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26-10-2021 | Original Research

Preparation of cationic cotton through reaction with different polyelectrolytes

Authors: Jeferson Correia, Fernando Ribeiro Oliveira, Rita de Cássia Siqueira Curto Valle, José Alexandre Borges Valle

Published in: Cellulose | Issue 18/2021

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Abstract

Cationization of cotton fabrics was performed by exhaustion procedure utilizing four different reagents provided with quaternary ammonium groups: poly diallyldimethylammonium chloride (PDDACl), poly acrylamide-co-diallyldimethylammonium chloride (PAcD), poly[bis(2-chloroethyl) ether-alt-1,3-bis[3-(dimethylamino)propyl]urea] quaternized (P42) and 3-chloro-2-hydroxypropyl trimethyl ammonium chloride (CHPTAC). Pretreated samples were dyed using Reactive Red 195 dye. The cationic fabrics were analyzed by colorimetric and fastness properties, zeta potential, SEM, FTIR and an estimate of the bactericidal effect. Cationic cotton treated with PDDACl and CHPTAC showed a higher affinity for the reactive dye, with color strength (K/S) values varying from 41 to 48, against 32 for conventional dyeing. P42 presented competitive results with K/S of 27–28. The cationic dyeing considerably reduced the amount of effluent, especially for the CHPTAC samples, which requires a single washing bath for complete removal of unfixed dye. The PDDACl and P42 samples presented bactericidal activity.

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Title: Preparation of cationic cotton through reaction with different polyelectrolytes
Authors: Jeferson Correia
Fernando Ribeiro Oliveira
Rita de Cássia Siqueira Curto Valle
José Alexandre Borges Valle
Publication date: 26-10-2021
Publisher: Springer Netherlands
Published in: Cellulose / Issue 18/2021
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04260-4

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