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Published in: Journal of Material Cycles and Waste Management 5/2020

14-05-2020 | ORIGINAL ARTICLE

Recovery of fluoride from water through adsorption using orange-waste gel, followed by desorption using saturated lime water

Authors: Hari Paudyal, Keisuke Ohto, Hidetaka Kawakita, Katsutoshi Inoue

Published in: Journal of Material Cycles and Waste Management | Issue 5/2020

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Abstract

In this study, a new process for the recovery of fluoride from water with orange-waste gel loaded with Zr(IV) is investigated using saturated Ca(OH)2 as the desorption agent to desorb fluoride from a fluoride-loaded adsorbent. The maximum adsorption capacities of Zr(IV)-loaded orange-waste gel at pH values of 2.5, 3, 4, 6, and 8 were found to be 1.23, 1.52, 1.74, 1.10, and 0.53 mmol/g, respectively. The white precipitate obtained after the desorption using saturated Ca(OH)2 solution was characterized by scanning electron microscopy, X-ray diffraction, and dynamic light scattering techniques. The leakage of the total organic carbon during the desorption using Ca(OH)2 (7.31 mg/L) was found to be considerably less than that using NaOH (71.48 mg/L) at a solid/liquid ratio of 5 g/L. It is considered that fluoride was first desorbed by the saturated Ca(OH)2 solution, after which it combined with the Ca(II) ions provided by lime water to form a CaF2 precipitate, which is a raw material employed in various industrial processes, including cement manufacturing. Therefore, the saturated Ca(OH)2 solution investigated in this study can be considered as an efficient, economically viable, and promising desorbent for the removal of fluoride from fluoride-loaded adsorbents in an aqueous solution.

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Metadata
Title
Recovery of fluoride from water through adsorption using orange-waste gel, followed by desorption using saturated lime water
Authors
Hari Paudyal
Keisuke Ohto
Hidetaka Kawakita
Katsutoshi Inoue
Publication date
14-05-2020
Publisher
Springer Japan
Published in
Journal of Material Cycles and Waste Management / Issue 5/2020
Print ISSN: 1438-4957
Electronic ISSN: 1611-8227
DOI
https://doi.org/10.1007/s10163-020-01042-1

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