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Topics in Catalysis
Published in: Topics in Catalysis 4-6/2015

01-04-2015 | Original Paper

Support Effects of Ni2P Catalysts on the Hydrodeoxygenation of Guaiacol: In Situ XAFS Studies

Authors: Ji-Sue Moon, Yong-Kul Lee

Published in: Topics in Catalysis | Issue 4-6/2015

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Abstract

The hydrodeoxygenation (HDO) of guaiacol was investigated over SiO2, ZrO2, and active carbon (AC) supported Ni2P catalysts. The physical properties of the catalysts were analyzed by temperature-programmed reduction (H2-TPR), CO-uptake chemisorption, and N2 physisorption. X-ray diffraction and extended X-ray adsorption fine structure spectroscopy were used to obtain structural properties for the supported Ni2P catalysts. The HDO was tested in a batch reactor at 573 K and 30 atm. The Ni2P/SiO2 catalyst underwent a decrease in the HDO conversion from 87 to 30 % for the first and second run of reaction. However, the Ni2P/ZrO2 and Ni2P/AC catalysts showed a little low but stable HDO conversions of 72 and 46 %, respectively. The in situ XAFS analysis revealed that differently from the cases of Ni2P/ZrO2 or and Ni2P/AC catalysts, the local structure of the Ni2P on SiO2 support underwent an oxidation to form nickel phosphate during the reaction, demonstrating that the SiO2 based Ni2P was vulnerable to the water or hydroxyl group of the reactant due to the hydrophilic nature of SiO2 support.
previous article Production of Phenol and Cresol from Guaiacol on Nickel Phosphide Catalysts Supported on Acidic Supports
next article Active Sites in Ni2P/USY Catalysts for the Hydrodeoxygenation of 2-Methyltetrahydrofuran

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Literature
1.
2.
Bridgwater AV (1996) Production of high grade fuels and chemicals from catalytic pyrolysis of biomass. Catal Today 29:285–295CrossRef
3.
Bulushev DA, Ross JRH (2011) Catalysis for conversion of biomass to fuels via pyrolysis and gasification: A review. Catal Today 171:1–13CrossRef
4.
Gayubo AG, Aguayo AT, Atuxtxa A, Aguado R, Olazar M, Bilbao J (2004) Transformation of oxygenate components of biomass pyrolysis oil on a HZSM-5 zeolite. II. Aldehydes, ketones, and acids. Ind Eng Chem Res 43:2619–2626CrossRef
5.
Huber GW, Iborra S, Corma A (2006) Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. Chem Rev 106:4044–4098CrossRef
6.
Bui VN, Laurenti D, Afanasiev P, Geantet C (2011) Hydrodeoxygenation of guaiacol with CoMo Catalysts. Part I: promoting effect of cobalt on HDO selectivity and activity. Appl Catal B 101:239–245CrossRef
7.
Bui VN, Laurenti D, Afanasiev P, Geantet C (2011) Hydrodeoxygenation of guaiacol. Part II: support effect for CoMoS catalysts on HDO activity and selectivity. Appl Catal B 101:246–255CrossRef
8.
Gevert BS, Otterstedt JE, Massoth FE (1987) Kinetics of the HDO of methyl-substituted phenols. Appl Catal 31:119–131CrossRef
9.
Dupont C, Lemeur R, Daudin A, Raybaud P (2011) Hydrodeoxygenation pathways catalyzed by MoS2 and NiMoS active phases: a DFT study. J Catal 279:276–286CrossRef
10.
Popov A, Kondratieva E, Mariey L, Goupil JM, El Fallah J, Gilson JP, Travert A, Maugé F (2013) Bio-oil hydrodeoxygenation: adsorption of phenolic compounds on sulfided (Co)Mo catalysts. J Catal 297:176–186CrossRef
11.
Şenol OI, Ryymin EM, Viljava TR, Krause AOI (2007) Effect of hydrogen sulphide on the hydrodeoxygenation of aromatic and aliphatic oxygenates on sulphided catalysts. J Mol Catal A-Chem 277:107–112CrossRef
12.
Romero Y, Richard F, Brunet S (2010) Hydrodeoxygenation of 2-ethylphenol as a model compound of bio-crude over sulfided Mo-based catalysts: promoting effect and reaction mechanism. Appl Catal B 98:213–223CrossRef
13.
Romero Y, Richard F, Renème Y, Brunet S (2009) Hydrodeoxygenation of benzofuran and its oxygenated derivatives (2,3-dihydrobenzofuran and 2-ethylphenol) over NiMoP/Al2O3 catalyst. Appl Catal A 353:46–53CrossRef
14.
Ferrari M, Maggi R, Delmon B, Grange P (2001) Influences of the hydrogen sulfide partial pressure and of a nitrogen compound on the hydrodeoxygenation activity of a CoMo/carbon catalyst. J Catal 198:47–55CrossRef
15.
Ferrari M, Delmon B, Grange P (2002) Influence of the impregnation order of molybdenum and cobalt in carbon-supported catalysts for hydrodeoxygenation reactions. Carbon 40:497–511CrossRef
16.
Gutierrez A, Kaila RK, Honkela M, Slioor R, Krause AOI (2009) Hydrodeoxygenation of guaiacol on noble metal catalysts. Catal Today 147:239–246CrossRef
17.
Ardiyanti AR, Gutierrez A, Honkela ML, Krause AOI, Heeres HJ (2011) Hydrotreatment of wood-based pyrolysis oil using zirconia-supported mono- and bimetallic (Pt, Pd, Rh) catalysts. Appl Catal A 407:56–66CrossRef
18.
Wang W, Yang Y, Luo H, Hu T, Liu W (2011) Amorphous Co-Mo-B catalyst with high activity for the hydrodeoxygenation of bio-oil. Catal Comm 12:436–440CrossRef
19.
Sun J, Karim AM, Zhang H, Kovarik L, Li XS, Hensley AJ, McEwen JS, Wang Y (2013) Carbon-supported bimetallic Pd-Fe catalysts for vapor-phase hydrodeoxygenation of guaiacol. J Catal 306:47–57CrossRef
20.
Zhao C, He J, Lemonidou AA, Li X, Lercher JA (2011) Aqueous-phase hydrodeoxygenation of bio-derived phenols to cycloalkanes. J Catal 280:8–16CrossRef
21.
Zhu X, Lobban LL, Mallinson RG, Resasco DE (2011) Bifunctional transalkylation and hydrodeoxygenation of anisole over a Pt/HBeta catalys. J Catal 281:21–29CrossRef
22.
Kim YT, Dumesic JA, Huber GW (2013) Aqueous-phase hydrodeoxygenation of sorbitol: a comparative study of Pt/Zr phosphate and PtReOx/C. J Catal 304:72–85CrossRef
23.
Bui P, Cecilia JA, Oyama ST, Takagaki A, Infantes-Molina A, Zhao H, Li D, Rodríguez-Castellón E, Jiménez López A (2012) Studies of the synthesis of transition metal phosphides and their activity in the hydrodeoxygenation of a biofuel model compound. J Catal 294:184–198CrossRef
24.
De La Puente G, Gil A, Pis JJ, Grange P (1999) Effects of support surface chemistry in hydrodeoxygenation reactions over CoMo/activated carbon sulfided catalysts. Langmuir 15:5800–5806CrossRef
25.
Laurent E, Delmon B (1994) Study of the hydrodeoxygenation of carbonyl, carboxylic and guaiacyl groups over sulfided CoMo/γ-Al2O3 and NiMo/γ-Al2O3 catalysts. I. Catalytic reaction schemes. Appl Catal A 109:77–96CrossRef
26.
Zakzeski J, Bruijnincx PCA, Jongerius AL, Weckhuysen BM (2010) The catalytic valorization of lignin for the production of renewable chemicals. Chem Rev 110:3552–3599CrossRef
27.
Laurent E, Delmon B (1994) Study of the hydrodeoxygenation of carbonyl, carboxylic and guaiacyl groups over sulfided CoMo/γ-Al2O3 and NiMo/γ-Al2O3 catalyst. II. Influence of water, ammonia and hydrogen sulfide. Appl Catal A 109:97–115CrossRef
28.
Laurent E, Delmon B (1994) Influence of water in the deactivation of a sulfided NiMo γ-Al2O3 catalyst during hydrodeoxygenation. J Catal 146(281–285):288–291
29.
Moon JS, Kim EG, Lee YK (2014) Active sites of Ni2P/SiO2 catalyst for hydrodeoxygenation of guaiacol: a joint XAFS and DFT study. J Catal 311:144–152CrossRef
30.
Centeno A, Laurent E, Delmon B (1995) Influence of the Support of CoMo Sulfide Catalysts and of the Addition of Potassium and Platinum on the Catalytic Performances for the Hydrodeoxygenation of Carbonyl, Carboxyl, and Guaiacol-Type Molecules. J Catal 154:288–298CrossRef
31.
Wu SK, Lai PC, Lin YC, Wan HP, Lee HT, Chang YH (2013) Atmospheric hydrodeoxygenation of guaiacol over alumina-, zirconia-, and silica-supported nickel phosphide catalysts. ACS Sustainable Chem Eng 1:349–358CrossRef
32.
Nimmanwudipong T, Aydin C, Lu J, Runnebaum RC, Brodwater KC, Browning ND, Block DE, Gates BC (2012) Selective hydrodeoxygenation of guaiacol catalyzed by platinum supported on magnesium oxide. Catal Lett 142:1190–1196CrossRef
33.
Gevert BS, Otterstedt JE, Massoth FE (1987) Kinetics of the HDO of methyl-substituted phenols. Appl Catal 31:119–131CrossRef
34.
Kresse G, Hafner J (1993) Ab initio molecular dynamics for liquid metals. Phys Rev B: Condens Matter 47:558–561CrossRef
35.
Lee YK, Oyama ST (2006) Bifunctional nature of a SiO2-supported Ni2P catalyst for hydrotreating: EXAFS and FTIR studies. J Catal 239:376–389CrossRef
36.
Oyama ST, Wang X, Lee YK, Chun WJ (2004) Active phase of Ni2P/SiO2 in hydroprocessing reactions. J Catal 221:263–273CrossRef
37.
Seo HR, Cho KS, Lee YK (2011) Formation mechanisms of Ni2P nanocrystals using XANES and EXAFS spectroscopy. Mater. Sci. Eng B 176:132–140CrossRef
38.
Zhuravelev LT (2000) The surface chemistry of amorphous silica Zhuravlev model. Colloids Surf B 173:1–38CrossRef
Metadata
Title
Support Effects of Ni2P Catalysts on the Hydrodeoxygenation of Guaiacol: In Situ XAFS Studies
Authors
Ji-Sue Moon
Yong-Kul Lee
Publication date
01-04-2015
Publisher
Springer US
Published in
Topics in Catalysis / Issue 4-6/2015
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-015-0362-4

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