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01-01-2017 | Original Article

Structure analysis of geopolymers synthesized from clay originated from Serbia

Authors: Snežana S. Nenadović, Ljiljana M. Kljajević, Maja A. Nešić, Marijana Ž. Petković, Katarina V. Trivunac, Vladimir B. Pavlović

Published in: Environmental Earth Sciences | Issue 2/2017

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Abstract

The paper presents chemical and structural analysis of geopolymer materials which are obtained by alkali-activated calcined clay (metakaolin) originated from Serbia under strictly defined conditions. Characterization of the metakaolin and geopolymers molecular structure has been done using X-ray diffraction, scanning electron microscope, Fourier transform infrared spectroscopy and matrix-assisted laser desorption ionization time-of-flight mass spectrometry. The paper presents the possibility of obtaining geopolymer structure and differences in chemical and structural characterization of these materials taking into account the concentration of NaOH as a variable parameter. The results of MALDI analysis of metakaolin and synthesized geopolymer structures using various matrix system: 2,4,6 trihydroxyacetophenone (THAP), α-cyano-4-hydroxycinnamic, 2,6 dihydroxyacetophenone and laser desorption/ionization, have shown that THAP matrix is the most appropriate for analysing these aluminosilicate materials.

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Title: Structure analysis of geopolymers synthesized from clay originated from Serbia
Authors: Snežana S. Nenadović
Ljiljana M. Kljajević
Maja A. Nešić
Marijana Ž. Petković
Katarina V. Trivunac
Vladimir B. Pavlović
Publication date: 01-01-2017
Publisher: Springer Berlin Heidelberg
Published in: Environmental Earth Sciences / Issue 2/2017
Print ISSN: 1866-6280
Electronic ISSN: 1866-6299
DOI: https://doi.org/10.1007/s12665-016-6360-4

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