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Journal of Materials Science
Published in: Journal of Materials Science 1/2015

01-01-2015 | Original Paper

Subsolidus phase relations of Li2O–FeO–P2O5 system and the solid solubility of Li1+x Fe1−x PO4 compounds under Ar/H2 atmosphere

Authors: Xinghao Lin, Yanming Zhao, Youzhong Dong, Zhiyong Liang, Danlin Yan, Xudong Liu, Quan Kuang

Published in: Journal of Materials Science | Issue 1/2015

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Abstract

The phase relation of Li2O–FeO–P2O5 ternary system under the 95 %Ar + 5 %H2 atmosphere has been systematically investigated by X-ray diffraction (XRD), and there exist 8 binary compounds, 4 ternary compounds, 2 two-phase regions, and 17 three-phase regions. No other new lithium ferrous phosphates can be existed in the Li2O–FeO–P2O5 ternary system under the 95 %Ar + 5 %H2 atmosphere. In this system, the Li1+x Fe1−x PO4 solid solution phase with the homogeneous range of −0.15 ≤ x ≤ 0.06 is determined. Their corresponding lattice parameters are obtained by the refinement results, and the results show that the lattice parameters (a, b, c, V) vary linearly with the increasing amount of excess Li-ion (x > 0) or with the increasing amount of excess Fe-ion (x < 0). The phase diagram determined in this paper can provide more information about the phase relation of Li2O–FeO–P2O5 ternary system and serve as a guide for the future investigation of lithium iron phosphates in this system.
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Literature
1.
Anolini E (2004) LiCoO2: formation, structure, lithium and oxygen nonstoichiometry, electrochemical behaviour and transport properties. Solid State Ionics 170:159–171CrossRef
2.
Thomas MGSR, David WIF, Goodenough JB (1985) Synthesis and structural characterization of the normal spinel Li[Ni2]O4. Mater Res Bull 20:1137–1146CrossRef
3.
Kanamura K, Naito H, Yao T, Takehara Z (1996) Structure change of the LiMn2O4 spinel structure induced by extraction of lithium. J Mater Chem 6:33–36CrossRef
4.
Lu ZH, MacNeil DD, Dahn JR (2001) Layered Li[NixCo1-2xMnx]O2 cathode materials for lithium-Ion batteries. Electrochem Solid-State Lett 4:A200–A203CrossRef
5.
Padhi AK, Nanjundaswamy KS, Goodenough JB (1997) Phospho-olivines as positive-electrode materials for rechargeable lithium batteries. J Electrochem Soc 144:1188–1194CrossRef
6.
Chung SY, Bloking JT, Chiang YM (2002) Electronically conductive phospho-olivines as lithium storage electrodes. Nat Mater 1:123–128CrossRef
7.
MacNeil DD, Lu ZH, Chen ZH, Dahn JR (2002) A comparison of the electrode/electrolyte reaction at elevated temperatures for various Li-ion battery cathodes. J Power Sources 108:8–14CrossRef
8.
Takahashi M, Tobishima S, Takei K, Sakurai Y (2002) Reaction behavior of LiFePO4 as a cathode material for rechargeable lithium batteries. Solid State Ionics 148:283–289CrossRef
9.
Ravet N, Chouinard Y, Magnan JF, Besner S, Gauthier M, Armand M (2001) Electroactivity of natural and synthetic triphylite. J Power Sources 97–98:503–507CrossRef
10.
11.
Wang JJ, Sun XL (2012) Understanding and recent development of carbon coating on LiFePO4 cathode materials for lithium-ion batteries. Energy Environ Sci 5:5163–5185CrossRef
12.
Yi TF, Li XY, Liu HP, Shu J, Zhu YR, Zhu RS (2012) Recent developments in the doping and surface modification of LiFePO4 as cathode material for power lithium ion battery. Ionics 18:529–539CrossRef
13.
Churikov AV, Ivanishchev AV, Ushakov AV, Gamayunova IM, Leenson IA (2013) Thermodynamics of LiFePO4 solid-phase synthesis using iron (II) oxalate and ammonium dihydrophosphate as precursors. J Chem Eng Data 58:1747–1759CrossRef
14.
Churikov A, Gribov A, Bobyl A, Kamzin A, Terukov E (2014) Mechanism of LiFePO4 solid-phase synthesis using iron (II) oxalate and ammonium dihydrophosphate as precursors. Ionics 20:1–13CrossRef
15.
Ong SP, Wang L, Kang B, Ceder G (2008) Li–Fe–P–O2 phase diagram from first principles calculations. Chem Mater 20:1798–1807CrossRef
16.
Ji LN, Li JB, Chen YQ, Luo J, Liang JK, Rao GH (2009) Subsolidus phase relations of the ZnO-Li2O-P2O5 system. J. Alloys Comp 486:352–356CrossRef
17.
Tien TY, Hummel FA (1961) Studies in Lithium Oxide Systems: XI, Li2O–B2O3–P2O5. J Am Ceram Soc 44:206–208CrossRef
18.
Guitel JC, Tordjman I (1976) Structural crystallography and crystal chemistry. Acta Crystallogr B 32:2960–2966CrossRef
19.
Murashova EV, Chudinova NN (2001) Synthesis and crystal structures of lithium polyphosphates, LiPO3, Li4H(PO3)5, and LiMn(PO3)3. Crystallogr Rep 46:942–947CrossRef
20.
Ben-Chaabane T, Smiri-Dogguy L, Laligant Y, LeBail A (1998) Li6P6O18: X-ray powder structure determination of lithium cyclohexaphosphate. Eur J Solid State Inorg Chem 35:255–264CrossRef
21.
Yakubovich OV, Mel’nikov OK (1994) The crystal structure of Li4[P2O7]. Crystallogr Rep 39:737–742
22.
Daidouh A, Veiga ML, Pico C (1997) Martinez-Ripoll, M. A New Polymorph of Li4P2O7. Acta Crystallogr C 53:167–169CrossRef
23.
Keffer C, Mighell AD, Mauer F, Swanson H, Block S (1967) The Crystal Structure of Twinned Low-Temperature Lithium Phosphate. Inorg Chem 6:119–125CrossRef
24.
Bondareva OS, Simonov MA, Belov NV (1978) The crystal structure of the synthetic analogue of the lithiophospate gamma-Li3PO4. Soviet Physics–Doklady 23:287–288
25.
Weil M, Glaum R (1998) Crystallization of ultraphosphates via the gas phase. The crystal structures of FeP4011, ZnP4O11 and CdP4O11. Eur J Solid State Inorg Chem 35:495–508CrossRef
26.
Nord AG, Ericsson T, Werner PE (1990) The crystal structure of iron(II) tetrametaphosphate Fe2P4O12. Zeitschrift fuer Kristallographie 192:83–90
27.
Hoggins JT, Swinnea JS, Steinfink H (1983) Crystal structure of Fe2P2O7. J Solid State Chem 47:278–283CrossRef
28.
Stefanidis T, Nord AG (1982) The crystal structure of iron(II) diphosphate, Fe2P2O7. Zeitschrift fuer Kristallographie 159:255–264
29.
Parada C, Perles J, Saez-Puche R, Ruiz-Valero C (2003) Snejko N. Crystal growth, structure and magnetic properties of a new polymorph of Fe2P2O7. Chem Mater 15:3347–3351CrossRef
30.
Kostiner E, Rea JR (1974) Crystal structure of ferrous phosphatefe2(P2O4)2. Inorg Chem 13:2876–2880CrossRef
31.
Warner JK, Cheetham AK, Nord AG, von Dreele RB, Yethiraj M (1992) Magnetic structure of iron(II) phosphate, sarcopside, Fe3(PO4)2. J Mater Chem 2:191–196CrossRef
32.
Bouchdoug M, Courtois A, Gerardin R, Steinmetz J, Gleitzer C (1982) Preparation et etude d’un oxyphosphate Fe4(PO4)2O. J Solid State Chem 42:149–157CrossRef
33.
Dong YZ, Zhao YM, Fu P, Zhou H, Hou XM (2008) Phase relations of Li2O-FeO-B2O3 ternary system and electrochemical properties of LiFeBO3 compound. J. Alloys Comp 461:585–590CrossRef
34.
Liang ZY, Zhao YM, Ouyang LZ, Dong YZ, Kuang Q, Lin XH, Liu XD, Yan DL (2014) Synthesis of carbon-coated Li3VO4 and its high electrochemical performance as anode material for lithium-ion batteries. J Power Sources 252:244–247CrossRef
35.
Garcia-Moreno O, Alvarez-Vega M, Garcia-Alvarado F, Garcia-Jaca J, Amores JMG, Sanjuan ML, Amador U (2001) Influence of the structure on the electrochemical performance of lithium transition metal phosphates as cathodic materials in rechargeable lithium batteries: A new high-pressure form of LiMPO4(M)Fe and Ni). Chem Mater 13:1570–1576CrossRef
36.
Bjoerling CO, Westgren A (1938) Minerals of the Varutrask pegmatite: IX. X-ray studies on triphylite, varulite, and their oxidation products. Geologiska Foereningens i Stockholm Foerhandlingar 60:67–72CrossRef
37.
Delacourt C, Rodriguez-Carvajal J, Schmitt B, Tarascon JM, Masquelier C (2005) Crystal chemistry of the olivine-type Li x FePO4 system (0 ≤ x ≤ 1) between 25 and 370◦C. Solid State Sci 7:1506–1516CrossRef
38.
Yakubovich OV, Simonov MA, Belov NV (1977) The crystal structure of a synthetic triphylite LiFe(PO4). Soviet Physics–Doklady 22:347–348
39.
Nishimura H, Nakamura M, Natsui R, Yamada A (2010) New Lithium Iron Pyrophosphate as 3.5 V Class Cathode Material for Lithium Ion Battery. J Am Chem Soc 132:13596–13597CrossRef
40.
Ramana CV, Ait-Salah A, Julien CM (2006) Structure of LiFe2P3O10 studied by transmission electron microscopy. Mater Sci Eng, B 135:78–81CrossRef
41.
Genkina EA, Maksimov BA, Kabalov YK, Mel’nikov OE (1983) Crystal structure of Li, Fe metaphosphate LiFeP3O9. Soviet Physics–Doklady 28:426–428
42.
Zhuang VV, Allen JL, Ross PN, Guo J-H, Jow TR (2006) Electronic properties of LiFePO4 and Li doped LiFePO4. ECS Trans 1:69–72CrossRef
Metadata
Title
Subsolidus phase relations of Li2O–FeO–P2O5 system and the solid solubility of Li1+x Fe1−x PO4 compounds under Ar/H2 atmosphere
Authors
Xinghao Lin
Yanming Zhao
Youzhong Dong
Zhiyong Liang
Danlin Yan
Xudong Liu
Quan Kuang
Publication date
01-01-2015
Publisher
Springer US
Published in
Journal of Materials Science / Issue 1/2015
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8579-3

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