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Journal of Nanoparticle Research

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01-12-2015 | Research Paper

Selective hydrogenation of 2-methyl-3-butyn-2-ol catalyzed by embedded polymer-protected PdZn nanoparticles

Authors: Lyudmila B. Okhlopkova, Ekaterina V. Matus, Igor P. Prosvirin, Michail A. Kerzhentsev, Zinfer R. Ismagilov

Published in: Journal of Nanoparticle Research | Issue 12/2015

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Abstract

PdZn/TiO₂ catalysts were synthesized by sol–gel method using a template Pluronic F127. PdZn nanoparticles with the size ranging from 1.7 to 2 nm were prepared by ethylene glycol reduction of ZnCl₂ and Pd(CH₃COO)₂ in the presence of stabilizer and introduced into the matrix by addition into TiO₂ sol, followed by different activation procedures. The structure, particles size, and chemical composition of nanoparticles and catalysts were characterized by transmission electron microscopy, X-ray photoelectron spectroscopy, X-ray fluorescence spectroscopy, and energy dispersive spectroscopy. The prepared catalysts have been tested in the selective hydrogenation of 2-methyl-3-butyn-2-ol, and the results have been compared with catalysts prepared by conventional impregnation. The results indicate that bimetallic PdZn nanoparticles-based catalysts show higher selectivity than corresponding monometallic Pd/TiO₂. Embedded on titania, bimetallic nanoparticles stabilized with polyvinylpyrrolidone exhibit good activity (1.1–1.8 mol MBY/mol Pd/s⁻¹) and high selectivity to 2-methyl-3-buten-2-ol (81.5–88.9 % at 95 % conversion). The influence of the nature of the stabilizer, the stabilizer/metal molar ratio, and activation conditions on the catalytic behavior of the samples was analyzed. It is shown that the particle size does not significantly affect the catalytic properties in the range of 4.4–6.5 nm. The nature and amount of stabilizer seem to be crucial to prepare efficient catalyst.

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Title: Selective hydrogenation of 2-methyl-3-butyn-2-ol catalyzed by embedded polymer-protected PdZn nanoparticles
Authors: Lyudmila B. Okhlopkova
Ekaterina V. Matus
Igor P. Prosvirin
Michail A. Kerzhentsev
Zinfer R. Ismagilov
Publication date: 01-12-2015
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 12/2015
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-015-3289-6

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