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04-04-2022 | Original Research

Structure, physicochemical properties, and adsorption performance of the ethyl cellulose/bentonite composite films

Authors: Olga V. Alekseeva, Andrew V. Noskov, Alexander V. Agafonov

Published in: Cellulose | Issue 7/2022

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Abstract

Ethyl cellulose (EC) was filled with bentonite (Bent) particles by mechanical dispersion to produce composite film materials that were studied using various methods. According to X-ray diffraction (XRD) analysis, the inter-chain separation length was larger in EC/Bent composite then those in pure polymer. Infrared spectrometry indicated a formation of hydrogen bonds between the hydroxyl groups of EC and the silanol groups of clay. Tests showed an increase in tensile strength of the polymer material (by 35–40%) when doped with bentonite. It was found that modification of polymer with bentonite resulted in increasing of the adsorption efficiency of methylene blue (MB): the equilibrium concentration of MB ions in adsorbent phase increased 2.5 times. The MB adsorption kinetics obeyed the pseudo-first-order mechanism. Isotherms were in good agreement with Langmuir model. For the composite, the maximum monolayer adsorption capacity was 4 times higher than that for pure polymer.

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Title: Structure, physicochemical properties, and adsorption performance of the ethyl cellulose/bentonite composite films
Authors: Olga V. Alekseeva
Andrew V. Noskov
Alexander V. Agafonov
Publication date: 04-04-2022
Publisher: Springer Netherlands
Published in: Cellulose / Issue 7/2022
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-04546-1

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