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Journal of Polymer Research
Published in: Journal of Polymer Research 6/2015

01-06-2015 | Original Paper

Polymer-metal complexes of polyacrylonitrile and its copolymers: synthesis and theoretical study

Authors: Raulia Syrlybaeva, Nazrin Movsum-zade, Ilnara Safiullina, Yuri Puzin, Eldar Movsum-zade

Published in: Journal of Polymer Research | Issue 6/2015

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Abstract

Polyacrylonitrile, poly(styrene-acrylonitrile) and poly(acrylonitrile-butadiene-styrene) complexes with transition metal salts have been synthesized. The synthesis were attempted by carrying out free radical polymerization reactions in aqueous transition metal salt solutions (ZnCl2, CuCl2, CoCl2, CoSO4, NiSO4, CuSO4) and by addition of the transition metal salts to the reaction mixture in the final stage of the polymerization. It is shown experimentally and theoretically that the first method is successful only when zinc chloride is used, while the cobalt, nickel, copper complexes are formed through the addition of the salts to the ready polymers. Reactions that take place during studied complexations were investigated by means of ab initio quantum chemistry calculations, thermodynamic parameters for these reactions were determined.
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Metadata
Title
Polymer-metal complexes of polyacrylonitrile and its copolymers: synthesis and theoretical study
Authors
Raulia Syrlybaeva
Nazrin Movsum-zade
Ilnara Safiullina
Yuri Puzin
Eldar Movsum-zade
Publication date
01-06-2015
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 6/2015
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-015-0716-4

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