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Polymer Blends: Introduction Read chapter Read first chapter

2014 | OriginalPaper | Chapter

17. Polymer Blends Containing “Nanoparticles”

Authors : D. R. Paul, R. R. Tiwari

Published in: Polymer Blends Handbook

Publisher: Springer Netherlands

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Abstract

This chapter discusses the role of various nanoparticles in immiscible polymer blends for control of the size of the dispersed polymer phase particles, phase inversion and rheological behavior, impact strength, and mechanical performance. Various issues such as the effect of nanoparticle dimensions on the polymer particle size and properties, blending sequence, location of nanoparticles in the blend components, mechanism behind improvement in properties, individual effect of various fillers on the blend properties, and future trends are also discussed in detail. Since the literature on polymer nanocomposites is vast and the utilization of nanoparticles in blends has significantly increased in recent years, this chapter is designed to review the current state of knowledge in this area. To do so, various examples of polymer blends and nanofillers relevant to the abovementioned factors are discussed.

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previous chapter High Performance Polymer Alloys and Blends for Special Applications
next chapter Polyethylenes and Their Blends
Glossary
ABS
Acrylonitrile–butadiene–styrene
AFM
Atomic force microscopy
a-PA
Amorphous polyamide
CaCO3
Calcium carbonate
CNT
Carbon nanotube
CTE
Coefficient of linear thermal expansion
D-B
Ductile–brittle
EA
Ethylene–acrylate copolymer
E-MA-GMA
Ethylene–methyl acrylate–glycidyl methacrylate copolymer
EOR
Ethylene–octene rubber
EOR-g-MA
Ethylene–octene rubber grafted maleic anhydride
EPDM
Ethylene–propylene–diene terpolymer
EPDM-g-MA
Ethylene–propylene–diene grafted maleic anhydride
EPR
Ethylene–propylene rubber
EPR-g-MA
Ethylene–propylene rubber grafted maleic anhydride
EVA
Ethylene–vinyl acetate copolymer
FD
Flow direction
HDPE
High-density polyethylene
H-PP
High molecular weight polypropylene
LCP
Liquid crystalline polymer
LDPE
Low-density polyethylene
LLDPE
Linear low-density polyethylene
L-PP
Low molecular weight polypropylene
MA
Maleic anhydride
MFI
Melt flow index
MMT
Montmorillonite
M-PP
Medium molecular weight polypropylene
MWCNT
Multiwalled carbon nanotube
MWD
Molecular weight distribution
ND
Normal direction
OMMT
Organically modified montmorillonite
PA
Polyamide
PA 6
Polyamide 6
PA 66
Polyamide 66
PBT
Polybutylene terephthalate
PC
Polycarbonate
PCL
Poly (ε-caprolactone)
PDMS
Polydimethylsiloxane
PE
Polyethylene
PE-GMA
Ethylene–glycidyl methacrylate
PET
Poly (ethylene terephthalate)
PIB
Polyisobutylene
PLA
Polylactide
PLLA
Poly (l-lactide)
PP
Polypropylene
PPC
Poly (propylene carbonate)
PP-g-MA
Polypropylene grafted maleic anhydride
pph
Parts per hundred
PPO
Polyphenylene oxide
PPS
Poly (p-phenylene sulfide)
PS
Polystyrene
PVDF
Polyvinylidene fluoride
SAN
Poly (styrene acrylonitrile)
SBS
Styrene–butadiene–styrene
SEBS
Styrene–ethylene–butylene–styrene
SEBS-g-MA
SEBS grafted maleic anhydride
SEM
Scanning electron microscope
SEP
Styrene–ethylene–propylene
SiO2
Silica
SIS
Styrene–isoprene–styrene
TD
Transverse direction
TEM
Transmission electron microscope
TiO2
Titanium dioxide
TPO
Thermoplastic olefin
VA
Vinyl acetate
VP 701
Vulcanized butadiene–styrene rubber
a
Yasuda parameter
\( {\overline{\boldsymbol{d}}}_{\boldsymbol{w}} \)
Weight average particle size
G′, G″, G*
Storage, loss and complex shear modulus, respectively
h
Hour
m
Meter
min
Minute
N
Newton
n
Power law index
nm
Nanometer
p
Viscosity ratio of dispersed to continuous phase
R
Volume average dispersed particle radius
T g
Glass transition temperature
T m
Melting temperature
wt%
Weight percent
γ
Interfacial tension
η
Shear viscosity
η 0
Zero shear viscosity
η 1, η 2
Viscosity of phase 1 and 2 respectively
η d , η m
Viscosity of dispersed and matrix phase respectively
λ
Time constant
μm
Micrometer
σ 0
Melt yield stress
τ
Relaxation time
ϕ
Volume fraction
χ c
Percent crystallinity
ω
Frequency
ω a
Wetting coefficient
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Metadata
Title
Polymer Blends Containing “Nanoparticles”
Authors
D. R. Paul
R. R. Tiwari
Copyright Year
2014
Publisher
Springer Netherlands
Book
Polymer Blends Handbook

Print ISBN: 978-94-007-6063-9

Electronic ISBN: 978-94-007-6064-6

Copyright Year: 2014

DOI
https://doi.org/10.1007/978-94-007-6064-6_20

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