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Journal of Polymer Research
Published in: Journal of Polymer Research 10/2016

01-10-2016 | ORIGINAL PAPER

Preparation, morphological and thermal characterization of novel nanocomposites based on poly (amide-ester-imide) containing amino acid and nano-Mg-doped fluorapatite surface modified with biodegradable diacid N-trimellitylimido-L-leucine

Authors: Shadpour Mallakpour, Marziyeh Khani, Fereshteh Mallakpour, Mohammadhossein Fathi

Published in: Journal of Polymer Research | Issue 10/2016

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Abstract

In this investigation, we prepared novel nanocomposites (NC) s based on poly (amide-ester-imide) (PAEI) containing L-leucine moiety and surface modified nano-Mg-doped fluorapatite (Mod-MgFA) with biodegradable diacid, via ultrasound irradiation. First, surface of nanocystalline Mg-doped fluorapatite was functionalized with biodegradable optically active diacid N-trimellitylimido-L-leucine (TML) by ultrasonic irradiation, so as to increase the compatibility and dispersity in the PAEI matrix. After modification via diacid TML, the Mg-doped fluorapatite was altered from a hydrophilic state to an organophilic one. At that time, the obtained functionalized Mod-MgFA was investigated as reinforcing agent for the synthesis of the PAEI NCs. The resulting NCs were characterized by Fourier transform infrared (FT-IR), transmission electron microscopy, field emission-scanning electron microscopy (FE-SEM), X-ray diffraction, and thermogravimetric analysis (TGA) techniques. TGA data showed an increasing in thermal stability of the aforementioned NCs when compared to the neat PAEI. FE-SEM results presented a rather good amount of dispersion of Mod-MgFA in the polymer matrix.
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Metadata
Title
Preparation, morphological and thermal characterization of novel nanocomposites based on poly (amide-ester-imide) containing amino acid and nano-Mg-doped fluorapatite surface modified with biodegradable diacid N-trimellitylimido-L-leucine
Authors
Shadpour Mallakpour
Marziyeh Khani
Fereshteh Mallakpour
Mohammadhossein Fathi
Publication date
01-10-2016
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 10/2016
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-016-1107-1

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