Skip to main content
Top
Published in: Journal of Materials Science: Materials in Electronics 6/2015

01-06-2015

Structural, dielectric and electrical properties of the Ba2BiNbO6 double perovskite

Authors: Niranjan Panda, B. N. Parida, R. Padhee, R. N. P. Choudhary

Published in: Journal of Materials Science: Materials in Electronics | Issue 6/2015

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The polycrystalline sample of Ba2BiNbO6 (a member of double perovskite family) was synthesized by a high-temperature solid-state reaction method (calcination at 910 °C, and sintering at 950 °C). Preliminary analysis of room temperature X-ray data pattern of the sample confirms the formation of a single phase compound in orthorhombic crystal system. The room temperature scanning electron microscope image of the pellet sample clearly shows the uniform distribution of grains and formation of a high density sample. Detailed studies of dielectric and polarization characteristics with temperature confirmed the existence of ferroelectricity in the material. Studies of electrical properties exhibits a strong correlation with the micro-structure and resistive properties of the material. The electrical transport shows the existence of non-exponential-type of conductivity relaxation in the material. This lead-free ferroelectric has many interesting characteristics as compared to that of their lead-based counterpart, Pb2BiNbO6.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference F.W. Aiger, Modern Oxide Materials-Preparation, Properties and Device Applications (Academic Press. Inc., London, 1972) F.W. Aiger, Modern Oxide Materials-Preparation, Properties and Device Applications (Academic Press. Inc., London, 1972)
2.
go back to reference G. Goodman, Ferroelectric properties of lead metaniobate. J. Am. Ceram. Soc. 36, 368–372 (1953)CrossRef G. Goodman, Ferroelectric properties of lead metaniobate. J. Am. Ceram. Soc. 36, 368–372 (1953)CrossRef
3.
go back to reference M.H. Francombe, B. Lewis, Structural, dielectric and optical properties of ferroelectric lead metaniobate. Acta Crystallogr. 11, 696 (1958)CrossRef M.H. Francombe, B. Lewis, Structural, dielectric and optical properties of ferroelectric lead metaniobate. Acta Crystallogr. 11, 696 (1958)CrossRef
4.
go back to reference M.E. Lines, A.M. Glass, Principles and applications of ferroelectrics and related materials (Oxford University Press, Oxford, UK, 2001)CrossRef M.E. Lines, A.M. Glass, Principles and applications of ferroelectrics and related materials (Oxford University Press, Oxford, UK, 2001)CrossRef
5.
go back to reference C.A. Randall, A.D. Hilton, D.J. Barber, T.R. Shrout, Extrinsic contributions to the grain size dependence of relaxor ferroelectric Pb(Mg1/3Nb2/3)O3: PbTiO3 ceramics. J. Mat. Res. 8, 880–884 (1993)CrossRef C.A. Randall, A.D. Hilton, D.J. Barber, T.R. Shrout, Extrinsic contributions to the grain size dependence of relaxor ferroelectric Pb(Mg1/3Nb2/3)O3: PbTiO3 ceramics. J. Mat. Res. 8, 880–884 (1993)CrossRef
6.
go back to reference R. Guo, A.S. Bhalla, C.A. Randall, L.E. Cross, Dielectric and pyroelectric properties of the morphotropic phase boundary lead barium niobate (PBN) single crystals at low temperature (10–300 K). J. Appl. Phys. 67, 6405 (1990)CrossRef R. Guo, A.S. Bhalla, C.A. Randall, L.E. Cross, Dielectric and pyroelectric properties of the morphotropic phase boundary lead barium niobate (PBN) single crystals at low temperature (10–300 K). J. Appl. Phys. 67, 6405 (1990)CrossRef
7.
go back to reference M. Lee, R.S. Feigelson, A. Liu, L. Hesselink, Photorefractive properties of tungsten bronze ferroelectric lead barium niobate (Pb1−x Ba x Nb2O6)crystals. J. Appl. Phys. 83, 5967 (1998)CrossRef M. Lee, R.S. Feigelson, A. Liu, L. Hesselink, Photorefractive properties of tungsten bronze ferroelectric lead barium niobate (Pb1−x Ba x Nb2O6)crystals. J. Appl. Phys. 83, 5967 (1998)CrossRef
8.
go back to reference T.R. Shrout, H. Chen, L.E. Cross, Dielectric and piezoelectric properties of Pb1−xBaxNb2O6 ferroelectric tungsten bronze crystals. Ferroelectrics 74, 317–324 (1987)CrossRef T.R. Shrout, H. Chen, L.E. Cross, Dielectric and piezoelectric properties of Pb1−xBaxNb2O6 ferroelectric tungsten bronze crystals. Ferroelectrics 74, 317–324 (1987)CrossRef
9.
go back to reference M. Lee, H. Lee, R.K. Route, R.S. Feigelson, Optical properties of lead barium niobate (Pb1−x Ba x Nb2O6) crystals. J. Appl. Phys. 81, 917 (1997)CrossRef M. Lee, H. Lee, R.K. Route, R.S. Feigelson, Optical properties of lead barium niobate (Pb1−x Ba x Nb2O6) crystals. J. Appl. Phys. 81, 917 (1997)CrossRef
10.
go back to reference G. Burns, F.H. Dacol, R. Guo, A.S. Bhalla, Ferroelectric (Pb, Ba)Nb2O6 near the morphotropic phase boundary. Appl. Phys. Lett. 57, 543 (1990)CrossRef G. Burns, F.H. Dacol, R. Guo, A.S. Bhalla, Ferroelectric (Pb, Ba)Nb2O6 near the morphotropic phase boundary. Appl. Phys. Lett. 57, 543 (1990)CrossRef
11.
go back to reference V.R. Palkar, S.K. Malik, Observation of magnetoelectric behavior at room temperature in Pb(FexTi1−x)O3. Solid State Commun. 134, 783–786 (2005)CrossRef V.R. Palkar, S.K. Malik, Observation of magnetoelectric behavior at room temperature in Pb(FexTi1−x)O3. Solid State Commun. 134, 783–786 (2005)CrossRef
12.
go back to reference D.A. Landínez Téllez, G. Peña Rodríguez, J. Arbey Rodríguez, F. Fajardo, J. Roa Rojas, Structural, magnetic, multiferroic, and electronic properties of Sr2TiMnO6 double perovskite. Dyna 79, 111–115 (2012) D.A. Landínez Téllez, G. Peña Rodríguez, J. Arbey Rodríguez, F. Fajardo, J. Roa Rojas, Structural, magnetic, multiferroic, and electronic properties of Sr2TiMnO6 double perovskite. Dyna 79, 111–115 (2012)
13.
go back to reference V.A. Isupov, Nature of physical phenomena in ferroelectric relaxors. Phys. Solid State 45, 1107–1111 (2003)CrossRef V.A. Isupov, Nature of physical phenomena in ferroelectric relaxors. Phys. Solid State 45, 1107–1111 (2003)CrossRef
14.
go back to reference P. Baettig, N.A. Spaldin, Ab initio prediction of a multiferroic with large polarization. Appl. Phys. Lett. 86, 12505–12507 (2005)CrossRef P. Baettig, N.A. Spaldin, Ab initio prediction of a multiferroic with large polarization. Appl. Phys. Lett. 86, 12505–12507 (2005)CrossRef
15.
go back to reference C. Ang, R. Guo, A.S. Bhalla, L.E. Cross, Dielectric dispersion at microwave frequencies. J. Appl. Phys. 87, 3937–3940 (2000)CrossRef C. Ang, R. Guo, A.S. Bhalla, L.E. Cross, Dielectric dispersion at microwave frequencies. J. Appl. Phys. 87, 3937–3940 (2000)CrossRef
16.
go back to reference H.P. Klug, L.E. Alexander, X-ray Diffraction Procedures for Polycrystalline and Amorphous Materials (Wiley-Interscience, New York, 1974) H.P. Klug, L.E. Alexander, X-ray Diffraction Procedures for Polycrystalline and Amorphous Materials (Wiley-Interscience, New York, 1974)
17.
go back to reference E.W. POWD, An interactive powder diffraction data interpretation and indexing Program, Ver 2.1 (School of Physical Science, Finders University of South Australia, Bedford Park, SA 5042, Australia) E.W. POWD, An interactive powder diffraction data interpretation and indexing Program, Ver 2.1 (School of Physical Science, Finders University of South Australia, Bedford Park, SA 5042, Australia)
18.
go back to reference B.N. Parida, P.R. Das, R. Padhee, R.N.P. Choudhary, A new ferroelectric oxide Li2Pb2Pr2W2Ti4Nb4O30: synthesis and characterization. J. Phys. Chem. Solids 73, 713 (2012)CrossRef B.N. Parida, P.R. Das, R. Padhee, R.N.P. Choudhary, A new ferroelectric oxide Li2Pb2Pr2W2Ti4Nb4O30: synthesis and characterization. J. Phys. Chem. Solids 73, 713 (2012)CrossRef
19.
go back to reference B.D. Cullity, Elements of X-ray Diffraction (Addison-Wesley Publishing Co. Inc., Boston, 1978) B.D. Cullity, Elements of X-ray Diffraction (Addison-Wesley Publishing Co. Inc., Boston, 1978)
20.
go back to reference B.N. Parida, P.R. Das, R. Padhee, R.N.P. Choudhary, Phase transition and conduction mechanism of rare earth based tungsten-bronze compounds. J. Alloys Compd. 540, 267 (2012)CrossRef B.N. Parida, P.R. Das, R. Padhee, R.N.P. Choudhary, Phase transition and conduction mechanism of rare earth based tungsten-bronze compounds. J. Alloys Compd. 540, 267 (2012)CrossRef
21.
go back to reference K. Jawahar, Choudhary RNP, structural and dielectric properties of Y3/2Bi3/2Fe5O12. Mater. Lett. 62, 911–913 (2008)CrossRef K. Jawahar, Choudhary RNP, structural and dielectric properties of Y3/2Bi3/2Fe5O12. Mater. Lett. 62, 911–913 (2008)CrossRef
22.
go back to reference P.R. Das, L. Biswal, B. Behera, R.N.P. Choudhary, Structural and electrical properties of Na2Pb2Eu2W2Ti4X4O30 (X = Nb, Ta) ferroelectric ceramics. Mater. Res. Bull. 44, 1214–1218 (2009)CrossRef P.R. Das, L. Biswal, B. Behera, R.N.P. Choudhary, Structural and electrical properties of Na2Pb2Eu2W2Ti4X4O30 (X = Nb, Ta) ferroelectric ceramics. Mater. Res. Bull. 44, 1214–1218 (2009)CrossRef
23.
go back to reference C.G. Koops, On the dispersion of resistivity and dielectric constant of some semiconductors at audiofrequencies. Phys. Rev. 83, 121–124 (1951)CrossRef C.G. Koops, On the dispersion of resistivity and dielectric constant of some semiconductors at audiofrequencies. Phys. Rev. 83, 121–124 (1951)CrossRef
24.
go back to reference D.P. Almond, A.R. West, Impedance and modulus spectroscopy of “real” dispersive conductors. Solid State Ionics 11, 57–64 (1983)CrossRef D.P. Almond, A.R. West, Impedance and modulus spectroscopy of “real” dispersive conductors. Solid State Ionics 11, 57–64 (1983)CrossRef
25.
go back to reference D.C. Sinclair, A.R. West, Impedance and modulus spectroscopy of semiconducting BaTiO3 showing positive temperature coefficient of resistance. J. Appl. Phys. 66, 3850 (1989)CrossRef D.C. Sinclair, A.R. West, Impedance and modulus spectroscopy of semiconducting BaTiO3 showing positive temperature coefficient of resistance. J. Appl. Phys. 66, 3850 (1989)CrossRef
26.
go back to reference M. Nobre, S. Lanfredi, Ferroelectric state analysis in grain boundary of Na0.85Li0.15NbO3 ceramic. J. Appl. Phys. 93, 5557 (2003)CrossRef M. Nobre, S. Lanfredi, Ferroelectric state analysis in grain boundary of Na0.85Li0.15NbO3 ceramic. J. Appl. Phys. 93, 5557 (2003)CrossRef
28.
go back to reference N.K. Karan, D.K. Pradhan, R. Thomas, B. Natesan, R.S. Katiyar, Solid State Ionics 179, 689 (2008)CrossRef N.K. Karan, D.K. Pradhan, R. Thomas, B. Natesan, R.S. Katiyar, Solid State Ionics 179, 689 (2008)CrossRef
29.
go back to reference Z. Lu, J.P. Bonnet, J. Ravez, P. Hagenmuller, Solid State Ionics 57, 235 (1992)CrossRef Z. Lu, J.P. Bonnet, J. Ravez, P. Hagenmuller, Solid State Ionics 57, 235 (1992)CrossRef
30.
go back to reference A.K. Jonscher, Dielectric Relaxation in Solids (Chelsea Dielectric Press, London, 1983) A.K. Jonscher, Dielectric Relaxation in Solids (Chelsea Dielectric Press, London, 1983)
Metadata
Title
Structural, dielectric and electrical properties of the Ba2BiNbO6 double perovskite
Authors
Niranjan Panda
B. N. Parida
R. Padhee
R. N. P. Choudhary
Publication date
01-06-2015
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 6/2015
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-015-2905-7

Other articles of this Issue 6/2015

Journal of Materials Science: Materials in Electronics 6/2015 Go to the issue