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2020 | OriginalPaper | Chapter

25. Photoresponsive Molecular Crystals for Light-Driven Photoactuators

Authors : Seiya Kobatake, Daichi Kitagawa

Published in: Photosynergetic Responses in Molecules and Molecular Aggregates

Publisher: Springer Singapore

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Abstract

Various types of photomechanical motion have drawn much attention because there is a potential to create photomechanical actuators from molecular-scale to macro-scale. To construct photoactuators, it is necessary to utilize a molecular assembly with a small free volume. Photochromic compounds undergo photoreversible isomerization between the original colorless isomer and the photogenerated colored isomer upon alternating irradiation with UV and visible light. Among many known photochromic compounds, diarylethenes undergo photochromic reactions even in the crystalline phase. The present review introduces recent development in the study of photomechanical crystals including crystal shape changes, bending velocity, dependence of the bending behavior on irradiation wavelength, the behavior in mixed crystal, new types of photomechanical motion, and applications. These photomechanical behaviors are based on geometrical structure changes in the crystalline phase and can be applied to macro-sized light-driven photoactuators.

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previous chapter Biomimetic Functions by Microscopic Molecular Reactions in Macroscopic Photoresponsive Crystalline System

next chapter Interplay of Photoisomerization and Phase Transition Events Provide a Working Supramolecular Motor

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Title: Photoresponsive Molecular Crystals for Light-Driven Photoactuators
Authors: Seiya Kobatake
Daichi Kitagawa
Publisher: Springer Singapore
Book: Photosynergetic Responses in Molecules and Molecular Aggregates
Print ISBN: 978-981-15-5450-6

Electronic ISBN: 978-981-15-5451-3

Copyright Year: 2020
DOI: https://doi.org/10.1007/978-981-15-5451-3_25

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