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Published in: Journal of Materials Science: Materials in Electronics 16/2019

20-07-2019

Structural, dielectric, and piezoelectric properties of lead-free (1 − x)K1/2Na1/2NbO3 − xCa(Zn1/3Ta2/3)O3 perovskite solid solution

Authors: Sushmita Dwivedi, Nidhi Chamoli, Tanvi Pareek, Deepu Kumar, Pradeep Kumar, Sunil Kumar

Published in: Journal of Materials Science: Materials in Electronics | Issue 16/2019

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Abstract

Polycrystalline ceramics in (1 − x)K1/2Na1/2NbO3 − xCaZn1/3Ta2/3O3 (abbreviated as KNN-CZT) solid solution have been fabricated by using conventional solid-state synthesis route and the effect of CZT addition on the crystal structure, dielectric, and piezoelectric behaviour of KNN has been studied. Rietveld refinement of the room temperature X-ray diffraction data confirmed the crystal structure to be a pure perovskite phase for the compositions in the range x = 0 − 0.10. Further, the crystal structure gradually changed from orthorhombic to cubic via the formation of rhombohedral and tetragonal mixed phases with the increase in x. Raman spectroscopy suggested damping of phonon modes and a strong anharmonicity in the crystal arising due to the increased disorder in the structure as a consequence of multivalent cations occupying the A and B sites in CZT substituted compositions. Dielectric behaviour indicated the shifting of both tetragonal-cubic and orthorhombic–tetragonal phase transitions towards room temperature. The temperature dependent dielectric constant was modelled by Lorentz quadratic law, and the fitted value of diffuseness parameters confirmed an increase in diffuseness of phase transition with increasing substitution. Sample with the composition corresponding to x = 0.02 showed an improved piezoelectric coefficient d33 ~ 125 pC/N and electromechanical coupling coefficient kp ~ 30% at room temperature and d33 ~ 61 pC/N and kp ~ 24% at 300 °C which make this material a potential candidate for high-temperature piezoelectric applications. Variation of voltage coefficient (g33) with the change in compositions are also reported. Improvement in the piezoelectric properties is attributed to the reduced oxygen vacancies.

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Appendix
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Metadata
Title
Structural, dielectric, and piezoelectric properties of lead-free (1 − x)K1/2Na1/2NbO3 − xCa(Zn1/3Ta2/3)O3 perovskite solid solution
Authors
Sushmita Dwivedi
Nidhi Chamoli
Tanvi Pareek
Deepu Kumar
Pradeep Kumar
Sunil Kumar
Publication date
20-07-2019
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 16/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-01881-1

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