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Published in: Colloid and Polymer Science 6/2017

13-04-2017 | Original Contribution

Pickering emulsion polymerized magnetite-poly(methyl methacrylate) composite particles and their magnetorheology

Authors: Chun Yan Gao, Shang Hao Piao, Hyoung Jin Choi

Published in: Colloid and Polymer Science | Issue 6/2017

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Abstract

Magnetic poly(methyl methacrylate) (PMMA)/Fe3O4 composite nanoparticles were fabricated by Pickering emulsion polymerization using nano-sized iron oxide (Fe3O4) particles as a solid stabilizer that had been synthesized initially from a hydrothermal process. High-resolution scanning electron microscopy was applied to characterize the morphology of the materials. Fourier transformation infrared spectroscopy confirmed the chemical structure of both pure Fe3O4 and PMMA/Fe3O4 composites. The magnetic properties and atomic and molecular structure of a crystal of the materials were examined by vibration sample magnetometry and X-ray diffraction, respectively. The magnetorheological (MR) features of both pure Fe3O4 and PMMA/Fe3O4 nanoparticles dispersed in mineral oil under a magnetic field were characterized by a rotational rheometer. The dynamic yield stress was higher than the elastic stress under external magnetic field. The PMMA/Fe3O4 composite-based MR fluid showed good dispersion stability, while exhibiting typical MR characteristics for the applied magnetic field dependent yield stress with a slope of 1.5.

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Metadata
Title
Pickering emulsion polymerized magnetite-poly(methyl methacrylate) composite particles and their magnetorheology
Authors
Chun Yan Gao
Shang Hao Piao
Hyoung Jin Choi
Publication date
13-04-2017
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 6/2017
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4086-9

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