Top

Colloid and Polymer Science

Published in:

05-10-2017 | Original Contribution

Study of interaction between chitosan and sodium lauryl ether sulfate

Authors: Lidija Petrović, Jelena Milinković, Jadranka Fraj, Sandra Bučko, Jaroslav Katona, Ljiljana Spasojević

Published in: Colloid and Polymer Science | Issue 12/2017

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Chitosan is a biopolymer that has many potential applications in the industry because of its unique physicochemical properties. Many of these properties depend on its ability to interact with surfactants. The purpose of this study was to investigate interactions between chitosan (Ch), a cationic polysaccharide, and sodium lauryl ether sulfate (SLES), an anionic surfactant with ethylene oxide groups in the polar part of the molecule, in aqueous solution. Changes in the Ch/SLES mixtures were monitored by turbidity, surface tension, electrophoretic mobility, and viscosity measurements. Obtained results show that electrostatic interactions that occur at low SLES concentrations were less pronounced than hydrophobic. The region of hydrophobic interactions was linearly dependent on the concentration of the polymer, so that it ends at Ch/SLES mass ratio 1:3 by forming neutral complexes, which were completely precipitated as a coacervate phase. The research also demonstrates that small variations in structure of anionic surfactant (SDS and SLES) can lead to significant differences in interactions with cationic polymer-chitosan.

previous article Synthesis, characterization, and physicochemical properties of a series of quaternary gemini surfactants with different spacer lengths

next article Steady/unsteady electroosmotic flow through nanochannel filled with electrolyte solution surrounded by an immiscible liquid

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Touhami Y, Rana D, Neale GH, Hornof V (2001) Study of polymer-surfactant interactions via surface tension measurements. Colloid Polym Sci 279:297–300CrossRef

Goddard DE (2002) Polymer/surfactant interaction: interfacial aspects. J Colloid Interface Sci 256:228–235. https://doi.org/10.1006/jcis.2001.8066 CrossRef

Holmberg K, Jonsson B, Kronberg B, Lindman B (2002) Surfactants and polymers in aqueous solution. John Wiley and Sons, New YorkCrossRef

Mesa CL (2005) Polymer-surfactant and protein-surfactant interactions. J Colloid Interface Sci 286:148–157. https://doi.org/10.1016/j.jcis.2004.12.038 CrossRef

Taylor DJF, Thomas RK, Penfold J (2007) Polymer/surfactant interactions at the air/water interface. Adv Colloid Interf Sci 132:69–110. https://doi.org/10.1016/j.cis.2007.01.002 CrossRef

Sinha VR, Singla AK, Wadhawan S, Kaushik R, Kumria R, Bansal K, Dhawan S (2004) Chitosan microspheres as a potential carrier for drugs. Int J Pharm 274:1–33. https://doi.org/10.1016/j.ijpharm.2003.12.026 CrossRef

Berger J, Reist M, Mayer JM, Felt O, Gurny R (2004) Structure and interactions in chitosan hydrogels formed by complexation or aggregation for biomedical applications. Eur J Pharm Biopharm 57:35–52. https://doi.org/10.1016/S0939-6411(03)00160-7 CrossRef

Rosca C, Popa MI, Lisa G, Chitanu GC (2005) Interaction of chitosan with natural or synthetic anionic polyelectrolytes. 1. The chitosan-carboxymethylcellulose complex. Carbohydr Polym 62:35–41. https://doi.org/10.1016/j.carbpol.2005.07.004 CrossRef

Claesson PM, Barry WN (1992) pH-dependent interactions between adsorbed chitosan layers. Langmuir 8:1406–1412CrossRef

10.

Rinaudo M, Pavlov G, Desbrières J (1999) Influence of acetic acid concentration on the solubilization of chitosan. Polymer 40:7029–7032. https://doi.org/10.1016/S0032-3861(99)00056-7 CrossRef

11.

Kumar MNVR (2000) A review of chitin and chitosan applications. React Funct Polym 46:1–27. https://doi.org/10.1016/S1381-5148(00)00038-9 CrossRef

12.

Kumar MNVR, Muzzarelli RAA, Muzzarelli C, Sashiwa H, Domb AJ (2004) Chitosan chemistry and pharmaceutical perspectives. Chem Rev 104:6017–6084. https://doi.org/10.1021/cr030441b CrossRef

13.

Chiappisi L, Gradzielski M (2015) Co-assembly in chitosan-surfactant mixtures: thermodynamics, structure, interfacial properties and application. Adv Colloid Interf Sci 220:92–107. https://doi.org/10.1016/j.cis.2015.03.003 CrossRef

14.

Rinaudo M, Auzely R, Vallin C, Mullagaliev I (2005) Specific interactions in modified chitosan systems. Biomacromolecules 6:2396–2407. https://doi.org/10.1021/bm0580025 CrossRef

15.

Rinaudo M (2006) Chitin and chitosan: properties and applications. Prog Polym Sci 31:603–632. https://doi.org/10.1016/j.progpolymsci.2006.06.001 CrossRef

16.

Lee KY (2007) Chitosan and its derivatives for gene delivery. Macromol Res 15(3):195–201CrossRef

17.

Younes I, Rinaudo M (2015) Chitin and chitosan preparation from marine sources. Structure, properties and applications. Mar Drugs 13:1133–1174. https://doi.org/10.3390/md13031133 CrossRef

18.

Goddard DE (1993) Interaction of surfactants with polymers and proteins. Application of polymer–surfactant systems. FL: CRC Press, Boca Raton, pp. 395–413

19.

Onesippe C, Lagerge S (2008) Studies of the association of chitosan and alkylated chitosan with oppositely charged sodium dodecyl sulfate. Colloids Surf A Physicochem Eng Asp 330:201–206. https://doi.org/10.1016/j.colsurfa.2008.07.054 CrossRef

20.

Petrovic L, Sovilj V, Katona J, Milanovic J (2010) Influence of polymer–surfactant interactions on o/w emulsion properties and microcapsule formation. J Colloid Sci 342:333–339. https://doi.org/10.1016/j.jcis.2009.10.077 CrossRef

21.

Katona J, Sovilj V, Petrović L, Mucić N (2010) Tensiometric investigation of the interaction and phase separation in a polymer mixture–ionic surfactant ternary system. J Serb Chem Soc 75(6):823–831. https://doi.org/10.2298/JSC100112056K CrossRef

22.

Petrović L, Milinković J, Fraj J, Bučko S, Katona J (2016) An investigation of chitosan and sodium dodecyl sulfate interactions in acetic media. J Serb Chem Soc 81(5):575–587. https://doi.org/10.2298/JSC151119024P

23.

Im SH, Ryoo JJ (2009) Characterization of sodium laureth sulfate by reversed-phase liquid chromatography with evaporative light scattering detection and 1H nuclear magnetic resonance spectroscopy. J Chromatogr A 1216:2339–2344. https://doi.org/10.1016/j.chroma.2009.01.005 CrossRef

24.

Peretz S, Spiroiu FM, Anghel DF, Stoian C, Zgherea G (2013) Chitosan microparticulate systems prepared by polymer-surfactant interaction. Rev Roum Chim 58(2–3):275–281

25.

Vleugels LFW, Pollet J, Tuinier R (2015) Polycation−sodium lauryl ether sulfate-type surfactant complexes: influence of ethylene oxide length. J Phys Chem B 119:6338−6347. https://doi.org/10.1021/acs.jpcb.5b02043 CrossRef

26.

Aoudia M, Maamari T, Salmi F (2009) Intramolecular and intermolecular ion–dipole interactions in sodium lauryl ether sulfates (SLES) self-aggregation and mixed micellization with Triton X-100. Colloids Surf A Physicochem Eng Asp 335:55–61. https://doi.org/10.1016/j.colsurfa.2008.10.026 CrossRef

27.

Yuan Y, Chesnutt BM, Haggard WO, Bumgardner JD (2011) Deacetylation of chitosan: material characterization and in vitro evaluation via albumin adsorption and pre-osteoblastic cell cultures. Materials 4:1399–1416. https://doi.org/10.3390/ma4081399 CrossRef

28.

Grant J, Lee H, Roger C, Liu W, Allen C (2008) Intermolecular interactions and morphology of aqueous polymer/surfactant mixtures containing cationic chitosan and nonionic sorbitan esters. Biomacromolecules 9:2146–2152. https://doi.org/10.1021/bm800219m CrossRef

29.

Milanović J, Petrović L, Sovilj V, Katona J (2014) Complex coacervation in gelatin/sodium caseinate mixtures. Food Hydrocoll 37:196–202. https://doi.org/10.1016/j.foodhyd.2013.10.016 CrossRef

30.

Babak VG, Desbrieres J (2006) Dynamic surface tension and dilational viscoelasticity of adsorption layers of alkylated chitosans and surfactant−chitosan complexes. Colloid Polym Sci 284:745–754. https://doi.org/10.1007/s00396-005-1427-x CrossRef

31.

Onesippe C, Lagerge S (2008) Study of the complex formation between sodium dodecyl sulfate and chitosan. Colloids Surf A Physicochem Eng Asp 317:100–108. https://doi.org/10.1016/j.colsurfa.2007.10.002 CrossRef

32.

Myers D (1996) Surfactant science and technology, 3rd edn. Johan Wiley and Sons, Hoboken

33.

Voisin D, Vincent B (2003) Flocculation in mixtures of cationic polyelectrolytes and anionic surfactants. Adv Colloid Interf Sci 106:1−22. https://doi.org/10.1016/S0001-8686(03)00103-9 CrossRef

Title: Study of interaction between chitosan and sodium lauryl ether sulfate
Authors: Lidija Petrović
Jelena Milinković
Jadranka Fraj
Sandra Bučko
Jaroslav Katona
Ljiljana Spasojević
Publication date: 05-10-2017
Publisher: Springer Berlin Heidelberg
Published in: Colloid and Polymer Science / Issue 12/2017
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-017-4205-7

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 12/2017

Methods of increasing hydrophobicity of polyurethane materials: important applications of coatings with low surface free energy

Analytical and preparative polymethacrylate monolith fabrication: effect of porogen content and column size on pore morphology

Effects of hydrophilic groups of curing agents on the properties of flame-retardant two-component waterborne coatings

Simulation study on the conformational properties of an adsorbed polymer on a nanoparticle

Preparation and properties of poly (propylene carbonate)-based waterborne polyurethane-acrylate composite emulsion

Interaction of oxy-diester-linked cationic gemini surfactants with nonionic amphiphiles in aqueous medium

Premium Partners