Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Adsorption
Published in: Adsorption 1-2/2015

01-02-2015

Selective adsorption of ethylene over ethane on natural mordenite and on K+-exchanged mordenite

Authors: D. Vargas-Hernández, M. A. Pérez-Cruz, R. Hernández-Huesca

Published in: Adsorption | Issue 1-2/2015

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Pure-component adsorption equilibrium and kinetics of ethylene (C2H4) and ethane (C2H6) on natural mordenite (ZNT) from Tamaulipas, Mexico, and on cation-exchanged mordenite samples (1.5 K-ZNT and 1.8 K-ZNT) were measured at 0, 20, 60, and 100 °C using a glass high-vacuum volumetric system. The measured data were analyzed using the Dual Langmuir model. All of the samples showed selectivity toward ethylene. The adsorbed amounts of ethane and ethylene on the 1.5 K-ZNT and 1.8 K-ZNT samples were lower than those on ZNT; this result can be due to a decrease in micropore volume because of the presence of the K+ cations in the cation-exchanged samples. It was established that the adsorptive separation of these gases on ZNT can be effected most efficiently at 100 °C, whereas the use of 1.8 K-ZNT could be recommended at ambient temperature.
previous article Recovery of p-nitrotoluene by selective adsorption using MFI type zeolites

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
Aguilar-Armenta, G., Patiño-Iglesias, M.E.: Adsorption equilibria and kinetics of propylene and propane on natural erionite and on erionite exchanged with K+ and Ag+. Langmuir 18(20), 7456–7461 (2002)CrossRef
Albesa, A.G., Rafti, M., Rawat, D.S., Vicente, J.L., Migone, A.D.: Ethane/ethylene adsorption on carbon nanotubes: temperature and size effects on separation capacity. Langmuir 28(3), 1824–1832 (2011)CrossRef
Anson, A., Lin, C.C.H., Kuznicki, T.M., Kuznicki, S.M.: Separation of ethylene/ethane mixtures by adsorption on small-pored titanosilicate molecular sieves. Chem. Eng. Sci. 65(2), 807–811 (2010)CrossRef
Anson, A., Wang, Y., Lin, C.C.H., Kuznicki, T.M., Kuznicki, S.M.: Adsorption of ethane and ethylene on modified ETS-10. Chem. Eng. Sci. 63(16), 4171–4175 (2008)CrossRef
Babarao, R., Hu, Z.Q., Jiang, J.W., Chempath, S., Sandler, S.I.: Storage and separation of CO2 and CH4 in silicalite, C168 schwarzite, and IRMOF-1: a comparative study from Monte Carlo simulation. Langmuir 23(2), 659–666 (2007)CrossRef
Barrer R.M. In: Molecular Sieves Zeolites, Adv. Chem. Ser. 102, American Chemical Society, Washington, DC (1971).
Basaldella, E.I., Tara, J.C., Armenta, G.A., Patiño-Iglesias, M.E., Castellón, E.R.: Propane/propylene separation by selective olefin adsorption on Cu/SBA-15 mesoporous silica. J. Sol-Gel. Sci. Technol. 37(2), 141–146 (2006)CrossRef
Basaldella, E.I., Vázquez, P.G., Firpo, N.: Synthesis of Ag/SBA-15 as adsorbent for propane/propylene separation. In Studies in Surface Science and Catalysis, edited by N. Ž. a. P. N. J. Čejka: Elsevier, 1081–1088 (2005)
Berlier, K., Olivier, M.G., Jadot, R.: Adsorption of methane, ethane, and ethylene on zeolite. J. Chem. Eng. Data 40(6), 1206–1208 (1995)CrossRef
Blas, F.J., Vega, L.F., Gubbins, K.E.: Modeling new adsorbents for ethylene/ethane separations by adsorption via π-complexation. Fluid Phase Equilib. 150, 117–124 (1998a)CrossRef
Blas, F.J., Vega, L.F., Gubbins, K.E.: Modeling new adsorbents for ethylene/ethane separations by adsorption via π-complexation. Fluid Phase Equilib. 150–151, 117–124 (1998b)CrossRef
Brandani, S., Hufton, J., Ruthven, D.: Self-diffusion of propane and propylene in 5A and 13X zeolite crystals studied by the tracer ZLC method. Zeolites 15(7), 624–631 (1995)CrossRef
Breck, D.W.: Zeolite Molecular Sieves. Wiley, New York (1974)
Cheng, L., Yang, R.: Monolayer cuprous chloride dispersed on pillared clays for olefin-paraffin separations by π-complexation. Adsorption 1(1), 61–75 (1995)CrossRef
Chmelik, C., Freude, D., Bux, H., Haase, J.: Ethene/ethane mixture diffusion in the MOF sieve ZIF-8 studied by MAS PFG NMR diffusometry. Microporous Mesoporous Mater. 147(1), 135–141 (2012)CrossRef
Choi, B.-U., Choi, D.-K., Lee, Y.-W., Lee, B.-K., Kim, S.-H.: Adsorption equilibria of methane, ethane, ethylene, nitrogen, and hydrogen onto activated carbon. J. Chem. Eng. Data 48(3), 603–607 (2003)CrossRef
Choudary, N.V., Kumar, P., Bhat, T.S.G., Cho, S.H., Han, S.S., Kim, J.N.: Adsorption of light hydrocarbon gases on alkene-selective adsorbent. Ind. Eng. Chem. Res. 41(11), 2728–2734 (2002)CrossRef
Chudasama, C.D., Sebastian, J., Jasra, R.V.: Pore-size engineering of zeolite A for the size/shape selective molecular separation. Ind. Eng. Chem. Res. 44(6), 1780–1786 (2005)CrossRef
Costa, E., Calleja, G., Marron, C., Jimenez, A., Pau, J.: Equilibrium adsorption of methane, ethane, ethylene, and propylene and their mixtures on activated carbon. J. Chem. Eng. Data 34(2), 156–160 (1989)CrossRef
Da Silva, F.A., Rodrigues, A.E.: Adsorption equilibria and kinetics for propylene and propane over 13X and 4A zeolite pellets. Ind. Eng. Chem. Res. 38(5), 2051–2057 (1999)CrossRef
Da Silva, F.A., Rodrigues, A.E.: Vacuum swing adsorption for propylene/propane separation with 4A zeolite. Ind. Eng. Chem. Res. 40(24), 5758–5774 (2001)CrossRef
Dewitt, A.C., Herwig, K.W., Lombardo, S.: Adsorption and diffusion behavior of ethane and ethylene in sol-gel derived microporous silica. Adsorption 11(5–6), 491–499 (2005)CrossRef
Do, D.: Adsorption Analysis: Equilibria and Kinetics. Series on Chemical Engineering, vol. 2. Imperial College Press, London (1998)
Eldridge, R.B.: Olefin/paraffin separation technology: a review. Ind. Eng. Chem. Res. 32(10), 2208–2212 (1993)CrossRef
Fuertes, A.B., Menendez, I.: Separation of hydrocarbon gas mixtures using phenolic resin-based carbon membranes. Sep. Purif. Technol. 28(1), 29–41 (2002)CrossRef
Giannakopoulos, I.G., Nikolakis, V.: Separation of propylene/propane mixtures using faujasite-type zeolite membranes. Ind. Eng. Chem. Res. 44(1), 226–230 (2004)CrossRef
Gilliland, E.R., Bliss, H.L., Kip, C.E.: Reaction of olefins with solid cuprous halides. J. Am. Chem. Soc. 63(8), 2088–2090 (1941)CrossRef
Gilliland, E.R., Seebold, J.E., FitzHugh, J.R., Morgan, P.S.: Reaction of olefins with solid cuprous halides. J. Am. Chem. Soc. 61(8), 1960–1962 (1939)CrossRef
Grande, C.A., Araujo, J.D.P., Cavenati, S., Firpo, N., BASALDELLA, E., Rodrigues, A.E.: New π-complexation adsorbents for propane–propylene separation. Langmuir 20(13), 5291–5297 (2004)CrossRef
Grande, C.A., Cavenati, S., Barcia, P., Hammer, J., Fritz, H.G., Rodrigues, A.E.: Adsorption of propane and propylene in zeolite 4A honeycomb monolith. Chem. Eng. Sci. 61(10), 3053–3067 (2006)CrossRef
Grande, C.A., Gascon, J., Kapteijn, F., Rodrigues, A.E.: Propane/propylene separation with Li-exchanged zeolite 13X. Chem. Eng. J. 160(1), 207–214 (2010)CrossRef
Grande, C.A., Gigola, C., Rodrigues, A.E.: Adsorption of propane and propylene in pellets and crystals of 5A zeolite. Ind. Eng. Chem. Res. 41(1), 85–92 (2001)CrossRef
Grande, C.A., Rodrigues, A.E.: Adsorption of binary mixtures of propane–propylene in carbon molecular sieve 4A. Ind. Eng. Chem. Res. 43(25), 8057–8065 (2004)CrossRef
Grande, C.A., Rodrigues, A.E.: Propane/propylene separation by pressure swing adsorption using zeolite 4A. Ind. Eng. Chem. Res. 44(23), 8815–8829 (2005)CrossRef
Hirai, H., Hara, S., Komiyama, M.: Polystyrene-supported aluminium silver chloride as selective ethylene adsorbent. Die Angewandte Makromolekulare Chemie 130(1), 207–212 (1985a)CrossRef
Hirai, H., Kurima, K., Wada, K., Komiyama, M.: Selective ethylene adsorbents composed of copper(I) chloride and polystyrene resins having amino groups. Chem. Lett. 14(10), 1513–1516 (1985b)CrossRef
Iucolano, F., Aprea, P., Caputo, D., Colella, C., Eić, M., Huang, Q.: Adsorption and diffusion of propane and propylene in Ag+-impregnated MCM-41. Adsorption 14(2–3), 241–246 (2008)CrossRef
Jiang, D.-E., Sumpter, B.G., Dai, S.: Olefin adsorption on silica-supported silver salts—a DFT study. Langmuir 22(13), 5716–5722 (2006)CrossRef
Lee, Y., Reisner, B.A., Hanson, J.C., Jones, G.A., Parise, J.B., Corbin, D.R., Toby, B.H., Freitag, A., Larese, J.Z.: New insight into cation relocations within the pores of zeolite rho: in situ synchrotron X-ray and neutron powder diffraction studies of Pb- and Cd-exchanged rho. J. Phys. Chem. B 105(30), 7188–7199 (2001)CrossRef
Myers, A.L., Prausnitz, J.M.: Thermodynamics of mixed-gas adsorption. AIChE J. 11, 121–127 (1965)CrossRef
Li, K., Olson, D.H., Seidel, J., Emge, T.J., Gong, H., Zeng, H., Li, J.: Zeolitic imidazolate frameworks for kinetic separation of propane and propene. J. Am. Chem. Soc. 131(30), 10368–10369 (2009)CrossRef
Lin, C.C.H., Sawada, J.A., Wu, L., Haastrup, T., Kuznicki, S.M.: Anion-controlled pore size of titanium silicate molecular sieves. J. Am. Chem. Soc. 131(2), 609–614 (2008)CrossRef
Mathias, P.M., Kumar, R., Moyer, J.D., Schork, J.M., Srinivasan, S.R., Auvil, S.R., Talu, O.: Correlation of multicomponent gas adsorption by the dual-site langmuir model. Application to nitrogen/oxygen adsorption on 5A-zeolite. Ind. Eng. Chem. Res. 35(7), 2477–2483 (1996)CrossRef
Murthi, M., Snurr, R.Q.: Effects of molecular siting and adsorbent heterogeneity on the ideality of adsorption equilibria. Langmuir 20(6), 2489–2497 (2004)CrossRef
Nakahara, T., Wakai, T.: Adsorption of ethylene/ethane mixtures on a carbon molecular sieve. J. Chem. Eng. Data 32(1), 114–117 (1987)CrossRef
Olivier, M.-G., Bougard, J., Jadot, R.: Adsorption of propane, propylene and propadiene on activated carbon. Appl. Therm. Eng. 16(5), 383–387 (1996)CrossRef
Padin, J., Rege, S.U., Yang, R.T., Cheng, L.S.: Molecular sieve sorbents for kinetic separation of propane/propylene. Chem. Eng. Sci. 55(20), 4525–4535 (2000)CrossRef
Padin, J., Yang, R.T.: New sorbents for olefin/paraffin separations by adsorption via π-complexation: synthesis and effects of substrates. Chem. Eng. Sci. 55(14), 2607–2616 (2000)CrossRef
Park, J.-H., Han, S.-S., Kim, J.-N., Cho, S.-H.: Vacuum swing adsorption process for the separation of ethylene/ethane with AgNO3/clay adsorbent. Korean J. Chem. Eng. 21(1), 236–245 (2004)CrossRef
Rege, S.U., Padin, J., Yang, R.T.: Olefin/paraffin separations by adsorption: π-complexation vs. kinetic separation. AIChE J. 44(4), 799–809 (1998)CrossRef
Romero-Pérez, A., Aguilar-Armenta, G.: Adsorption kinetics and equilibria of carbon dioxide, ethylene, and ethane on 4A(CECA) zeolite. J. Chem. Eng. Data 55(9), 3625–3630 (2010)CrossRef
Ruthven, D.: Gas separation by adsorption processes by Ralph T. Yang, Butterworths, Boston 1986. Can J Chem Eng 67(1), 174 (1989)CrossRef
Silva, F.A.D., Rodrigues, A.E.: Propylene/propane separation by vacuum swing adsorption using 13X zeolite. AIChE J. 47(2), 341–357 (2001)CrossRef
Sircar, S., and A. L. Myers. 2003. Gas separation by zeolites
Sá Gomes, P., Lamia, N., Rodrigues, A.E.: Design of a gas phase simulated moving bed for propane/propylene separation. Chem. Eng. Sci. 64(6), 1336–1357 (2009)CrossRef
Tang, Z., Dong, J., Nenoff, T.M.: Internal surface modification of MFI-type zeolite membranes for high selectivity and high flux for hydrogen. Langmuir 25(9), 4848–4852 (2009)CrossRef
Timofeev, D.P., Erashko, I.T.: Sorption kinetics of water vapor on type a zeolites. Bull Acad Sci USSR, Div Chem Sci 10(7), 1105–1109 (1961)CrossRef
Van Miltenburg, A., Zhu, W., Kapteijn, F., Moulijn, J.A.: Adsorptive separation of light olefin/paraffin mixtures. Chem. Eng. Res. Des. 84(5), 350–354 (2006)CrossRef
Wang, S., Yang, Q., Zhong, C.: Adsorption and separation of binary mixtures in a metal-organic framework Cu-BTC: a computational study. Sep. Purif. Technol. 60(1), 30–35 (2008)CrossRef
Wu, Z., Han, S.-S., Cho, S.-H., Kim, J.-N., Chue, K.-T., Yang, R.T.: Modification of resin-type adsorbents for ethane/ethylene separation. Ind. Eng. Chem. Res. 36(7), 2749–2756 (1997)CrossRef
Yang, R. T. 1986. Gas separation by adsorption processes
Yang, R.T., Kikkinides, E.S.: New sorbents for olefin/paraffin separations by adsorption via π-complexation. AIChE J. 41(3), 509–517 (1995)CrossRef
Yoon, J.W., Jang, I.T., Lee, K.Y., Hwang, Y.K., Chang, J.-S.: Adsorptive separation of propylene and propane on a porous metal-organic framework, copper trimesate. Bull. Korean Chem. Soc. 31(1), 220–223 (2010)CrossRef
Metadata
Title
Selective adsorption of ethylene over ethane on natural mordenite and on K+-exchanged mordenite
Authors
D. Vargas-Hernández
M. A. Pérez-Cruz
R. Hernández-Huesca
Publication date
01-02-2015
Publisher
Springer US
Published in
Adsorption / Issue 1-2/2015
Print ISSN: 0929-5607
Electronic ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-015-9658-8

Other articles of this Issue 1-2/2015

Adsorption 1-2/2015 Go to the issue

OriginalPaper

A modified multi-site occupancy model: evaluation of azeotropelike behavior in adsorption

Editorial

Preface: 10th Brazilian meeting on adsorption

OriginalPaper

Recovery of p-nitrotoluene by selective adsorption using MFI type zeolites

OriginalPaper

Easily tunable parameterization of a force field for gas adsorption on FAU zeolites

OriginalPaper

Isotherms, kinetics and thermodynamics for adsorption of pyridine vapors on modified activated carbons

OriginalPaper

Activated carbons prepared from peanut shell and sunflower seed shell for high CO2 adsorption

Premium Partners

    Image Credits