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Cellulose
Published in: Cellulose 12/2017

16-10-2017 | Original Paper

Preparation of a cellulosic adsorbent by functionalization with pyridone diacid for removal of Pb(II) and Co(II) from aqueous solutions

Authors: Chang Sun, Jiadong Ni, Chunyan Zhao, Jinmei Du, Change Zhou, Shugen Wang, Changhai Xu

Published in: Cellulose | Issue 12/2017

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Abstract

A cellulosic adsorbent (PDA–MCC) was prepared by halogenation of microcrystalline cellulose (MCC) and functionalized with pyridone diacid (PDA) for removing lead and cobalt ions from aqueous solutions. PDA–MCC was characterized by Fourier transform infrared spectroscopy, scanning electron microscope, and thermal gravimetric analysis. The performance of PDA–MCC in removing lead and cobalt ions was examined by investigating the adsorption behaviors of lead and cobalt ions on PDA–MCC. Results from the adsorption of lead and cobalt ions on PDA–MCC showed that the adsorption kinetics followed the pseudo-second-order kinetic model, and the adsorption isotherms could be described by the Langmuir model. The maximum adsorption capacities of PDA–MCC towards lead and cobalt ions were determined to be 177.75 and 122.70 mg/g, respectively, which are greater than those of most reported cellulosic adsorbents. The reusable experiment showed that PDA–MCC could be regenerated in an acid solution, and had the adsorption capacities remained greater than 75% even after five cycles of regeneration.
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Metadata
Title
Preparation of a cellulosic adsorbent by functionalization with pyridone diacid for removal of Pb(II) and Co(II) from aqueous solutions
Authors
Chang Sun
Jiadong Ni
Chunyan Zhao
Jinmei Du
Change Zhou
Shugen Wang
Changhai Xu
Publication date
16-10-2017
Publisher
Springer Netherlands
Published in
Cellulose / Issue 12/2017
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-017-1519-z

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