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2010 | OriginalPaper | Chapter

Stimuli-Sensitive Microhydrogels

Author : Haruma Kawaguchi

Published in: Biomedical Applications of Hydrogels Handbook

Publisher: Springer New York

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Abstract

Microhydrogels have become a very interesting and important material in hydrogels bioapplications. New techniques for the design, synthesis, characterization, function, and application of microhydrogels are providing exciting new possibilities in the micronized science. Hydrogels are a soft material with sizes and shapes that are subject to change depending on environmental conditions such as temperature, pH, coexisting materials, and light. Hydrogels that respond to these environmental stimuli and cause swelling changes in aqueous media are known as “stimuli-sensitive hydrogels.”

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previous chapter Stimuli-Responsive PEGylated Nanogels for Smart Nanomedicine

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Tanaka T, Fillmore DJ (1979) Kinetics of swelling of gels. J Chem Phys 70:1214–1218CrossRef

Schield HG (1992) Poly(N-isopropylacrylamide): experiment, theory and application. Prog Polym Sci 17:163–249CrossRef

Ito S (1987) Phase-transition of aqueous solution of poly(N-alkylacrylamide) derivatives. Effect of side chain structure. Kobunshi Ronbunshu 46(7):437–443CrossRef

Pelton RH, Chibante P (1986) Preparation of aqueous latexes with N-isopropylacrylamide. Coll Surf 20:247–256CrossRef

Kawaguchi H, Yamada Y, Kataoka S, Morita Y, Ohtsuka Y (1991) Hydrogel microspheres. 2. Precipitation copolymerization of acrylamide with comonomers to prepare monodisperse hydrogel microspheres. Polym J 23:955–962CrossRef

Nakazawa Y, Kamijo Y, Fujimoto K, Kawaguchi H, Yuguchi Y, Urakawa H, Kajiwara K (1996) Preparation and structural characteristics of stimuri-responsive hydrogel microsphere. Angew Makromol Chem 240:187–196CrossRef

Jones CD, Lyon LA (2003) Macromolecules 19:4544

Imaz A, Forcada J (2008) N-vinylcaprolactam-based microgels: effect of the concentration and type of cross-linker. J Polym Sci A Polym Chem 46(8):2766–2775CrossRef

Tsuji S, Kawaguchi H (2004) Temperature-sensitive hairy particles prepared by living radical graft polymerization. Langmuir 20:2449–2455CrossRef

10.

Tsuji S, Kawaguchi H (2005) Self-assembly of poly(N-isopropylacrylamide)-carrying microspheres into two-dimensional colloidal arrays. Langmuir 21(6):2434–2437CrossRef

11.

Tsuji S, Kawaguchi H (2006) Effect of graft chain length and structure design on temperature-sensitive hairy particles. Macromolecules 39(13):4338–4344CrossRef

12.

Heskins M, Guillet JE, James E (1968) Solution properties of poly(N-isopropylacrylamide). J Macromol Sci Chem A2:1441–1455

13.

Harsh DC, Gehrke SH (1991) J Control Release 17:175CrossRef

14.

Lu X, Hu Z, Gao J (2001) Macromolecules 34:2242CrossRef

15.

Sato T, Tsuji S, Kawaguchi H (2008) Preparation of functional nanoparticles by assembling block copolymers formed by living radical polymerization. Ind Eng Chem Res 47:6358–6361CrossRef

16.

Guillot S, Delsanti M, Désert S, Langevin D (2003) Surfactant-Induced Collapse of Polymer Chains and Monodisperse Growth of Aggregates near the Precipitation Boundary in Carboxymethylcellulose−DTAB Aqueous Solutions. Langmuir 19(2):230–237CrossRef

17.

Hoshino F, Fujimoto T, Kawaguchi H, Ohtsuka Y (1987) N-substituted acrylamide-styrne copolymer latexes II. Polymerization behavior and thermosensitive stability of latexes. Polym J 19(2):241–247CrossRef

18.

Wu C, Zhou S (1997) Macromolecules 30:574CrossRef

19.

Ohshima H, Makino K, Kato T, Fujimoto K, Kondo T (1993) Kawaguchi, Electrophoretic mobility of latex particles covered with temperature-sensitive hydrogel layers. J Colloid Interface Sci 159:512–514CrossRef

20.

Rubio RJ, Frick B, Seydel T, Stamm M, Fernandez BA, Lopez CE (2008) Polymer chain dynamics of core-shell thermosensitive microgels. Macromolecules 41(13):4739–4745CrossRef

21.

Tsuji S, Kawaguchi H (2008) Thermosensitive Pickering emulsion stabilized by poly(N-isopropylacrylamide)-carrying particles. Langmuir 24(7):3300–3305CrossRef

22.

Brugger B, Richtering W (2008) Emulsions stabilized by stimuli-sensitive poly(N-isopropylacrylamide)-co-methacrylic acid polymers: microgels versus low molecular weight polymers. Langmuir 24(15):7769–7777CrossRef

23.

Suzuki D, Tsuji S, Kawaguchi H (2008) Janus microgels prepared by surfactant-free Pickering emulsion-based modification and their self-assembly. J Am Chem Soc 129(26):8088–8089CrossRef

24.

Ni H, Kawaguchi H, Endo T (2007) Preparation of pH-sensitive hydrogel microspheres of poly(acrylamide-co-methacrylic acid) with sharp pH–volume transition. Colloid Polym Sci 285:819–826CrossRef

25.

Ni H, Kawaguchi H (2007) Preparation of amphoteric microgels of poly (acrylamide/methacrylicacid/dimethylamino ethylene methacrylate) with a novel pH-volume transition. Macromolecules 40:6370–6376CrossRef

26.

Freemont TJ, Saunders BR (2008) pH-Responsive microgel dispersions for repairing damaged load-bearing soft tissue. Soft Matter 4(5):919–924CrossRef

27.

Dalmont H, Pinprayoon O, Saunders BR (2008) Study of pH-responsive microgels containing methacrylic acid: effects of particle composition and added calcium. Langmuir 24:2834–2840CrossRef

28.

Amalvy JL, Wanless EJ, Li Y, Michailidou V, Armes SP (2004) Synthesis and characterization of novel pH responsive microgels based on tertiary amine methacrylates. Langmuir 20:8992–8999CrossRef

29.

Teng D, Hou J, Zhang X, Wang X, Wang Z, Li C (2008) Glucosamine-carrying temperature- and pH-sensitive microgels: preparation, characterization, and in vitro drug release studies. J Colloid Interface Sci 322(1):333–341CrossRef

30.

Bredley M, Vincent B (2008) Poly(vinylpyridine) core/poly(N-isopropylacrylamide) shell microgel particles: their characterization and the uptake and release of anionic surfactant. Langmuir 24(6):2421–2425CrossRef

31.

Ho BS, Tan BH, Tan JPK, Tam KC (2008) Inverse microemulsion polymerization of sterically stabilized polyampholyte microgels. Langmuir 24(15):7698–7703CrossRef

32.

Ni P (2008) Nanoparticles comprising pH/temperature-responsive amphiphilic block copolymers and their applications in biotechnology. In: Elaissari A (ed) Colloidal nanoparticles in biotechnology. Wiley, New York

33.

Kleinen J, Richtering W (2008) Defined complexes of negatively charged multisensitive poly(N-isopropylacrylamide-co-methacrylic acid) microgels and poly(diallyldimethylammonium chloride). Macromolecules 41:1785–1790CrossRef

34.

Zhang J, Xu S, Kumacheva E (2004) Polymer microgels: reactors for semiconductor, metal, and magnetic nanoparticles. J Am Chem Soc 126(25):7908–7914CrossRef

35.

Liu S, Weaver JVM, Save M, Armes SP (2003) Synthesis of pH-responsive shell cross-linked micelles and their use as nanoreactors for the preparation of gold nanoparticles. Langmuir 18:8350CrossRef

36.

Nassif N, Gehrke N, Pinna N, Shirshova N, Tauer K, Antonietti M, Colfen H (2005) Synthesis of stable aragonite superstructures by a biomimetic crystallization pathway. Angew Chem Int Ed Engl 117:6158CrossRef

37.

Zhang Q, Tang Y, Zha L, Ma J, Liang B (2008) Effects of hectorite content on the temperature-sensitivity of PNIPAM microgels. Eur Polym J 44(5):1358–1367CrossRef

38.

Suzuki D, Kawaguchi H (2005) Modification of gold nanoparticle composite nanostructures using thermosensitive core-shell particles as a template. Langmuir 21(18):8175–8179CrossRef

39.

Suzuki D, Kawaguchi H (2005) Gold nanoparticle localization at the core surface by using thermosensitive core-shell particles as a template. Langmuir 21:12016–12024CrossRef

40.

Hantzschel N, Zhang F, Eckert F, Pich A, Winnik M (2007) Poly(N-vinylcaprolactam-co-glycidyl methacrylate) aqueous microgels labeled with fluorescent LaF₃:Eu nanoparticles. Langmuir 23:10793–10800CrossRef

41.

Suzuki D, Kawaguchi H (2006) Hybrid microgels with reversibly changeable multiple brilliant color. Langmuir 22:3818–3822CrossRef

42.

Suzuki D, McGrath J, Kawguchi H, Lyon LA (2007) Colloidal crystals of thermosensitive, core/shell hybrid microgels. J Phys Chem C 111:5667–5672CrossRef

43.

Schrinner M, Proch S, Mei Y, Kempe R, Miyajima N, Ballauff M (2008) Stable bimetallic gold-platinum nanoparticles immobilized on spherical polyelectrolyte brushes: synthesis, characterization, and application for the oxidation of alcohols. Adv Mater 20(10):1928–1933CrossRef

44.

Wong JE, Gaharwar AK, Mueller-Schulte D, Bahadur D, Richtering W (2008) Dual-stimuli responsive PNIPAM microgel achieved via layer-by-layer assembly: magnetic and thermoresponsive. J Colloid Interface Sci 324:47–54CrossRef

45.

Suzuki D, Kawaguchi H (2006) Stimuli-sensitive core/shell template particles for immobilizing inorganic nanoparticles in the core. Colloid Polym Sci 284:1443–1451CrossRef

46.

Agrawal M, Pich A, Gupta S, Zafeiropoulos NE, Rubio-Retama J, Simon F, Stamm M (2008) Temperature sensitive hybrid microgels loaded with ZnO nanoparticles. J Mater Chem 18(22):2581–2586CrossRef

47.

Wang P, Chen D, Tang FQ (2006) Preparation of titania-coated polystyrene particles in mixed solvents by ammonia catalysis. Langmuir 22:4832–4835CrossRef

48.

Kawaguchi H, Suzuki D, Kaneshima D (2008) Synthesis and application of polymeric microspheres containing inorganic particles. Trans Mater Res Soc Jpn 33(2):205–208

49.

Coutinho CA, Harrinauth RK, Gupta VK (2008) Settling characteristics of composites of PNIPAM microgels and TiO2 nanoparticles. Colloids Surf A Physicochem Eng Asp 318(1–3):111–121CrossRef

50.

Shen L, Pich A, Fava D, Wang M, Kumar S, Wu C, Scholes GD, Winnik MA (2008) Loading quantum dots into thermo-responsive microgels by reversible transfer from organic solvents to water. J Mater Chem 18(7):763–770CrossRef

51.

Zhao X, Gan J, Chuchi S, Liu G, Chen A (2007) Poly(N-isopropyl acrylamide) microgel doped with luminescent PbS quantum dots. Chinese J React Polym 16(1–2):55–60

52.

Hain J, Eckert F, Pich A, Hans-Juergen A (2008) Multi-sensitive microgels filled with conducting poly(3, 4-ethylenedioxythiophene) nanorods. Macromol Rapid Commun 29(6):472–478CrossRef

53.

Suzuki D, Yoshida R (2008) Temporal control of self-oscillation for microgels by cross-linking network structure. Macromolecules 41(15):5830–5838CrossRef

54.

Zhou J, Wang G, Marquez M, Hu ZB (2008) The formation of crystalline hydrogel films by self-crosslinking microgels. Soft Matter 5:820–826CrossRef

55.

Musch J, Schneider S, Lindner P, Richtering W (2008) Unperturbed volume transition of thermosensitive poly(N-isopropylacrylamide) microgel particles embedded in a hydrogel matrix. J Phys Chem B 112(20):6309–6314CrossRef

Title: Stimuli-Sensitive Microhydrogels
Author: Haruma Kawaguchi
Publisher: Springer New York
Book: Biomedical Applications of Hydrogels Handbook
Print ISBN: 978-1-4419-5918-8

Electronic ISBN: 978-1-4419-5919-5

Copyright Year: 2010
DOI: https://doi.org/10.1007/978-1-4419-5919-5_6

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