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Metal Science and Heat Treatment
Published in: Metal Science and Heat Treatment 7-8/2011

01-10-2011 | Titanium and Nickel Alloys

Structure, sorption and catalytic properties of a hydrogen-accumulating alloy of the Ti – Fe – Zr – Mo system

Author: V. P. Mordovin

Published in: Metal Science and Heat Treatment | Issue 7-8/2011

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Abstract

The sorption properties of a titanium-base hydrogen-accumulating Ti – 42% Fe – 5% Zr – 1% Mo alloy, in which the formed hydride phases are more stable and hydrogen-accumulating than in the known TiFe compound, are studied. It is shown that the alloy bearing hydrogen, oxygen, nitrogen, and carbon is a catalytically active material. It can be used for synthesizing aliphatic amino acids and hydrocarbons.
previous article Electrotechnical anisotropic steel. Part 1. History of development
next article X-ray-electron and electron diffraction study of ordering alloys of the Ni – Mo system

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Footnotes
1
The tested batch of the alloy was melted by A. Sh. Fridman, V. N. Chubarov and T. N. Milyaeva.
 
2
The analysis was performed with participation of G. U. Lubman.
 
3
The characteristics of the specimens were obtained by S. V. Kutsev with the help of Nicolet Avatar-330 and Tristar 3000 devices.
 
Literature
1.
B. A. Kolachev, R. E. Shalin, and A. A. Il’in, Hydrogen-Accumulating Alloys, A Reference Book [in Russian], Metallurgiya, Moscow (1995), 384 p.
2.
R. Viswall, “Storage of hydrogen in metals,” in: G. Alefeld and J. Volkl, Hydrogen in Metals, Vol. 2, Applied Aspects [Russian translation], Mir, Moscow (1981), pp. 241 – 289.
3.
T. Mizuno and T. Morozumi, “Titanium concentration in FeTi x (1 ≤ x ≤ 2) alloys and its effect on hydrogen storage properties,” J. Less-Common Met., 84, 237 – 244 (1982).CrossRef
4.
A. V. Aleksandrov and M. I. Musatov, “Development of skull melting of titanium alloys,” Tekhnol. Legk. Splavov, No. 5 – 6, 80 – 82 (2001).
5.
A. L. Andreev, N. F. Anoshkin, G. A. Bochvar, et al., Titanium Alloys. Melting and Casting of Titanium Alloys [in Russian], Metallurgiya, Moscow (1994), 368 p.
6.
Patent 7513159 Netherlands, MKI C01B6/02, B01D53/16, F17C11/00, Titaan en Ijzer Bevattend Materiaal Voor Het Opslaan Van Waterstof, Publ. 13.05.1977.
7.
Chemical Encyclopedia, in 5 Vols., Vol. 1 [in Russian], Sov. Éntsiklopediya (1988), 623 p.
Metadata
Title
Structure, sorption and catalytic properties of a hydrogen-accumulating alloy of the Ti – Fe – Zr – Mo system
Author
V. P. Mordovin
Publication date
01-10-2011
Publisher
Springer US
Published in
Metal Science and Heat Treatment / Issue 7-8/2011
Print ISSN: 0026-0673
Electronic ISSN: 1573-8973
DOI
https://doi.org/10.1007/s11041-011-9392-0

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