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Published in: Journal of Materials Science 14/2021

09-02-2021 | Chemical routes to materials

Quaternary ammonium cellulose promoted synthesis of hollow nano-sized ZSM-5 zeolite as stable catalyst for benzene alkylation with ethanol

Authors: Pengfei Nie, Xuguang Liu, Pingping Zhang, Xun Yuan, Xia Li, Sen Lin, Zhengmao Yin, Zhiyi Wang

Published in: Journal of Materials Science | Issue 14/2021

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Abstract

Catalytic alkylation of benzene with ethanol has been considered as a sustainable alternative for producing ethylbenzene/diethylbenzene. This paper reports the promoted synthesis of hollow nano-sized (20–80 nm) ZSM-5 zeolite as excellent yet durable catalyst of benzene alkylation, which is achieved by adding N-methyl-2-pyrrolidone (NMP) and quaternary ammonium cationic hydroxyethyl cellulose (JR-400) in its synthesis gel during the synthesis. It is revealed by the ESI–MS and TEM characterization that the NMP promotes the dissolution–recrystallization of the ZSM-5 and a hollow structure is generated during the process. The JR-400 as special promoter further favors the formation of ordered nano-zeolite grain and suitable microstructure, confirmed by the molecular dynamic modeling and characterization. That action corporately contributed to the hollow nano-sized ZSM-5 zeolite that provided hierarchical porous structure and mild acid centers, as evidenced by the 129Xe and 1H NMR spectra. The obtained hollow zeolite ZSM-5 then exhibits enhanced catalytic activities and selectivity for benzene alkylation. Moreover, it also displays an extremely superior stability (deactivation rate constant, −0.06%/h) in the catalysis of benzene alkylation with ethanol. This behavior is attributed to its hierarchical porous structure (namely less diffusion resistance) and mild acid centers, which is beneficial to moderate the carbon deposition and then the catalyst deactivation. Those research results urge the JR-400-promoted synthesis as a facile strategy for the hollow nano-sized ZSM-5 with enhanced catalytic performance during the benzene alkylation with the ethanol.

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Appendix
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Metadata
Title
Quaternary ammonium cellulose promoted synthesis of hollow nano-sized ZSM-5 zeolite as stable catalyst for benzene alkylation with ethanol
Authors
Pengfei Nie
Xuguang Liu
Pingping Zhang
Xun Yuan
Xia Li
Sen Lin
Zhengmao Yin
Zhiyi Wang
Publication date
09-02-2021
Publisher
Springer US
Published in
Journal of Materials Science / Issue 14/2021
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-021-05856-8

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