Skip to main content
Top
Published in: Journal of Polymer Research 2/2019

01-02-2019 | ORIGINAL PAPER

Preparation of diamine-based polybenzoxazine coating for corrosion protection on mild steel

Authors: Rui Zhang, Xin Lu, Chang Lou, Changlu Zhou, Zhong Xin

Published in: Journal of Polymer Research | Issue 2/2019

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The diamine-based polybenzoxazine (PpC-mda) coating was prepared on mild steel (MS) by spray coating and thermal curing method. The thermal curing process and thermal stability of PpC-mda were studied by differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA), respectively. The corrosion resistance properties of PpC-mda coating were investigated by electrochemical measurements. The results revealed that the hydrophobic PpC-mda coating exhibited high corrosion resistance on mild steel with the protection efficiency of 99.93%.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Döner A, Solmaz R, Özcan M, Kardaş G (2011) Experimental and theoretical studies of thiazoles as corrosion inhibitors for mild steel in sulphuric acid solution. Corros Sci 53:2902–2913CrossRef Döner A, Solmaz R, Özcan M, Kardaş G (2011) Experimental and theoretical studies of thiazoles as corrosion inhibitors for mild steel in sulphuric acid solution. Corros Sci 53:2902–2913CrossRef
2.
go back to reference Eddy NO, Ebenso EE (2010) Corrosion inhibition and adsorption characteristics of tarivid on mild steel in H2SO4. E-Journal of Chemistry 7:S442–S448CrossRef Eddy NO, Ebenso EE (2010) Corrosion inhibition and adsorption characteristics of tarivid on mild steel in H2SO4. E-Journal of Chemistry 7:S442–S448CrossRef
3.
go back to reference Palomino LEM, Suegama PH, Aoki IV, Pászti Z, de Melo HG (2007) Investigation of the corrosion behaviour of a bilayer cerium-silane pre-treatment on Al 2024-T3 in 0.1M NaCl. Electrochim Acta 52:7496–7505CrossRef Palomino LEM, Suegama PH, Aoki IV, Pászti Z, de Melo HG (2007) Investigation of the corrosion behaviour of a bilayer cerium-silane pre-treatment on Al 2024-T3 in 0.1M NaCl. Electrochim Acta 52:7496–7505CrossRef
4.
go back to reference Behzadnasab M, Mirabedini SM, Kabiri K, Jamali S (2011) Corrosion performance of epoxy coatings containing silane treated ZrO2 nanoparticles on mild steel in 3.5% NaCl solution. Corros Sci 53:89–98CrossRef Behzadnasab M, Mirabedini SM, Kabiri K, Jamali S (2011) Corrosion performance of epoxy coatings containing silane treated ZrO2 nanoparticles on mild steel in 3.5% NaCl solution. Corros Sci 53:89–98CrossRef
5.
go back to reference Saravanan K, Sathiyanarayanan S, Muralidharan S, Azim SS, Venkatachari G (2007) Performance evaluation of polyaniline pigmented epoxy coating for corrosion protection of steel in concrete environment. Progress in Organic Coatings 59:160–167CrossRef Saravanan K, Sathiyanarayanan S, Muralidharan S, Azim SS, Venkatachari G (2007) Performance evaluation of polyaniline pigmented epoxy coating for corrosion protection of steel in concrete environment. Progress in Organic Coatings 59:160–167CrossRef
6.
go back to reference Brostow W, Dutta M, Rusek P (2010) Modified epoxy coatings on mild steel: tribology and surface energy. Eur Polym J 46:2181–2189CrossRef Brostow W, Dutta M, Rusek P (2010) Modified epoxy coatings on mild steel: tribology and surface energy. Eur Polym J 46:2181–2189CrossRef
7.
go back to reference Amoozadeh SM, Mahdavian M (2015) Synergistic inhibition effect of zinc acetylacetonate and benzothiazole in epoxy coating on the corrosion of mild steel. J Mater Eng Perform 24:2464–2472CrossRef Amoozadeh SM, Mahdavian M (2015) Synergistic inhibition effect of zinc acetylacetonate and benzothiazole in epoxy coating on the corrosion of mild steel. J Mater Eng Perform 24:2464–2472CrossRef
8.
go back to reference González-García Y, González S, Souto RM (2007) Electrochemical and structural properties of a polyurethane coating on steel substrates for corrosion protection. Corros Sci 49:3514–3526CrossRef González-García Y, González S, Souto RM (2007) Electrochemical and structural properties of a polyurethane coating on steel substrates for corrosion protection. Corros Sci 49:3514–3526CrossRef
9.
go back to reference Palimi MJ, Rostami M, Mahdavian M, Ramezanzadeh B (2015) A study on the corrosion inhibition properties of silane-modified Fe2O3 nanoparticle on mild steel and its effect on the anticorrosion properties of the polyurethane coating. J Coat Technol Res 12:277–292CrossRef Palimi MJ, Rostami M, Mahdavian M, Ramezanzadeh B (2015) A study on the corrosion inhibition properties of silane-modified Fe2O3 nanoparticle on mild steel and its effect on the anticorrosion properties of the polyurethane coating. J Coat Technol Res 12:277–292CrossRef
10.
go back to reference Barletta M, Venettacci S, Puopolo M, Vesco S, Gisario A (2014) Design and manufacturing of protective barriers on Fe 430 B substrates by phenyl methyl polysiloxane coatings: micromechanical response, chemical inertness, and corrosion resistance. J Coat Technol Res 12:333–346CrossRef Barletta M, Venettacci S, Puopolo M, Vesco S, Gisario A (2014) Design and manufacturing of protective barriers on Fe 430 B substrates by phenyl methyl polysiloxane coatings: micromechanical response, chemical inertness, and corrosion resistance. J Coat Technol Res 12:333–346CrossRef
11.
go back to reference Matin E, Attar MM, Ramezanzadeh B (2015) Investigation of corrosion protection properties of an epoxy nanocomposite loaded with polysiloxane surface modified nanosilica particles on the steel substrate. Progress in Organic Coatings 78:395–403CrossRef Matin E, Attar MM, Ramezanzadeh B (2015) Investigation of corrosion protection properties of an epoxy nanocomposite loaded with polysiloxane surface modified nanosilica particles on the steel substrate. Progress in Organic Coatings 78:395–403CrossRef
12.
go back to reference Wang CF, Chen HY, Kuo SW, Lai YS, Yang P-F (2013) Rapid, low temperature microwave synthesis of durable, superhydrophobic carbon nanotube–polybenzoxazine nanocomposites. RSC Adv 3:9764CrossRef Wang CF, Chen HY, Kuo SW, Lai YS, Yang P-F (2013) Rapid, low temperature microwave synthesis of durable, superhydrophobic carbon nanotube–polybenzoxazine nanocomposites. RSC Adv 3:9764CrossRef
13.
go back to reference Liu J, Lu X, Xin Z, Zhou CL (2013) Synthesis and surface properties of low surface free energy silane-functional polybenzoxazine films. Langmuir 29:411–416CrossRef Liu J, Lu X, Xin Z, Zhou CL (2013) Synthesis and surface properties of low surface free energy silane-functional polybenzoxazine films. Langmuir 29:411–416CrossRef
14.
go back to reference Tseng MC, Liu YL (2010) Preparation, morphology, and ultra-low dielectric constants of benzoxazine-based polymers/polyhedral oligomeric silsesquioxane (POSS) nanocomposites. Polymer 51:5567–5575CrossRef Tseng MC, Liu YL (2010) Preparation, morphology, and ultra-low dielectric constants of benzoxazine-based polymers/polyhedral oligomeric silsesquioxane (POSS) nanocomposites. Polymer 51:5567–5575CrossRef
15.
go back to reference Zhou CL, Lu X, Xin Z, Liu J (2013) Corrosion resistance of novel silane-functional polybenzoxazine coating on steel. Corros Sci 70:145–151CrossRef Zhou CL, Lu X, Xin Z, Liu J (2013) Corrosion resistance of novel silane-functional polybenzoxazine coating on steel. Corros Sci 70:145–151CrossRef
16.
go back to reference Escobar J, Poorteman M, Dumas L, Bonnaud L, Dubois P, Olivier MG (2015) Thermal curing study of bisphenol a benzoxazine for barrier coating applications on 1050 aluminum alloy. Progress in Organic Coatings 79:53–61CrossRef Escobar J, Poorteman M, Dumas L, Bonnaud L, Dubois P, Olivier MG (2015) Thermal curing study of bisphenol a benzoxazine for barrier coating applications on 1050 aluminum alloy. Progress in Organic Coatings 79:53–61CrossRef
17.
go back to reference Raicopol M, Bălănucă B, Sliozberg K, Schlüter B, Gârea SA, Chira N, Schuhmann W, Andronescu C (2015) Vegetable oil-based polybenzoxazine derivatives coatings on Zn–mg–Al alloy coated steel. Corros Sci 100:386–395CrossRef Raicopol M, Bălănucă B, Sliozberg K, Schlüter B, Gârea SA, Chira N, Schuhmann W, Andronescu C (2015) Vegetable oil-based polybenzoxazine derivatives coatings on Zn–mg–Al alloy coated steel. Corros Sci 100:386–395CrossRef
18.
go back to reference Patil DM, Phalak GA, Mhaske ST (2017) Enhancement of anti-corrosive performances of cardanol based amine functional benzoxazine resin by copolymerizing with epoxy resins. Progress in Organic Coatings 105:18–28CrossRef Patil DM, Phalak GA, Mhaske ST (2017) Enhancement of anti-corrosive performances of cardanol based amine functional benzoxazine resin by copolymerizing with epoxy resins. Progress in Organic Coatings 105:18–28CrossRef
19.
go back to reference Patil DM, Phalak GA, Mhaske ST (2017) Synthesis and characterization of bio-based benzoxazine oligomer from cardanol for corrosion resistance application. J Coat Technol Res 14:517–530CrossRef Patil DM, Phalak GA, Mhaske ST (2017) Synthesis and characterization of bio-based benzoxazine oligomer from cardanol for corrosion resistance application. J Coat Technol Res 14:517–530CrossRef
20.
go back to reference Lu X, Liu Y, Zhang WF, Zhang XY, Zhou CL, Xin Z (2017) Crosslinked main-chain-type polybenzoxazine coatings for corrosion protection of mild steel. J Coat Technol Res 14:937–944CrossRef Lu X, Liu Y, Zhang WF, Zhang XY, Zhou CL, Xin Z (2017) Crosslinked main-chain-type polybenzoxazine coatings for corrosion protection of mild steel. J Coat Technol Res 14:937–944CrossRef
21.
go back to reference Men W, Lu Z (2007) Synthesis and characterization of 4,4′-diaminodiphenyl methane-based benzoxazines and their polymers. J Appl Polym Sci 106:2769–2774CrossRef Men W, Lu Z (2007) Synthesis and characterization of 4,4′-diaminodiphenyl methane-based benzoxazines and their polymers. J Appl Polym Sci 106:2769–2774CrossRef
22.
go back to reference Liu Y, Li Z, Zhang J, Zhang H, Fan H, Run M (2012) Polymerization behavior and thermal properties of benzoxazine based on 4,4′-diaminodiphenyl ether. J Therm Anal Calorim 111:1523–1530CrossRef Liu Y, Li Z, Zhang J, Zhang H, Fan H, Run M (2012) Polymerization behavior and thermal properties of benzoxazine based on 4,4′-diaminodiphenyl ether. J Therm Anal Calorim 111:1523–1530CrossRef
23.
go back to reference Liu Y, Liao C, Hao Z, Luo X, Jing S, Run M (2014) The polymerization behavior and thermal properties of benzoxazine based on o-allylphenol and 4,4′-diaminodiphenyl methane. React Funct Polym 75:9–15CrossRef Liu Y, Liao C, Hao Z, Luo X, Jing S, Run M (2014) The polymerization behavior and thermal properties of benzoxazine based on o-allylphenol and 4,4′-diaminodiphenyl methane. React Funct Polym 75:9–15CrossRef
24.
go back to reference Poorteman M, Renaud A, Escobar J, Dumas L, Bonnaud L, Dubois P, Olivier MG (2016) Thermal curing of Para-phenylenediamine benzoxazine for barrier coating applications on 1050 aluminum alloys. Progress in Organic Coatings 97:99–109CrossRef Poorteman M, Renaud A, Escobar J, Dumas L, Bonnaud L, Dubois P, Olivier MG (2016) Thermal curing of Para-phenylenediamine benzoxazine for barrier coating applications on 1050 aluminum alloys. Progress in Organic Coatings 97:99–109CrossRef
25.
go back to reference Bălănucă B, Raicopol M, Maljusch A, Garea S, Hanganu A, Schuhmann W, Andronescu C (2015) Phenolated oleic acid based polybenzoxazine derivatives as corrosion protection layers. ChemPlusChem 80:1170–1177CrossRef Bălănucă B, Raicopol M, Maljusch A, Garea S, Hanganu A, Schuhmann W, Andronescu C (2015) Phenolated oleic acid based polybenzoxazine derivatives as corrosion protection layers. ChemPlusChem 80:1170–1177CrossRef
26.
go back to reference Zhou CL, Lin JP, Lu X, Xin Z (2016) Enhanced corrosion resistance of polybenzoxazine coatings by epoxy incorporation. RSC Adv 6:28428–28434CrossRef Zhou CL, Lin JP, Lu X, Xin Z (2016) Enhanced corrosion resistance of polybenzoxazine coatings by epoxy incorporation. RSC Adv 6:28428–28434CrossRef
27.
go back to reference Cal E, Maffezzoli A, Mele G, Martina F, Mazzetto SE, Tarzia A, Stifani C (2007) Synthesis of a novel cardanol-based benzoxazine monomer and environmentally sustainable production of polymers and bio-composites. Green Chem 9:754CrossRef Cal E, Maffezzoli A, Mele G, Martina F, Mazzetto SE, Tarzia A, Stifani C (2007) Synthesis of a novel cardanol-based benzoxazine monomer and environmentally sustainable production of polymers and bio-composites. Green Chem 9:754CrossRef
28.
go back to reference Altinkok C, Kiskan B, Yagci Y (2011) Synthesis and characterization of sulfone containing main chain oligobenzoxazine precursors. J Polym Sci A Polym Chem 49:2445–2450CrossRef Altinkok C, Kiskan B, Yagci Y (2011) Synthesis and characterization of sulfone containing main chain oligobenzoxazine precursors. J Polym Sci A Polym Chem 49:2445–2450CrossRef
29.
go back to reference Zúñiga C, Larrechi MS, Lligadas G, Ronda JC, Galià M, Cádiz V (2011) Polybenzoxazines from renewable diphenolic acid. J Polym Sci A Polym Chem 49:1219–1227CrossRef Zúñiga C, Larrechi MS, Lligadas G, Ronda JC, Galià M, Cádiz V (2011) Polybenzoxazines from renewable diphenolic acid. J Polym Sci A Polym Chem 49:1219–1227CrossRef
30.
go back to reference Aydogan C, Kiskan B, Hacioglu SO, Toppare L, Yagci Y (2014) Electrochemical manipulation of adhesion strength of polybenzoxazines on metal surfaces: from strong adhesion to dismantling. RSC Adv 4:27545CrossRef Aydogan C, Kiskan B, Hacioglu SO, Toppare L, Yagci Y (2014) Electrochemical manipulation of adhesion strength of polybenzoxazines on metal surfaces: from strong adhesion to dismantling. RSC Adv 4:27545CrossRef
31.
go back to reference Low HY, Ishida H (1998) Mechanistic study on the thermal decomposition of polybenzoxazines: effects of aliphatic amines. Journal of Polymer Science Part B Polymer Physics 36:1935–1946CrossRef Low HY, Ishida H (1998) Mechanistic study on the thermal decomposition of polybenzoxazines: effects of aliphatic amines. Journal of Polymer Science Part B Polymer Physics 36:1935–1946CrossRef
32.
go back to reference Lu X, Liu Y, Zhou CL, Zhang WF, Xin Z (2016) Corrosion protection of hydrophobic bisphenol A-based polybenzoxazine coatings on mild steel. RSC Adv 6:5805–5811CrossRef Lu X, Liu Y, Zhou CL, Zhang WF, Xin Z (2016) Corrosion protection of hydrophobic bisphenol A-based polybenzoxazine coatings on mild steel. RSC Adv 6:5805–5811CrossRef
33.
go back to reference Radhakrishnan S, Siju CR, Mahanta D, Patil S, Madras G (2009) Conducting polyaniline–nano-TiO2 composites for smart corrosion resistant coatings. Electrochim Acta 54:1249–1254CrossRef Radhakrishnan S, Siju CR, Mahanta D, Patil S, Madras G (2009) Conducting polyaniline–nano-TiO2 composites for smart corrosion resistant coatings. Electrochim Acta 54:1249–1254CrossRef
34.
go back to reference Wang P, Zhang D, Lu Z (2015) Advantage of super-hydrophobic surface as a barrier against atmospheric corrosion induced by salt deliquescence. Corros Sci 90:23–32CrossRef Wang P, Zhang D, Lu Z (2015) Advantage of super-hydrophobic surface as a barrier against atmospheric corrosion induced by salt deliquescence. Corros Sci 90:23–32CrossRef
35.
go back to reference Amirudin A, Thieny D (1995) Application of electrochemical impedance spectroscopy to study the degradation of polymer-coated metals. Progress in Organic Coatings 26:1–28CrossRef Amirudin A, Thieny D (1995) Application of electrochemical impedance spectroscopy to study the degradation of polymer-coated metals. Progress in Organic Coatings 26:1–28CrossRef
36.
go back to reference Mcintyre JM, Pham HQ (1996) Electrochemical impedance spectroscopy; a tool for organic coatings optimizations. Progress in Organic Coatings 27:201–207CrossRef Mcintyre JM, Pham HQ (1996) Electrochemical impedance spectroscopy; a tool for organic coatings optimizations. Progress in Organic Coatings 27:201–207CrossRef
37.
go back to reference Kannan MB, Gomes D, Dietzel W, Abetz V (2008) Polyoxadiazole-based coating for corrosion protection of magnesium alloy. Surf Coat Technol 202:4598–4601CrossRef Kannan MB, Gomes D, Dietzel W, Abetz V (2008) Polyoxadiazole-based coating for corrosion protection of magnesium alloy. Surf Coat Technol 202:4598–4601CrossRef
38.
go back to reference Qian M, McIntosh Soutar A, Tan XH, Zeng XT, Wijesinghe SL (2009) Two-part epoxy-siloxane hybrid corrosion protection coatings for carbon steel. Thin Solid Films 517:5237–5242CrossRef Qian M, McIntosh Soutar A, Tan XH, Zeng XT, Wijesinghe SL (2009) Two-part epoxy-siloxane hybrid corrosion protection coatings for carbon steel. Thin Solid Films 517:5237–5242CrossRef
39.
go back to reference Zuo Y, Pang R, Li W, Xiong JP, Tang YM (2008) The evaluation of coating performance by the variations of phase angles in middle and high frequency domains of EIS. Corros Sci 50:3322–3328CrossRef Zuo Y, Pang R, Li W, Xiong JP, Tang YM (2008) The evaluation of coating performance by the variations of phase angles in middle and high frequency domains of EIS. Corros Sci 50:3322–3328CrossRef
40.
go back to reference Li Y, Yang Z, Qiu H, Dai Y, Zheng Q, Li J, Yang J (2014) Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings. J Mater Chem A 2:14139CrossRef Li Y, Yang Z, Qiu H, Dai Y, Zheng Q, Li J, Yang J (2014) Self-aligned graphene as anticorrosive barrier in waterborne polyurethane composite coatings. J Mater Chem A 2:14139CrossRef
41.
go back to reference Mahdavian M, Attar MM (2006) Another approach in analysis of paint coatings with EIS measurement: phase angle at high frequencies. Corros Sci 48:4152–4157CrossRef Mahdavian M, Attar MM (2006) Another approach in analysis of paint coatings with EIS measurement: phase angle at high frequencies. Corros Sci 48:4152–4157CrossRef
42.
go back to reference Liu JG, Gong GP, Yan CW (2005) EIS study of corrosion behaviour of organic coating/Dacromet composite systems. Electrochim Acta 50:3320–3332CrossRef Liu JG, Gong GP, Yan CW (2005) EIS study of corrosion behaviour of organic coating/Dacromet composite systems. Electrochim Acta 50:3320–3332CrossRef
43.
go back to reference Liu X, Xiong J, Lv Y, Zuo Y (2009) Study on corrosion electrochemical behavior of several different coating systems by EIS. Progress in Organic Coatings 64:497–503CrossRef Liu X, Xiong J, Lv Y, Zuo Y (2009) Study on corrosion electrochemical behavior of several different coating systems by EIS. Progress in Organic Coatings 64:497–503CrossRef
44.
go back to reference T.C. Huang, Y.A. Su, T.C. Yeh, H.Y. Huang, C.P. Wu, K.Y. Huang, Y.C. Chou, J.M. Yeh, Y. Wei, Advanced anticorrosive coatings prepared from electroactive epoxy–SiO2 hybrid nanocomposite materials, Electrochim Acta, 56 (2011) 6142–6149 T.C. Huang, Y.A. Su, T.C. Yeh, H.Y. Huang, C.P. Wu, K.Y. Huang, Y.C. Chou, J.M. Yeh, Y. Wei, Advanced anticorrosive coatings prepared from electroactive epoxy–SiO2 hybrid nanocomposite materials, Electrochim Acta, 56 (2011) 6142–6149
Metadata
Title
Preparation of diamine-based polybenzoxazine coating for corrosion protection on mild steel
Authors
Rui Zhang
Xin Lu
Chang Lou
Changlu Zhou
Zhong Xin
Publication date
01-02-2019
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 2/2019
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-018-1683-3

Other articles of this Issue 2/2019

Journal of Polymer Research 2/2019 Go to the issue

Premium Partners