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Published in: Journal of Coatings Technology and Research 3/2021

08-02-2021

Poly(methyl methacrylate) intercalated layered double hydroxide film with enhanced alkaline corrosion resistance for aluminum alloy AA6061

Authors: Po-Yi Liu, Chih-Cheng Tsai, Shang-Tien Tsai, Wen-Chyuan ChangJean, Shou-Chiu Cheng, Tseng-Chang Tsai

Published in: Journal of Coatings Technology and Research | Issue 3/2021

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Abstract

The oriented growth of Zn-Al LDH film perpendicular to the surface of AA6061 substrate was confirmed by scanning microscopy image and X-ray diffraction pattern. The LDH film achieved a complete surface coverage on the AA6061 substrate and exhibited strong corrosion resistance in NaOH solution (pH of 13). Furthermore, a preparation protocol for poly(methyl methacrylate) (PMMA)-LDH composite film was demonstrated. LDH film intercalated only with PMMA but not polyurethane demonstrated greatly enhanced alkaline corrosion resistance, showing a more positive corrosion potential and reduced corrosion current by four orders of magnitude in electrochemical polarization spectroscopy. The enhancement in corrosion resistance by PMMA intercalation could be attributed to the increasing compactness in the LDH film and increasing hydrophobicity.

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Metadata
Title
Poly(methyl methacrylate) intercalated layered double hydroxide film with enhanced alkaline corrosion resistance for aluminum alloy AA6061
Authors
Po-Yi Liu
Chih-Cheng Tsai
Shang-Tien Tsai
Wen-Chyuan ChangJean
Shou-Chiu Cheng
Tseng-Chang Tsai
Publication date
08-02-2021
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 3/2021
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-020-00442-0

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