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Colloid and Polymer Science

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16-07-2019 | Original Contribution

RAFT synthesized poly-N-vinylsuccinimide macromolecules: properties in dilute solutions

Authors: G. M. Pavlov, O. V. Okatova, A. A. Gosteva, A. S. Gubarev, A. I. Gostev, E.V. Sivtsov

Published in: Colloid and Polymer Science | Issue 9/2019

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Abstract

A complex study of the properties of poly-N-vinylsuccinimides synthesized by the reversible addition-fragmentation chain transfer polymerization (RAFT) was carried out by the methods of molecular hydrodynamics. Molecular masses were determined from the sedimentation-diffusion analysis, the range was 5000 < M, g/mol < 68000. Scaling relationships of hydrodynamic characteristics with molecular mass were established, and the conformational characteristics of molecular chains of poly-N-vinylsuccinimides were estimated. The value of the statistical segment, determined from the data on translational and rotational friction, was (2.7 ± 0.1) nm. The polydispersity of several samples was evaluated from the results on velocity sedimentation.

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Title: RAFT synthesized poly-N-vinylsuccinimide macromolecules: properties in dilute solutions
Authors: G. M. Pavlov
O. V. Okatova
A. A. Gosteva
A. S. Gubarev
A. I. Gostev
E.V. Sivtsov
Publication date: 16-07-2019
Publisher: Springer Berlin Heidelberg
Published in: Colloid and Polymer Science / Issue 9/2019
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-019-04540-3

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