, Beurer E, Driesen K, Van Deun R, Van Hecke K, Van Meervelt L, Binnemans K (2005) Photostability of a highly luminescent europium β-diketonate complex in imidazolium ionic liquids. Chem Commun 4354–4356 Nockemann P, Beurer E, Driesen K, Van Deun R, Van Hecke K, Van Meervelt L, Binnemans K (2005) Photostability of a highly luminescent europium β-diketonate complex in imidazolium ionic liquids. Chem Commun 4354–4356
19.
go back to reference Lunstroot K, Driesen K, Nockemann P, Gorller-Walrand C, Binnemans K, Bellayer S, Le Bideau J, Vioux A (2006) Luminescent ionogels based on europium-doped ionic liquids confined within silica-derived networks. Chem Mater 18:5711–5715CrossRef Lunstroot K, Driesen K, Nockemann P, Gorller-Walrand C, Binnemans K, Bellayer S, Le Bideau J, Vioux A (2006) Luminescent ionogels based on europium-doped ionic liquids confined within silica-derived networks. Chem Mater 18:5711–5715CrossRef
20.
go back to reference Maggini L, Traboulsi H, Yoosaf K, Mohanraj J, Wouters J, Pietraszkiewicz O, Pietraszkiewicz M, Armaroli N, Bonifazi D (2011) Electrostatically-driven assembly of MWCNTs with a europium complex. Chem Commun 47:1625–1627CrossRef Maggini L, Traboulsi H, Yoosaf K, Mohanraj J, Wouters J, Pietraszkiewicz O, Pietraszkiewicz M, Armaroli N, Bonifazi D (2011) Electrostatically-driven assembly of MWCNTs with a europium complex. Chem Commun 47:1625–1627CrossRef
21.
22.
go back to reference Neouze MA (2010) About the interactions between nanoparticles and imidazolium moieties: emergence of original hybrid materials. J Mater Chem 20:9593–9607CrossRef Neouze MA (2010) About the interactions between nanoparticles and imidazolium moieties: emergence of original hybrid materials. J Mater Chem 20:9593–9607CrossRef
23.
go back to reference Li HR, Shao HF, Wang YG, Qin DS, Liu BY, Zhang WJ, Yan WD (2009) Soft material with intense photoluminescence obtained by dissolving Eu2O3 and organic ligand into a task-specific ionic liquid. Chem Commun 5209–5211 Li HR, Shao HF, Wang YG, Qin DS, Liu BY, Zhang WJ, Yan WD (2009) Soft material with intense photoluminescence obtained by dissolving Eu2O3 and organic ligand into a task-specific ionic liquid. Chem Commun 5209–5211
24.
go back to reference Litschauer M, Puchberger M, Peterlik H, Neouze MA (2010) Anion metathesis in ionic silica nanoparticle networks. J Mater Chem 20:1269–1276CrossRef Litschauer M, Puchberger M, Peterlik H, Neouze MA (2010) Anion metathesis in ionic silica nanoparticle networks. J Mater Chem 20:1269–1276CrossRef
25.
go back to reference Getsis A, Tang SF, Mudring AV (2010) A luminescent ionic liquid crystal: [C12mim]4[EuBr6]Br. Eur J Inorg Chem 2172–2177 Getsis A, Tang SF, Mudring AV (2010) A luminescent ionic liquid crystal: [C12mim]4[EuBr6]Br. Eur J Inorg Chem 2172–2177
26.
go back to reference Yamase T., H. Naruke (1991) X-Ray structural and photoluminescence spectroscopic investigation of the europium octamolybdate polymer Eu2(H2O)12[Mo8O27] · 6H2O and intramolecular energy transfer in the crystalline lattice. J. Chem. Soc., Dalton Trans. 285–292. Yamase T., H. Naruke (1991) X-Ray structural and photoluminescence spectroscopic investigation of the europium octamolybdate polymer Eu2(H2O)12[Mo8O27] · 6H2O and intramolecular energy transfer in the crystalline lattice. J. Chem. Soc., Dalton Trans. 285–292.
27.
go back to reference Ballardini R, Mulazzani QG (1984) Photophysical characterization of the decatungstoeuropate(9-) anion. Inorg Chem 23:300–305CrossRef Ballardini R, Mulazzani QG (1984) Photophysical characterization of the decatungstoeuropate(9-) anion. Inorg Chem 23:300–305CrossRef
28.
go back to reference Ito T, Yamase T (2006) Molecular luminescence spectroscopy of decatungstoeuropate Langmuir–Blodgett monolayers. J Alloys Compds 408–412:813–815CrossRef Ito T, Yamase T (2006) Molecular luminescence spectroscopy of decatungstoeuropate Langmuir–Blodgett monolayers. J Alloys Compds 408–412:813–815CrossRef
29.
go back to reference Eliseeva SV, Bunzli JCG (2010) Lanthanide luminescence for functional materials and bio-sciences. Chem Soc Rev 39:89–227CrossRef Eliseeva SV, Bunzli JCG (2010) Lanthanide luminescence for functional materials and bio-sciences. Chem Soc Rev 39:89–227CrossRef
30.
go back to reference Cuan J, Yan B (2013) Multi-component assembly and photophysical property of europium polyoxometalates and polymer functionalized (mesoporous) silica through double functional ionic liquid linker. Dalton Trans 42:14230–14239CrossRef Cuan J, Yan B (2013) Multi-component assembly and photophysical property of europium polyoxometalates and polymer functionalized (mesoporous) silica through double functional ionic liquid linker. Dalton Trans 42:14230–14239CrossRef
31.
go back to reference Cuan J, Yan B (2013) Cool-white light emitting hybrid materials of resin-mesoporous silica composite matrix encapsulating europium polyoxometalates through ionic liquid linker. RSC Adv 3:20077–20084CrossRef Cuan J, Yan B (2013) Cool-white light emitting hybrid materials of resin-mesoporous silica composite matrix encapsulating europium polyoxometalates through ionic liquid linker. RSC Adv 3:20077–20084CrossRef
32.
go back to reference Cuan J, Yan B (2014) Photofunctional hybrid materials with polyoxometalates and benzoate modified mesoporous silica through double functional imidazolium ionic liquid linkage. Microp Mesop Mater 183:9–16CrossRef Cuan J, Yan B (2014) Photofunctional hybrid materials with polyoxometalates and benzoate modified mesoporous silica through double functional imidazolium ionic liquid linkage. Microp Mesop Mater 183:9–16CrossRef
33.
go back to reference Cuan J, Yan B (2014) Luminescent lanthanide-polyoxometalates assembling zirconia/alumina/titania hybrid xerogels through task-specified ionic liquid linkage. RSC Adv 4:1735–1743CrossRef Cuan J, Yan B (2014) Luminescent lanthanide-polyoxometalates assembling zirconia/alumina/titania hybrid xerogels through task-specified ionic liquid linkage. RSC Adv 4:1735–1743CrossRef
34.
go back to reference Yan B, Shao YF (2014) Multicomponent hybrids with surfactant-encapsulated europium polyoxometalate covalently bonded ZnO and tunable luminescence. RSC Adv 4:3318–3325CrossRef Yan B, Shao YF (2014) Multicomponent hybrids with surfactant-encapsulated europium polyoxometalate covalently bonded ZnO and tunable luminescence. RSC Adv 4:3318–3325CrossRef
35.
go back to reference Li QP, Yan B (2012) Luminescent hybrid materials of lanthanide β-diketonate and mesoporous host through the covalent and ion bonding with anion metathesis. Dalton Trans 41:8567–8573CrossRef Li QP, Yan B (2012) Luminescent hybrid materials of lanthanide β-diketonate and mesoporous host through the covalent and ion bonding with anion metathesis. Dalton Trans 41:8567–8573CrossRef
36.
go back to reference Li QP, Yan B (2012) Luminescent GaN semiconductor based on surface modification with lanthanide complexes through an ionic liquid bridge. RSC Adv 2:10840–10843CrossRef Li QP, Yan B (2012) Luminescent GaN semiconductor based on surface modification with lanthanide complexes through an ionic liquid bridge. RSC Adv 2:10840–10843CrossRef
37.
go back to reference Li QP, Yan B (2013) Novel luminescent hyrids y incorporating rare earth beta-diketonates into polymers through ion pairing with an imidazolium counter ion. Photochem Photobiol Sci 12:1628–1635CrossRef Li QP, Yan B (2013) Novel luminescent hyrids y incorporating rare earth beta-diketonates into polymers through ion pairing with an imidazolium counter ion. Photochem Photobiol Sci 12:1628–1635CrossRef
38.
go back to reference Mei Y, Lu Y, Yan B (2013) Multi-component hybrid soft gels containing Eu3+ complexes and MS (M = Zn, Cd) nanoparticles assembled with mercapto-ion liquid linkage: adjustable color and white luminescence. New J Chem 37:2619–2623CrossRef Mei Y, Lu Y, Yan B (2013) Multi-component hybrid soft gels containing Eu3+ complexes and MS (M = Zn, Cd) nanoparticles assembled with mercapto-ion liquid linkage: adjustable color and white luminescence. New J Chem 37:2619–2623CrossRef
39.
go back to reference Mei Y, Yan B (2014) White hybrid soft materials of lanthanide (Eu3+, Sm3+) beta-diketonates and Ag/Ag2S nanoparticles based with thiol-functionalized ionic liquid bridge. Inorg Chem Commun 14:39–42CrossRef Mei Y, Yan B (2014) White hybrid soft materials of lanthanide (Eu3+, Sm3+) beta-diketonates and Ag/Ag2S nanoparticles based with thiol-functionalized ionic liquid bridge. Inorg Chem Commun 14:39–42CrossRef
40.
go back to reference Mei Y, Lu Y, Yan B (2014) Soft materials composed with lanthanide (Eu3+, Tb3+) beta-diketonates and ZnO nanoparticles through thio-functionalized ionic liquid bridge to integrate white luminescence. J Photochem Photobiol A Chem 280:1–4CrossRef Mei Y, Lu Y, Yan B (2014) Soft materials composed with lanthanide (Eu3+, Tb3+) beta-diketonates and ZnO nanoparticles through thio-functionalized ionic liquid bridge to integrate white luminescence. J Photochem Photobiol A Chem 280:1–4CrossRef
41.
go back to reference Peacock RD, Weakley TJR (1971) Heteropolytungstate complexes of the lanthanide elements Part I. Preparation and reactions. J Chem Soc A 1836–1839 Peacock RD, Weakley TJR (1971) Heteropolytungstate complexes of the lanthanide elements Part I. Preparation and reactions. J Chem Soc A 1836–1839
Metadata
Title
Photoluminescent hybrid materials of lanthanide (Eu3+, Sm3+) polyoxometalates and polymer resin through ionic liquid linker
Authors
Ying Mei
Bing Yan
Publication date
01-03-2015
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 3/2015
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-014-3471-x

Other articles of this Issue 3/2015

Colloid and Polymer Science 3/2015 Go to the issue

Premium Partners