Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Published in:
Introduction Read chapter Read first chapter

2017 | OriginalPaper | Chapter

8. Spatial Distribution of Molecules Desorbing with Surface Reaction

Author : Ken-ichi Tanaka

Published in: Dynamic Chemical Processes on Solid Surfaces

Publisher: Springer Singapore

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

When temperature of Pd(110) is raised in a flow of NO + H2, N2, N2O and NO are simultaneously desorbed at ca. 490–495 K and the catalytic reaction of NO + H2 → 1/2 N2 + H2O is followed at about 500 K. If 14NO is adsorbed on a 15N/Pd(110) surface, 14N15N and 15NO are simultaneously desorbed at 490–495 K. Interestingly, the N2 desorbed at ca. 490 K takes on a very sharp off-normal spatial distribution expressed by cos46(θ + 38°) towards to the 〈001〉 axis. The result strongly suggests that the N2 is formed by a surface reaction with anisotropic collision of moved N(a) with adsorbed NO(a). In contrast, the N2 formed by the catalytic reaction of NO + H2 → 1/2 N2 + H2O takes on a cos θ distribution, indicating thermal equilibrium is attained.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
previous chapter Overview of Catalysis
next chapter Formation of Active Ordered Layer on Pt–Rh Catalyst
Literature
1.
N. Takehiro, F. Besenbacher, F. Laegsgaard, K-I. Tanaka, and I Stensgaard, Surf. Sci. 397 (1998) 145.
2.
M. Ikai, Hong He, C. E. Borroni-Bird, H. Hirano, K-I. Tanaka, Surf. Sci. 315 (1994) L973.
3.
M. Ikai and K-I. Tanaka, Surf. Sci. 357/358 (1996) 781.
4.
D.R. Horton and R.I. Masel, Surf. Sci., 125 (1983) 699.
5.
J.N. Russell,Jr., I. Chorkendorff, A.-M. Lanzillotto, M.D. Alvey, and J.T. Yates, Jr., J. Chem. Phys., 85 (1986) 6186.
6.
H.J. Robota, W. Vielhaber, M.C. Lin, J. Segner, and G. Ertl, Surf. Sci.,155 (1985) 101.
7.
K.-H. Allers, H. Pfnür, P. Feulner, and D. Menzel, Surf. Sci., 286 (1993) 297.
8.
K.D. Rendulic and A. Winkler, Surf. Sci., 299/300 (1994) 261.
9.
R.C. Cosser, S.R. Bare, S. M. Francis, and D.A. King, Vacuum, 31 (1981) 503.
10.
H. Dietrich, K. Jacobi, and G. Ertl, J. Chem. Phys., 105 (1996) 8944.
11.
T.E. Madey and J.T. Yates,Jr., Surf. Sci., 63 (1977) 203.
12.
R.D. Ramsier and J.T. Yates,Jr., Surf. Sci. Rept. 12 (1991) 243.
13.
E.B.D. Bourdon, C.-C. Cho, P. Das, J.C. Polanyi, C.D. Stanners and G.-Q. Xu, J. Chem. Phys., 95 (1991) 1361.
14.
F.M. Zimmermann and W. Ho, Surf. Sci. Rept., 22 (1995) 127.
15.
E. Hasselbrink, S. Jakubith, S. Nettesheim, M. Wolf, A. Cassuto and G. Ertl, J. Chem. Phys., 92 (1990) 3154.
16.
X-L. Zhou, X-Y. Zhu, and J.M. White, Surf. Sci. Rept. 13 (1991) 73.
17.
L.J. Richter and R.R. Cavanagh, Prog. Surf. Sci., 39 (1992) 155.
18.
T. Matsushima, J. Chem. Phys. 91 (1989) 5722.
19.
T. Matsushima, J. Chem. Phys. 93 (1990) 1464.
20.
M. Ikai and K-I. Tanaka, J. Phys. Chem., B, 103 (1999) 8277.
21.
M. Ikai and K-I. Tanaka, J. Chem. Phys., 110 (1999) 7031.
22.
R. Raval,M.A. Harrison, S.Haq, and D.A. King, Surf. Sci. 294 (1993) 10.
23.
J. Shingh, W.K. Walter, A. Atrei, and D.A. King, hem. Phys. Lett.185 (1991) 426.
24.
R.G. Sharpe, and M. Bowker, Surf. Sci.,360 (1996) 21.
25.
K. Moriwaki, T. Matsumoto, M. Ikai, and K-I. Tanaka, Chem. Phys. Letters 292 (1998) 500.
26.
Y. Matsumoto, Y. Okawa, K. Suzuki, K. Mukai, and K-I. Tanaka, J. Am. Chem. Soc.,118 (1996) 9676.
27.
H. Kohguchi, Y. Ogi, and T. Suzuki, Phys. Chem. Chem. Phys.10 (2008) 7222.
28.
D.P. Masson, E.J. Lanzendorf, A.C. Kummel, Phys. Rev. Lett., 74 (1995) 1799.
29.
D.P. Masson, E.J. Lanzendorf, A.C. Kummel, J. Chem. Phys., 102 (1995) 9096.
Metadata
Title
Spatial Distribution of Molecules Desorbing with Surface Reaction
Author
Ken-ichi Tanaka
Copyright Year
2017
Publisher
Springer Singapore
Book
Dynamic Chemical Processes on Solid Surfaces

Print ISBN: 978-981-10-2838-0

Electronic ISBN: 978-981-10-2839-7

Copyright Year: 2017

DOI
https://doi.org/10.1007/978-981-10-2839-7_8

Premium Partners

    Image Credits