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2020 | OriginalPaper | Chapter

7. Plasmon-Associated Control of Chemical Reaction at Nanometer Scale

Authors : Shuichi Toyouchi, Tomoko Inose, Kenji Hirai, Hiroshi Uji-i

Published in: Photosynergetic Responses in Molecules and Molecular Aggregates

Publisher: Springer Singapore

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Abstract

In this chapter, we introduce multiphoton photochromic reversible reaction in a diarylethene derivative at nanometer scale much beyond the diffraction limit. For this, we have utilized nonlinear plasmonics along a plasmonic waveguide, particularly on the chemically synthesized silver nanowire. Propagating near-field surface plasmons excited by near-infrared femtosecond laser pulses successfully excite diarylethene derivatives surrounding a silver nanowire. Three-photon cyclization and two-photon cycloreversion reaction induced through the propagating surface plasmon polaritons were visualized by means of fluorescence imaging. We demonstrated one-color near-infrared laser reversible control by tuning the laser power.

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previous chapter Advanced Function Control of Photochemical Reactions Using Mesoscopic Structures

next chapter Modulations of Electronic States in Plasmonic Strong Coupling Systems and Their Application to Photochemical Reaction Fields

Graff A, Wagner D, Ditlbacher H, Kreibig U (2005) Silver nanowires. Eur Phys J D 34:263–269CrossRef

Wei H, Xu H (2012) Nanowire-based plasmonic waveguides and devices for integrated nanophotonic circuits. Nanophotonics 1:155–169CrossRef

Xiong X, Zou CL, Ren XF, Liu AP, Ye YX, Sun FW, Guo GC (2013) Silver nanowires for photonics applications. Laser Photon Rev 1–19

Hutchison JA, Centeno SP, Odaka H, Fukumura H, Hofens J, Uji-i H (2009) Subdiffraction limited, remote excitation of surface enhanced Raman scattering. Nano Lett 9:995–1001CrossRef

Fang Y, Wei H, Hao F, Nordlander P, Xu H (2009) Remote-excitation surface-enhanced Raman scattering using propagating Ag nanowire plasmons. Nano Lett 9:2049–2053CrossRef

Su L, Lu G, Kenens B, Rocha S, Fron E, Yuan H, Chen C, Dorpe PV, Roeffaers BJ, Mizuno H, Hofkens J, Hutchison JA, Uji-i H (2015) Visualization of molecular fluorescence point spread functions via remote excitation switching fluorescence microscopy. Nat. Commun. 6:1–9

Lu G, De Keersmaecker H, Su L, Kenens B, Rocha S, Fron E, Chen C, Van Dorpe P, Mizuno H, Hofkens J, Hutchison JA, Uji-i H (2014) Live-cell SERS endoscopy using plasmonic nanowire waveguides. Adv Mater 26:5124–5128CrossRef

Halas NJ, Lal S, Chang W-S, Link S, Nordlander P (2011) Plasmons in strongly coupled metallic nanostructures. Chem Rev 111:3913–3961CrossRef

Huang Y, Fang Y, Zhang Z, Zhu L, Sun M (2014) Nanowire-supported plasmonic waveguide for remote excitation of surface-enhanced Raman scattering. Light Sci Appl 3:e199CrossRef

10.

Krenn JR, Weeber J-C (2004) Surface plasmon polaritons in metal stripes and wires. Philos Trans R Soc Lond Ser A 362:739–756CrossRef

11.

Ditlbacher H, Hohenau A, Wagner D, Kreibig U, Rogers M, Hofer F, Aussenegg FR, Krenn JR (2005) Silver nanowires as surface plasmon resonators. Phys Rev Lett 95:257403CrossRef

12.

Sanders AW, Routenberg DA, Wiley BJ, Xia Y, Dufresne ER, Reed MA (2006) Observation of plasmon propagation, redirection, and fan-out in silver nanowires. Nano Lett 6:1822–1826CrossRef

13.

Ru EL, Etchegoin P (2008) Principles of surface-enhanced Raman spectroscopy: and related plasmonic effects. Elsevier Science

14.

Lin H, Centeno SP, Su L, Kenens B, Rocha S, Sliwa M, Hofkens J, Uji-i H (2012) Mapping of surface-enhanced fluorescence on metal nanoparticles using super-resolution photoactivation localization microscopy. Chem Phys Chem 13:973–981CrossRef

15.

Orrit M (2014) Nobel prize in chemistry: celebrating optical nanoscopy. Nat Photon 8:887–888CrossRef

16.

Rust MJ, Bates M, Zhuang X (2006) Sub-diffraction-limit imaging by stochastic optical reconstruction microscopy (STORM). Nat Methods 3:793–796CrossRef

17.

Schüttpelz M, Wolter S, van de Linde S, Heilemann M, Sauer M (2010) dSTORM: realtim subdiffraction-resolution fluorescence imaging with organic fluorophores. In: Proceedings of SPIE, vol 7571. pp 75710 V–7

18.

van de Linde S, Loschberger A, Klein T, Heidbreder M, Wolter S, Heilemann M, Sauer M (2011) Direct stochastic optical reconstruction microscopy with standard fluorescent probes. Nat Protoc 6:991–1009CrossRef

19.

Kauranen M, Zayats AV (2012) Nonlinear plasmonics. Nat Photon 6:737–748CrossRef

20.

Inose T, Toyouchi S, Lu G, Umemoto K, Tezuka Y, Lyu B, Masuhara A, Fron E, Fujita Y, Hirai K, Uji-i H (2019) Water-mediated polyol synthesis of pencil-like sharp silver nanowires suitable for nonlinear plasmonics. Chem Common 55:11630–11633CrossRef

21.

Irie M, Fukaminato T, Matsuda K, Kobatake S (2014) Photochromism of diarylethene molecules and crystals: Memories, switches, and actuators. Chem Rev 114:12174CrossRef

22.

Mori K, Ishibashi Y, Matsuda H, Ito S, Nagasawa Y, Nakagawa H, Uchida K, Yokojima S, Nakamura S, Irie M, Miyasaka H (2011) One-color reversible control of photochromic reactions in a diarylethene derivative: three-photon cyclization and two-photon cycloreversion by a near-infrared femtosecond laser pulse at 1.28 μm. J Am Chem Soc 133:2621

23.

Sotome H, Nagasaka T, Une K, Okui C, Ishibashi Y, Kamada K, Kobatake S, Irie M, Miyasaka H (2017) Efficient cycloreversion reaction of a diarylethene derivative in higher excited states attained by off-resonant simultaneous two-photon absorption. J Phys Chem Lett 8:3272CrossRef

24.

Kasha M (1950) Characterization of electronic transitions in complex molecules. Discuss Faraday Soc 9:14CrossRef

25.

de Klerk JS, Szemik-Hojniak A, Ariese F, Gooijer C (2007) Intramolecular proton-transfer processes starting at higher excited states: a fluorescence study on 2-butylamino-6-methyl-4-nitropyridine N-oxide in nonpolar solutions. J Phys Chem A 111:5828CrossRef

26.

Tseng HW, Shen JY, Kuo TY, Tu TS, Chen YA, Demchenko AP, Chou PT (2016) Excited-state intramolecular proton-transfer reaction demonstrating anti-Kasha behavior. Chem Sci 7:655CrossRef

27.

Sotome H, Nagasaka T, Une K, Morikawa S, Katayama T, Kobatake S, Irie M, Miyasaka H (2017) Cycloreversion reaction of a diarylethene derivative at higher excited states attained by two-color, two-photon femtosecond pulsed excitation. J Am Chem Soc 139:17159CrossRef

Title: Plasmon-Associated Control of Chemical Reaction at Nanometer Scale
Authors: Shuichi Toyouchi
Tomoko Inose
Kenji Hirai
Hiroshi Uji-i
Publisher: Springer Singapore
Book: Photosynergetic Responses in Molecules and Molecular Aggregates
Print ISBN: 978-981-15-5450-6

Electronic ISBN: 978-981-15-5451-3

Copyright Year: 2020
DOI: https://doi.org/10.1007/978-981-15-5451-3_7

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