Top

Journal of Materials Science: Materials in Electronics

Published in:

11-12-2015

Study of conjugated polymer/graphene oxide nanocomposites as flexible dielectric medium

Authors: Girish M. Joshi, Kalim Deshmukh

Published in: Journal of Materials Science: Materials in Electronics | Issue 4/2016

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Poly (3,4-ethylenedioxythiophene): (Polystyrenesulfonate) (PEDOT: PSS)/polypyrrole (PPy) and polyvinyl alcohol (PVA) loaded with Graphene oxide (GO) nanocomposites were prepared by sonication. GO (0.5–2.5 wt%) was dispersed homogeneously in the polymer matrix without severe aggregations. The structure and morphology of the composites was evaluated by Fourier transform infrared spectroscopy, UV–Vis spectroscopy, X-ray diffraction, Thermogravimetric analysis (TGA), Atomic force microscopy and Scanning electron microscopy. Microscopic measurements demonstrated that the GO was presence of GO in polymer system. Dielectric properties have been measured as function of broadband frequency (50 Hz–20 MHz) and temperature (40–150 °C). TGA results indicate improvement in the thermal stability of composites. Hence, based on the results obtained, we believe that PEDOT-PSS/PPy/PVA/GO composites films have potential to be used as flexible dielectric materials and for high performance charge storage device applications.

previous article Facile synthesis of BaTiO3 on multiwalled carbon nanotubes as a synergistic microwave absorber

next article Modified solar power: electrochemical synthesis of Nitrogen doped few layer graphene for supercapacitor applications

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 340 Zeitschriften

aus folgenden Fachgebieten:

Bauwesen + Immobilien
Business IT + Informatik
Finance + Banking
Management + Führung
Marketing + Vertrieb
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

S. Kuwabata, S. Masui, H. Yoneyama, Charge–discharge properties of composites of LiMn2O4 and polypyrrole as positive electrode materials for 4 V class of rechargeable Li batteries. Electrochim. Acta 44, 4593–4600 (1999)CrossRef

T.L. Rose, S.D. Antonio, M.H. Jillson, A.B. Kron, R. Suresh, F. Wang, A microwave shutter using conductive polymers. Synth. Met. 85, 1439–1440 (1997)CrossRef

N. Ahmad, A.G. MacDiarmid, Inhibition of corrosion of steels with the exploitation of conducting polymers. Synth. Met. 78, 103–110 (1996)CrossRef

J.Q. Kan, X.H. Pan, C. Chen, Polyaniline–uricase biosensor prepared with template process. Biosens. Bioelectron. 19, 1635–1640 (2004)CrossRef

T. Makela, S. Pienimaa, T. Taka, S. Jussila, H. Isotalo, Thin polyaniline films in EMI shielding. Synth. Met. 85, 1335–1336 (1997)CrossRef

L.B. Groenendaal, F. Jonas, D. Freitag, H. Pielartzik, J.R. Reynolds, Poly (3,4-ethylenedioxythiophene) and its derivatives: past, present, and future. Adv. Mater. 12, 481–494 (2000)CrossRef

J.Y. Kim, I.J. Chung, Y.C. Kim, J.W. Yu, Nanocrystal-conjugated polymer photovoltaic devices. J. Korean Phys. Soc. 45, 231–234 (2004)

C.S. Lee, J. Joo, S. Han, J.H. Lee, S.K. Koh, Actuation of PVDF cantilever with PEDOT/PSS (DMSO) electrode using ion-assisted-reaction. J. Korean Phys. Soc. 45, 747–750 (2004)

S. Cho, S.H. Park, K. Lee, Reflectance study on the metal-insulator transition driven by crystallinity change in poly (3,4-ethylenedioxythiophene)/poly(stylenesulfonate) Films. J. Korean Phys. Soc. 47, 474–478 (2005)

10.

G. Heywang, F. Jonas, Poly (alkylenedioxythiophene)-new, very stable conducting polymers. Adv. Mater. 4, 116–118 (1992)CrossRef

11.

T.M. Brown, J.S. Kim, R.H. Friend, F. Cacialli, R. Daik, W.J. Feast, Built-in field electroabsorption spectroscopy of polymer light-emitting diodes incorporating a doped poly(3,4-ethylene dioxythiophene) hole injection layer. Appl. Phys. Lett. 75, 1679–1681 (1999)CrossRef

12.

A.C. Arias, M. Granstrom, D.S. Thomas, K. Petritsch, R.H. Friend, Doped conducting-polymer–semiconducting-polymer interfaces: their use in organic photovoltaic devices. Phys. Rev. B 60, 1854–1860 (1999)CrossRef

13.

F. Jonas, G. Hevwang, Technical applications for conductive polymers. Electrochim. Acta 39, 1345–1347 (1994)CrossRef

14.

F. Jonas, W. Kraft, B. Muys, Poly (3,4-ethylenedioxythiophene): conductive coatings, technical applications and properties. Macromol. Symp. 100, 169–173 (1995)CrossRef

15.

M. Granstrom, O. Inganas, Flexible arrays of submicrometer-sized polymeric light emitting diodes. Adv. Mater. 7, 1012–1015 (1995)CrossRef

16.

Y. Cao, G. Yu, C. Zhang, R. Menon, A.J. Heeger, Polymer light-emitting diodes with polyethylene dioxythiophene–polystyrene sulfonate as the transparent anode. Synth. Met. 87, 171–174 (1997)CrossRef

17.

L.S. Roman, W. Mammo, L.A.A. Petersson, M.R. Andersson, O. Inganas, High quantum efficiency polythiophene. Adv. Mater. 10, 774–777 (1998)CrossRef

18.

H.W. Heur, R. Wehrmann, S. Kirchmeyer, Electrochromic window based on conducting poly(3,4-ethylenedioxythiophene)–poly(styrene sulfonate). Adv. Funct. Mater. 12, 89–94 (2002)CrossRef

19.

H.S. Woo, Y.B. Kim, R. Czerw, D.L. Carrol, J. Ballato, P.M. Ajayan, Tailoring hole transport in organic light-emitting devices using carbon nanotube-polymer nanocomposites. J. Korean Phys. Soc. 45, 507–511 (2004)

20.

A.K. Geim, K.S. Novoselov, The rise of graphene. Nat. Mater. 6, 183–191 (2007)CrossRef

21.

N.A. Kotov, Materials science: carbon sheet solutions. Nature 442, 254–255 (2006)CrossRef

22.

C. Gomez-Navarro, M. Burghard, K. Kern, Elastic properties of chemically derived single graphene sheets. Nano Lett. 8, 2045–2049 (2008)CrossRef

23.

P. Avouris, Z.H. Chen, V. Perebeinos, Carbon based electronics. Nat. Nanotechnol. 2, 605–615 (2007)CrossRef

24.

Y. Li, X.B. Fan, J.J. Qi, J.Y. Ji, S.L. Wang, G.L. Zhang, F.B. Zhang, Gold nanoparticles–graphene hybrids as active catalysts for Suzuki reaction. Mater. Res. Bull. 45, 1413–1418 (2010)CrossRef

25.

Z.F. Liu, Q. Liu, Y. Huang, Y.F. Ma, S.G. Yin, X.Y. Zhang, W. Sun, Y.S. Chun, Organic photovoltaic devices based on a novel acceptor material: graphene. Adv. Mater. 20, 3924–3930 (2008)CrossRef

26.

X. Wang, L.J. Zhi, K. Mullen, Transparent, conductive graphene electrodes for dyesensitized solar cells. Nano Lett. 8, 323–327 (2008)CrossRef

27.

S. Park, R.S. Ruoff, Chemical methods for the production of graphenes. Nat. Immunol. 4, 217–224 (2009)

28.

D.R. Dreyer, S. Park, C.W. Bielawski, R.S. Ruoff, The chemistry of graphene oxide. Chem. Soc. Rev. 39, 228–240 (2010)CrossRef

29.

G.M. Joshi, K. Deshmukh, Electrical characterization of polymer composite gel under biasing as polar medium. Ionics 20(4), 529–534 (2013)CrossRef

30.

S. Morariu, D. Rusu, In situ gelation of aqueous solutions of entangled poly(vinyl alcohol). Soft Matter 9, 1244–1253 (2013)CrossRef

31.

G.M. Joshi, T. Cuberes, Ionics, DC bias function of electrical characterization of PVA inducted nickel chloride composite film. Ionics 19(6), 947–950 (2013)CrossRef

32.

S. Marino, G.M. Joshi, A. Lusuardia, M.T. Cuberesa, Ultrasonic force microscopy on poly(vinyl alcohol)/SrTiO3 nano-perovskites hybrid films. Ultramicroscopy 142(3), 32–39 (2014)CrossRef

33.

E. Benseddik, M. Makhlouki, J.C. Bernede, S. Lefrant, A. Pron, XPS studies of environmental stability of polypyrrole-poly(vinyl alcohol) composites. Synth. Met. 72, 237–242 (1995)CrossRef

34.

W.S. Hummers, R.E. Offman, Preparation of graphitic oxide. J. Am. Chem. Soc. 80, 1339 (1958)CrossRef

35.

K. Deshmukh, S.M. Khatake, G.M. Joshi, Surface properties of graphene oxide reinforced polyvinylchloride nanocomposites. J. Polym. Res. 20, 286–296 (2013)CrossRef

36.

K. Deshmukh, G.M. Joshi, Novel nanocomposites of graphene oxide reinforced poly (3,4-ethylenedioxythiophene)-block-poly (ethylene glycol) and polyvinylidene fluoride for embedded capacitor applications. RSC Adv. 4, 37954–37963 (2014)CrossRef

37.

K. Deshmukh, G.M. Joshi, Thermo-mechanical properties of poly (vinyl chloride)/graphene oxide as high performance nanocomposites. Polym. Test. 34, 211–219 (2014)CrossRef

38.

L.A.A. Pettersson, S. Ghosh, O. Inganas, Optical anisotropy in thin films of poly (3,4-ethylenedioxythiophene)–poly (4-styrenesulfonate). Org. Electron. 3, 143–148 (2002)CrossRef

39.

Z. Ni, Y. Wang, T. Yu, Z. Shen, Raman spectroscopy and imaging of graphene. Nano Res. 1, 273–291 (2008)CrossRef

40.

R. Koizhaiganova, H.J. Kim, T. Vasudevan, S. Kudaibergenov, M.S. Lee, In situ polymerization of 3-hexylthiophene with double-walled carbon nanotubes: studies on the conductive nanocomposite. J. Appl. Polym. Sci. 115, 2448–2454 (2010)CrossRef

41.

S. Selvaganesh, J. Mathiyarasu, K. Phani, V. Yegnaraman, Chemical synthesis of PEDOT–Au nanocomposite. Nano Scale Res. Lett. 2, 546–549 (2007)CrossRef

42.

N. Ning, X. Bai, D. Yang, I. Zhang, Y. Lu, T. Nishi, M. Tian, Dramatically improved dielectric properties of polymer composites by controlling the alignment of carbon nanotubes in matrix. RSC Adv. 4, 4543–4551 (2014)CrossRef

43.

G.M. Joshi, S.M. Khatake, S. Kaleemulla, N.M. Rao, T. Cuberes, Effect of dopant and DC bias potential on dielectric properties of polyvinyl alcohol (PVA)/PbTiO₃-composite films. Curr. Appl. Phys. 11(6), 1322–1335 (2011)CrossRef

44.

K. Deshmukh, G.M. Joshi, Embedded capacitor applications of graphene oxide reinforced poly (3,4-ethylenedioxythiophene)-tetramethacrylate (PEDOT-TMA) composites. J. Mater. Sci. Mater. Electron. 26(8), 5896–5909 (2015)CrossRef

Title: Study of conjugated polymer/graphene oxide nanocomposites as flexible dielectric medium
Authors: Girish M. Joshi
Kalim Deshmukh
Publication date: 11-12-2015
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 4/2016
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-015-4172-z

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Springer Professional "Wirtschaft"

Other articles of this Issue 4/2016

EPR and optical properties of green emitting Mn-doped BaMgAl10O17 nano-phosphors prepared by a combustion reaction

Nonvolatile bio-memristor fabricated with natural bio-materials from spider silk

Optical and reliability properties studies of green YAG phosphors by Ga substitution

The electromagnetic and microwave absorbing properties of polycrystalline Y-type Ba1.5Sr0.5CoZnFe12−xAlxO22 hexaferrites over the microwave range

Synthesis, mechanical properties and thermal stability of the functional reduced graphene oxide/bisphenol A cyanate ester nanocomposites

Effect of Li and Bi co-substituted on structural and physical properties of BaTiO3 ceramics