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Journal of Coatings Technology and Research

Published in:

11-07-2022

Preparation and properties of a novel coating based on bismaleimides via Michael addition reaction

Authors: Jiajian He, Kai Cheng, Ruijun Lin, Qiuping Su, Yong Li, Zhiping Ma, Shaoshun Wang, Yuxin Gu, Xiaofeng Lin, Wenjing Lin, Guobin Yi

Published in: Journal of Coatings Technology and Research | Issue 6/2022

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Abstract

In this work, a malonate polyester suitable for Michael addition reaction was prepared by melting polycondensation of neopentyl glycol, terephthalic acid, and diethyl malonate, and its structure was characterized by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance spectroscopy (NMR). Then, Michael addition reaction between malonate polyester and diphenylmethane bismaleimide (BDM), catalyzed by 1, 8-diazabicyclo [5.4.0] undec-7-ene (DBU)/benzoic acid salt, was carried out to prepare the films with different contents of curing agent. The thermal and mechanical properties of the films were characterized by dynamic thermomechanical analysis, thermogravimetric analysis, and differential scanning calorimetry. We found that glass transition temperature (T_g) of the films increased with the increase in BDM amount. The T_g could reach up to 80°C, which indicated that the fabricated films show excellent thermal stability.

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Title: Preparation and properties of a novel coating based on bismaleimides via Michael addition reaction
Authors: Jiajian He
Kai Cheng
Ruijun Lin
Qiuping Su
Yong Li
Zhiping Ma
Shaoshun Wang
Yuxin Gu
Xiaofeng Lin
Wenjing Lin
Guobin Yi
Publication date: 11-07-2022
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 6/2022
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-022-00644-8

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