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Colloid and Polymer Science
Published in: Colloid and Polymer Science 5/2017

30-03-2017 | Original Contribution

Preparation of H2O2-induced poly (amidoamine) dendrimer-release multilayer films

Authors: Katsuhiko Sato, Kazuma Awaji, Megumi Ito, Jun-ichi Anzai

Published in: Colloid and Polymer Science | Issue 5/2017

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Abstract

Poly (amidoamine) (PAMAM) dendrimer-release multilayer films were prepared using phenylboronic acid-modified PAMAM dendrimers (PBA-D) and poly (vinyl alcohol) (PVA) through boronate ester bonds. The (PBA-D/PVA)10 film was stable in pH 9.0 solution. Upon addition of H2O2, PAMAM dendrimers were released from the (PBA-D/PVA)10 film due to oxidative scission of the carbon-boron bond in the PBA residues in PBA-D. For example, 75 and 90% of the PBA-D was released from the (PBA-D/PVA)10 film within 30 min of exposure to 0.5 and 1 mM H2O2, respectively. In addition, (PBA-D/PVA)10 films containing glucose oxidase responded to the presence of 1 mM glucose in pH 7.4 solution due to the enzymatic production of H2O2.
previous article Counterion-specific clouding in aqueous anionic surfactant: a case of Hofmeister-like series
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Metadata
Title
Preparation of H2O2-induced poly (amidoamine) dendrimer-release multilayer films
Authors
Katsuhiko Sato
Kazuma Awaji
Megumi Ito
Jun-ichi Anzai
Publication date
30-03-2017
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 5/2017
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-017-4073-1

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