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2017 | OriginalPaper | Chapter

6. Porous Carbons for Hydrogen Storage

Authors : Mathieu Bosch, Hong-Cai Zhou

Published in: Nanostructured Materials for Next-Generation Energy Storage and Conversion

Publisher: Springer Berlin Heidelberg

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Abstract

Porous carbon-based materials are promising candidates as adsorbents to increase the gravimetric and volumetric uptake of hydrogen at cryogenic temperatures and moderate pressures. In most cases, this uptake increases linearly with surface area, but strategies to increase uptake beyond that predicted by this “chahine rule,” to increase surface area, and to otherwise improve these materials are discussed.

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previous chapter Hydrogen Storage in Metal-Organic Frameworks

next chapter Strategies for Hydrogen Storage in Porous Organic Polymers

B. Panella, M. Hirscher, S. Roth, Hydrogen adsorption in different carbon nanostructures. Carbon 43(10), 2209–2214 (2005)

O.K. Farha, I. Eryazici, N.C. Jeong, B.G. Hauser, C.E. Wilmer, A.A. Sarjeant, R.Q. Snurr, S.T. Nguyen, A.Ö. Yazaydın, J.T. Hupp, Metal–organic framework materials with ultrahigh surface areas: is the sky the limit? J. Am. Chem. Soc. 134(36), 15016–15021 (2012)

S.J. Yang, J.H. Im, H. Nishihara, H. Jung, K. Lee, T. Kyotani, C.R. Park, General relationship between hydrogen adsorption capacities at 77 and 298 K and pore characteristics of the porous adsorbents. J. Phys. Chem. C 116(19), 10529–10540 (2012)

K. Kaneko, C. Ishii, M. Ruike, H. Kuwabara, Origin of superhigh surface-area and microcrystalline graphitic structures of activated carbons. Carbon 30(7), 1075–1088 (1992)

(a) D.A. Gómez-Gualdrón, P.Z. Moghadam, J.T. Hupp, O.K. Farha, R.Q. Snurr, Application of consistency criteria to calculate BET areas of micro- and mesoporous metal–organic frameworks. J. Am. Chem. Soc. 100, 100–101 (2015); (b) T.C. Wang, W. Bury, D.A. Gómez-Gualdrón, N.A. Vermeulen, J.E. Mondloch, P. Deria, K. Zhang, P.Z. Moghadam, A.A. Sarjeant, R.Q. Snurr, J.F. Stoddart, J.T. Hupp, O.K. Farha, Ultrahigh surface area zirconium MOFs and insights into the applicability of the BET theory. J. Am. Chem. Soc. 137(10), 3585–3591 (2015)

D.E. Demirocak, S.S. Srinivasan, M.K. Ram, D.Y. Goswami, E.K. Stefanakos, Volumetric hydrogen sorption measurements – uncertainty error analysis and the importance of thermal equilibration time. Int. J. Hydrogen Energy 38(3), 1469–1477 (2013)

T. Duren, F. Millange, G. Ferey, K.S. Walton, R.Q. Snurr, Calculating geometric surface areas as a characterization tool for metal-organic frameworks. J. Phys. Chem. C 111(42), 15350–15356 (2007)

M. Sevilla, R. Mokaya, Energy storage applications of activated carbons: Supercapacitors and hydrogen storage. Energy Environ. Sci. 7(4), 1250–1280 (2014)

B. Feng, S.K. Bhatia, Variation of the pore structure of coal chars during gasification. Carbon 41(3), 507–523 (2003)

10.

S. Osswald, C. Portet, Y. Gogotsi, G. Laudisio, J.P. Singer, J.E. Fischer, V.V. Sokolov, J.A. Kukushkina, A.E. Kravchik, Porosity control in nanoporous carbide-derived carbon by oxidation in air and carbon dioxide. J. Solid State Chem. 182(7), 1733–1741 (2009)

11.

(a) I. Cabria, M.J. Lopez, J.A. Alonso, The optimum average nanopore size for hydrogen storage in carbon nanoporous materials. Carbon 45(13), 2649–2658 (2007); (b) M. Sevilla, P. Valle-Vigon, A.B. Fuertes, N-doped polypyrrole-based porous carbons for CO₂ capture. Adv. Funct. Mater. 21(14), 2781–2787 (2011)

12.

H.L. Wang, Q.M. Gao, J. Hu, High hydrogen storage capacity of porous carbons prepared by using activated carbon. J. Am. Chem. Soc. 131(20), 7016–7022 (2009)

13.

S.J. Yang, H. Jung, T. Kim, C.R. Park, Recent advances in hydrogen storage technologies based on nanoporous carbon materials. Progr. Nat. Sci. Mater. Int. 22(6), 631–638 (2012)

14.

(a) Y. Liu, J.S. Xue, T. Zheng, J.R. Dahn, Mechanism of lithium insertion in hard carbons prepared by pyrolysis of epoxy resins. Carbon 34(2), 193–200 (1996); (b) V. Subramanian, C. Luo, A.M. Stephan, K.S. Nahm, S. Thomas, B. Wei, Supercapacitors from activated carbon derived from banana fibers. J. Phys. Chem. C 111(20), 7527–7531 (2007)

15.

D. Qu, Investigation of hydrogen physisorption active sites on the surface of porous carbonaceous materials. Chem. Eur. J. 14(3), 1040–1046 (2008)

16.

M. Molina-Sabio, F. Rodriguez-Reinoso, Role of chemical activation in the development of carbon porosity. Colloid Surf. A 241(1–3), 15–25 (2004)

17.

R. Yang, G. Liu, M. Li, J. Zhang, X. Hao, Preparation and N₂, CO₂ and H₂ adsorption of super activated carbon derived from biomass source hemp (Cannabis sativa L.) stem. Microporous Mesoporous Mater. 158, 108–116 (2012)

18.

J. Wang, I. Senkovska, S. Kaskel, Q. Liu, Chemically activated fungi-based porous carbons for hydrogen storage. Carbon 75, 372–380 (2014)

19.

I. Wróbel-Iwaniec, N. Díez, G. Gryglewicz, Chitosan-based highly activated carbons for hydrogen storage. Int. J. Hydrogen Energy 40(17), 5788–5796 (2015)

20.

J. Cai, J. Qi, C. Yang, X. Zhao, Poly(vinylidene chloride)-based carbon with ultrahigh microporosity and outstanding performance for CH₄ and H₂ storage and CO₂ capture. ACS Appl. Mater. Interfaces 6(5), 3703–3711 (2014)

21.

G. Mercier, A. Klechikov, M. Hedenström, D. Johnels, I.A. Baburin, G. Seifert, R. Mysyk, A.V. Talyzin, Porous graphene oxide/diboronic acid materials structure and hydrogen sorption. J. Phys. Chem. C 119(49), 27179–27191 (2015)

22.

D. Krishnan, F. Kim, J. Luo, R. Cruz-Silva, L.J. Cote, H.D. Jang, J. Huang, Energetic graphene oxide: challenges and opportunities. Nano Today 7(2), 137–152 (2012)

23.

S.H. Aboutalebi, S. Aminorroaya-Yamini, I. Nevirkovets, K. Konstantinov, H.K. Liu, Enhanced hydrogen storage in graphene oxide-MWCNTs composite at room temperature. Adv. Energy Mater. 2(12), 1439–1446 (2012)

24.

G. Srinivas, Y.W. Zhu, R. Piner, N. Skipper, M. Ellerby, R. Ruoff, Synthesis of graphene-like nanosheets and their hydrogen adsorption capacity. Carbon 48(3), 630–635 (2010)

25.

S. Gadipelli, Z.X. Guo, Graphene-based materials: synthesis and gas sorption, storage and separation. Prog. Mater. Sci. 69, 1–60 (2015)

26.

A. Klechikov, G. Mercier, T. Sharifi, I.A. Baburin, G. Seifert, A.V. Talyzin, Hydrogen storage in high surface area graphene scaffolds. Chem. Commun. 51(83), 15280–15283 (2015)

27.

S.J. Yang, T. Kim, J.H. Im, Y.S. Kim, K. Lee, H. Jung, C.R. Park, MOF-derived hierarchically porous carbon with exceptional porosity and hydrogen storage capacity. Chem. Mater. 24(3), 464–470 (2012)

28.

T. Segakweng, N. Musyoka, J. Ren, P. Crouse, H. Langmi, Comparison of MOF-5- and Cr-MOF-derived carbons for hydrogen storage application. Res. Chem. Intermed. 1–11 (2015)

29.

T.K. Kim, K.J. Lee, J.Y. Cheon, J.H. Lee, S.H. Joo, H.R. Moon, Nanoporous metal oxides with tunable and nanocrystalline frameworks via conversion of metal–organic frameworks. J. Am. Chem. Soc. 135(24), 8940–8946 (2013)

30.

W.Q. Wang, D.Q. Yuan, Mesoporous carbon originated from non-permanent porous MOFs for gas storage and CO₂/CH₄ separation. Sci. Rep-Uk 4 (2014)

31.

M. Hu, J. Reboul, S. Furukawa, N.L. Torad, Q. Ji, P. Srinivasu, K. Ariga, S. Kitagawa, Y. Yamauchi, Direct carbonization of al-based porous coordination polymer for synthesis of nanoporous carbon. J. Am. Chem. Soc. 134(6), 2864–2867 (2012)

32.

W. Xia, B. Qiu, D. Xia, R. Zou, Facile preparation of hierarchically porous carbons from metal-organic gels and their application in energy storage. Sci. Rep-Uk 2013, 3 (1935)

33.

K. Kongpatpanich, S. Horike, Y. Fujiwara, N. Ogiwara, H. Nishihara, S. Kitagawa, Formation of foam-like microstructural carbon material by carbonization of porous coordination polymers through a ligand-assisted foaming process. Chem-Eur. J. 21(38), 13278–13283 (2015)

34.

S.J. Yang, T. Kim, K. Lee, Y.S. Kim, J. Yoon, C.R. Park, Solvent evaporation mediated preparation of hierarchically porous metal organic framework-derived carbon with controllable and accessible large-scale porosity. Carbon 71, 294–302 (2014)

35.

K. Jayaramulu, K.K.R. Datta, K. Shiva, A.J. Bhattacharyya, M. Eswaramoorthy, T.K. Maji, Controlled synthesis of tunable nanoporous carbons for gas storage and supercapacitor application. Microporous Mesoporous Mater. 206, 127–135 (2015)

36.

A. Aijaz, J.-K. Sun, P. Pachfule, T. Uchida, Q. Xu, From a metal-organic framework to hierarchical high surface-area hollow octahedral carbon cages. Chem. Commun. 51(73), 13945–13948 (2015)

37.

G.J. Kubas, Metal-dihydrogen and sigma-bond coordination: the consummate extension of the Dewar-Chatt-Duncanson model for metal-olefin bonding. J. Organomet. Chem. 635(1–2), 37–68 (2001)

38.

Y.R. Liu, D. Li, B.P. Lin, Y. Sun, X.Q. Zhang, H. Yang, Hydrothermal synthesis of Ni-doped hierarchically porous carbon monoliths for hydrogen storage. J. Porous. Mater. 22(6), 1417–1422 (2015)

39.

V.B. Parambhath, R. Nagar, K. Sethupathi, S. Ramaprabhu, Investigation of spillover mechanism in palladium decorated hydrogen exfoliated functionalized graphene. J. Phys. Chem. C 115(31), 15679–15685 (2011)

40.

H.B. Aiyappa, P. Pachfule, R. Banerjee, S. Kurungot, Porous carbons from nonporous MOFs: influence of ligand characteristics on intrinsic properties of end carbon. Cryst. Growth Des. 13(10), 4195–4199 (2013)

41.

B.P. Vinayan, K. Sethupathi, S. Ramaprabhu, Facile synthesis of triangular shaped palladium nanoparticles decorated nitrogen doped graphene and their catalytic study for renewable energy applications. Int. J. Hydrogen Energy 38(5), 2240–2250 (2013)

42.

Y. Wang, J. Liu, K. Wang, T. Chen, X. Tan, C.M. Li, Hydrogen storage in Ni–B nanoalloy-doped 2D graphene. Int. J. Hydrogen Energ 36(20), 12950–12954 (2011)

43.

Y. Wang, C.X. Guo, X. Wang, C. Guan, H. Yang, K. Wang, C.M. Li, Hydrogen storage in a Ni-B nanoalloy-doped three-dimensional graphene material. Energy Environ. Sci. 4(1), 195–200 (2011)

44.

G.M. Psofogiannakis, T.A. Steriotis, A.B. Bourlinos, E.P. Kouvelos, G.C. Charalambopoulou, A.K. Stubos, G.E. Froudakis, Enhanced hydrogen storage by spillover on metal-doped carbon foam: an experimental and computational study. Nanoscale 3(3), 933–936 (2011)

45.

H. Nishihara, P.-X. Hou, L.-X. Li, M. Ito, M. Uchiyama, T. Kaburagi, A. Ikura, J. Katamura, T. Kawarada, K. Mizuuchi, T. Kyotani, High-pressure hydrogen storage in zeolite-templated carbon. J. Phys. Chem. C 113(8), 3189–3196 (2009)

46.

Z.X. Yang, Y.D. Xia, R. Mokaya, Enhanced hydrogen storage capacity of high surface area zeolite-like carbon materials. J. Am. Chem. Soc. 129(6), 1673–1679 (2007)

47.

N. Musyoka, J. Ren, P. Annamalai, H. Langmi, B. North, M. Mathe, D. Bessarabov, Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications. Res. Chem. Intermed. 1–9 (2015)

48.

E. Masika, R.A. Bourne, T.W. Chamberlain, R. Mokaya, Supercritical CO₂ mediated incorporation of pd onto templated carbons: a route to optimizing the pd particle size and hydrogen uptake density. ACS Appl. Mater. Interfaces 5(12), 5639–5647 (2013)

49.

H. Nishihara, S. Ittisanronnachai, H. Itoi, L.-X. Li, K. Suzuki, U. Nagashima, H. Ogawa, T. Kyotani, M. Ito, Experimental and theoretical studies of hydrogen/deuterium spillover on pt-loaded zeolite-templated carbon. J. Phys. Chem. C 118(18), 9551–9559 (2014)

50.

(a) Q. Zhou, C. Wang, Z. Fu, L. Yuan, X. Yang, Y. Tang, H. Zhang, Hydrogen adsorption on palladium anchored defected graphene with B-doping: a theoretical study. Int. J. Hydrogen Energy 40(6), 2473–2483 (2015); (b) L. Wang, J.A.J. Lachawiec, R.T. Yang, Nanostructured adsorbents for hydrogen storage at ambient temperature: high-pressure measurements and factors influencing hydrogen spillover. RSC Adv. 3(46), 23935–23952 (2013)

51.

J. Shi, W. Li, D. Li, Synthesis, nickel decoration, and hydrogen adsorption of silica-templated mesoporous carbon material with high surface area. J. Phys. Chem. C 119(41), 23430–23435 (2015)

52.

(a) G. Yushin, R. Dash, J. Jagiello, J.E. Fischer, Y. Gogotsi, Carbide-derived carbons: effect of pore size on hydrogen uptake and heat of adsorption. Adv. Funct. Mater. 16(17), 2288–2293 (2006); (b) Y. Gogotsi, R.K. Dash, G. Yushin, T. Yildirim, G. Laudisio, J.E. Fischer, Tailoring of nanoscale porosity in carbide-derived carbons for hydrogen storage. J. Am. Chem. Soc. 127(46), 16006–16007 (2005)

53.

H.S. Kim, J.P. Singer, Y. Gogotsi, J.E. Fischer, Molybdenum carbide-derived carbon for hydrogen storage. Microporous Mesoporous Mater. 120(3), 267–271 (2009)

54.

S.-H. Yeon, I. Knoke, Y. Gogotsi, J.E. Fischer, Enhanced volumetric hydrogen and methane storage capacity of monolithic carbide-derived carbon. Microporous Mesoporous Mater. 131(1–3), 423–428 (2010)

55.

M. Sevilla, R. Foulston, R. Mokaya, Superactivated carbide-derived carbons with high hydrogen storage capacity. Energ Environ Sci 3(2), 223–227 (2010)

56.

D. Yuan, W. Lu, D. Zhao, H.-C. Zhou, Highly stable porous polymer networks with exceptionally high gas-uptake capacities. Adv. Mater. 23(32), 3723–3725 (2011)

57.

T. Ben, H. Ren, S. Ma, D. Cao, J. Lan, X. Jing, W. Wang, J. Xu, F. Deng, J.M. Simmons, S. Qiu, G. Zhu, Targeted synthesis of a porous aromatic framework with high stability and exceptionally high surface area. Angew. Chem. Int. Ed. 48(50), 9457–9460 (2009)

58.

L.B. Sun, A.G. Li, X.D. Liu, X.Q. Liu, D.W. Feng, W.G. Lu, D.Q. Yuan, H.C. Zhou, Facile fabrication of cost-effective porous polymer networks for highly selective CO₂ capture. J. Mater. Chem. A 3(7), 3252–3256 (2015)

59.

S. Wu, Y. Liu, G. Yu, J. Guan, C. Pan, Y. Du, X. Xiong, Z. Wang, Facile preparation of dibenzoheterocycle-functional nanoporous polymeric networks with high gas uptake capacities. Macromolecules 47(9), 2875–2882 (2014)

60.

Z. Xiang, R. Mercado, J.M. Huck, H. Wang, Z. Guo, W. Wang, D. Cao, M. Haranczyk, B. Smit, Systematic tuning and multifunctionalization of covalent organic polymers for enhanced carbon capture. J. Am. Chem. Soc. 137(41), 13301–13307 (2015)

61.

W.G. Lu, Z.W. Wei, D.Q. Yuan, J. Tian, S. Fordham, H.C. Zhou, Rational design and synthesis of porous polymer networks: toward high surface area. Chem. Mater. 26(15), 4589–4597 (2014)

62.

Y. Li, T. Ben, B. Zhang, Y. Fu, S. Qiu, Ultrahigh gas storage both at low and high pressures in KOH-activated carbonized porous aromatic frameworks. Sci. Rep-Uk 3, 2420 (2013)

Title: Porous Carbons for Hydrogen Storage
Authors: Mathieu Bosch
Hong-Cai Zhou
Publisher: Springer Berlin Heidelberg
Book: Nanostructured Materials for Next-Generation Energy Storage and Conversion
Print ISBN: 978-3-662-53512-7

Electronic ISBN: 978-3-662-53514-1

Copyright Year: 2017
DOI: https://doi.org/10.1007/978-3-662-53514-1_6

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