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Published in: Colloid and Polymer Science 3/2011

01-02-2011 | Original Contribution

Surface active and aggregation behavior of methylimidazolium-based ionic liquids of type [C n mim] [X], n = 4, 6, 8 and [X] = Cl, Br, and I in water

Authors: Nilesh M. Vaghela, Nandhibatla V. Sastry, Vinod K. Aswal

Published in: Colloid and Polymer Science | Issue 3/2011

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Abstract

The surface active and aggregation behavior of ionic liquids of type [C n mim][X] (1-alkyl-3-methylimidazolium (mim) halides), where n = 4, 6, 8 and [X] = Cl, Br and I was investigated by using three techniques: surface tension, 1H nuclear magnetic resonance (NMR) spectroscopy, small-angle neutron scattering (SANS). A series of parameters including critical aggregation concentrations (CAC), surface active parameters and thermodynamic parameters of aggregation were calculated. The 1H NMR chemical shifts and SANS measurements reveal no evidence of aggregates for the short-chain 1-butylmim halides in water and however small oblate ellipsoidal shaped aggregates are formed by ionic liquids with 1-hexyl and 1-octyl chains. Analysis of SANS data analysis at higher concentrations of [C8mim][Cl] showed that the microstructures consist of cubically packed molecules probably through ππ and hydrogen bond interactions.

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Appendix
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Metadata
Title
Surface active and aggregation behavior of methylimidazolium-based ionic liquids of type [C n mim] [X], n = 4, 6, 8 and [X] = Cl−, Br−, and I− in water
Authors
Nilesh M. Vaghela
Nandhibatla V. Sastry
Vinod K. Aswal
Publication date
01-02-2011
Publisher
Springer-Verlag
Published in
Colloid and Polymer Science / Issue 3/2011
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-010-2332-5

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