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2017 | OriginalPaper | Chapter

Pyrolysis of Low-Density Polyethylene

Authors : Giorgio Zattini, Chiara Leonardi, Laura Mazzocchetti, Massimo Cavazzoni, Ivan Montanari, Cristian Tosi, Tiziana Benelli, Loris Giorgini

Published in: Sustainable Design and Manufacturing 2017

Publisher: Springer International Publishing

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Abstract

Pyrolysis of low-density polyethylene in an innovative batch pilot plant, with a hydraulic guard ensuring a safe process, was performed. The influence of process temperature on yield, distribution and composition of products was investigated. The oil/waxes were analyzed by gas chromatography coupled mass spectrometry, while pyrolysis gas was monitored online during the process by micro-gas chromatography. Pyrolysis were carried out at 450, 500, 550 and 600 °C. Results obtained show that low temperatures yield a greater amount of oil/waxes, and a gas enriched in carbon oxides and C3+ hydrocarbons. At higher temperatures, the gas fraction, riche in methane and hydrogen, is predominant over liquid products. This process has proved to be a versatile way to recover polyethylene wastes into valuable oils (rich in aliphatic and simple aromatic hydrocarbons) or gas, to be used as petrochemical feedstock or fuel, thus providing a sustainable method for material and energy recovery of waste packaging.

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Metadata
Title
Pyrolysis of Low-Density Polyethylene
Authors
Giorgio Zattini
Chiara Leonardi
Laura Mazzocchetti
Massimo Cavazzoni
Ivan Montanari
Cristian Tosi
Tiziana Benelli
Loris Giorgini
Copyright Year
2017
DOI
https://doi.org/10.1007/978-3-319-57078-5_46

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