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Overview on the Development of Chambers for the Study of Atmospheric Chemical Processes Read chapter Read first chapter

2006 | OriginalPaper | Chapter

Simulation Chamber Study of the Oxidation of Acetic Acid by OH Radicals: Detection of Reaction Products by CW-CRDS in the Near-Infrared Range

Authors : Sabine Crunaire, Christa Fittschen, Bernard Lemoine, Alexandre Tomas, Patrice Coddeville

Published in: Environmental Simulation Chambers: Application to Atmospheric Chemical Processes

Publisher: Springer Netherlands

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The branching ratio for the reaction of OH radicals with CH3COOD was determined at 298 2±K and at atmospheric pressure using an indoor smog chamber (300 L) coupled to two different detection systems: (i) Gas Chromatograph (GC) with FTIR detection for determination of [CH3COOD], (ii) Cavity Ring Down Spectroscopy (CRDS) using a telecommunication diode laser as a source for the determination of [HDO] and [H2O]. The reaction CH3COOD + OH occurs via D-atom abstraction with an efficiency of 36±20 %.

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previous chapter Atmospheric Oxidation of the Chlorinated Solvents, 1,1,1-Trichloroethane, Trichloroethene and Tetrachloroethene
next chapter Kinetics, Products and Mechanism of O(3P) Atom Reactions with Alkyl Iodides
Metadata
Title
Simulation Chamber Study of the Oxidation of Acetic Acid by OH Radicals: Detection of Reaction Products by CW-CRDS in the Near-Infrared Range
Authors
Sabine Crunaire
Christa Fittschen
Bernard Lemoine
Alexandre Tomas
Patrice Coddeville
Copyright Year
2006
Publisher
Springer Netherlands
Book
Environmental Simulation Chambers: Application to Atmospheric Chemical Processes

Print ISBN: 978-1-4020-4230-0

Electronic ISBN: 978-1-4020-4232-4

Copyright Year: 2006

DOI
https://doi.org/10.1007/1-4020-4232-9_15