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Journal of Nanoparticle Research

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01-10-2016 | Research Paper

Synthesis and characterization of magnetic silica-supported Mn(II)-substituted polyoxophosphotungstate as catalyst in sulfoxidation reaction

Authors: Zeinab Moradi-Shoeili, Maryam Zare, Mojtaba Bagherzadeh

Published in: Journal of Nanoparticle Research | Issue 10/2016

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Abstract

Polyoxometalate-functionalized magnetic nanoparticles (Fe₃O₄@SiO₂–MnPOW) were successfully synthesized via covalent anchoring of Mn(II)-substituted phosphotungstate on ammonium-modified Fe₃O₄@SiO₂ nanoparticles. The complete characterization of nanoparticles has been carried out by scanning electron microscope, energy-dispersive X-ray, X-ray diffraction, Fourier transform infrared and elemental analysis. The resulting nanocomposites were efficient catalysts for the selective oxidation of sulfides with different green oxidants in good to excellent yields and also high selectivity. Leaching and recycling tests showed that the nanocatalyst can be reused several times without significant loss of efficiency.

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Title: Synthesis and characterization of magnetic silica-supported Mn(II)-substituted polyoxophosphotungstate as catalyst in sulfoxidation reaction
Authors: Zeinab Moradi-Shoeili
Maryam Zare
Mojtaba Bagherzadeh
Publication date: 01-10-2016
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 10/2016
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-016-3609-5

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