Skip to main content
Top
Published in: Polymer Bulletin 10/2018

07-02-2018 | Original Paper

Synthesis and characterization of polypyrrole thin film by MW-CBD method for NH3 gas sensor

Authors: A. A. Yadav, S. B. Kulkarni, C. D. Lokhande

Published in: Polymer Bulletin | Issue 10/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The microwave-assisted chemical bath deposition method is used for synthesis of polypyrrole (Ppy) thin film. The structural, morphological, optical absorption and wettability properties of deposited Ppy thin films are studied using various characterization techniques. The X-ray diffraction pattern shows amorphous nature of Ppy thin film. To confirm the formation of Ppy compound, Fourier transform infrared spectroscopic study is used. The scanning electron microscopy study shows porous structure of Ppy thin film. The optical study revealed that Ppy thin film exhibits band gap of 3.5 eV. The Ppy film exhibited hydrophilic nature with contact angle of 41°. The Ppy films show 85% response to ammonia (NH3) gas at room temperature.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference Yan H, Zhang L, Shen J, Chen Z, Shi G, Zhang B (2006) Synthesis property and field-emission behaviour of amorphous polypyrrole nanowires. Nanotechnology 17:3446–3450CrossRefPubMed Yan H, Zhang L, Shen J, Chen Z, Shi G, Zhang B (2006) Synthesis property and field-emission behaviour of amorphous polypyrrole nanowires. Nanotechnology 17:3446–3450CrossRefPubMed
2.
go back to reference Cho JH, Yu JB, Kim JS, Sohn SO, Lee DD, Huh JS (2005) Sensing behaviours of polypyrrole sensor under humidity condition. Sens Actuator B 108:389–392CrossRef Cho JH, Yu JB, Kim JS, Sohn SO, Lee DD, Huh JS (2005) Sensing behaviours of polypyrrole sensor under humidity condition. Sens Actuator B 108:389–392CrossRef
3.
go back to reference Yadav AA, Lokhande VC, Bulakhe RN, Lokhande CD (2017) Amperometric CO2 gas sensor based on interconnected web-like nanoparticles of La2O3 synthesized by ultrasonic spray pyrolysis. Microchem Acta 184:3713–3720CrossRef Yadav AA, Lokhande VC, Bulakhe RN, Lokhande CD (2017) Amperometric CO2 gas sensor based on interconnected web-like nanoparticles of La2O3 synthesized by ultrasonic spray pyrolysis. Microchem Acta 184:3713–3720CrossRef
4.
go back to reference Wang Y, Jia WZ, Strout T, Schemp A, Zhang H, Li BK, Cui JH, Lei Y (2009) Ammonia gas sensor using polypyrrole-coated TiO2/ZnO nanofibers. Electroanalysis 21:1432–1435CrossRef Wang Y, Jia WZ, Strout T, Schemp A, Zhang H, Li BK, Cui JH, Lei Y (2009) Ammonia gas sensor using polypyrrole-coated TiO2/ZnO nanofibers. Electroanalysis 21:1432–1435CrossRef
5.
go back to reference Jiang L, Jun HK, Hoh YS, Lim JO, Lee DD, Huh JS (2005) Sensing characteristics of polypyrrole-poly(vinyl alcohol) methanol sensors prepared by in situ vapour state polymerisation. Sens Actuator B 105:132–136CrossRef Jiang L, Jun HK, Hoh YS, Lim JO, Lee DD, Huh JS (2005) Sensing characteristics of polypyrrole-poly(vinyl alcohol) methanol sensors prepared by in situ vapour state polymerisation. Sens Actuator B 105:132–136CrossRef
6.
go back to reference Melo CP, Neto BB, Lima EG, Lira LFB, Souza JEG (2005) Use of conducting polypyrrole blend as gas sensors. Sens Actuator B 109:348–354CrossRef Melo CP, Neto BB, Lima EG, Lira LFB, Souza JEG (2005) Use of conducting polypyrrole blend as gas sensors. Sens Actuator B 109:348–354CrossRef
7.
go back to reference Arora K, Chaubey A, Singhal R, Singh RP, Pandey MK, Samanta SB, Malhotra BD, Chand S (2006) Application of electrochemically prepared polypyrrole–polyvinyl sulphonate films to DNA biosensor. Biosens Bioelectron 21:1777–1783CrossRefPubMed Arora K, Chaubey A, Singhal R, Singh RP, Pandey MK, Samanta SB, Malhotra BD, Chand S (2006) Application of electrochemically prepared polypyrrole–polyvinyl sulphonate films to DNA biosensor. Biosens Bioelectron 21:1777–1783CrossRefPubMed
8.
go back to reference Suri K, Annapoorni S, Sarkar AK, Tandon RP (2002) Gas and humidity sensors based on iron oxide-polypyrrole nanocomposites. Sens Actuator B 81:277–282CrossRef Suri K, Annapoorni S, Sarkar AK, Tandon RP (2002) Gas and humidity sensors based on iron oxide-polypyrrole nanocomposites. Sens Actuator B 81:277–282CrossRef
9.
go back to reference Yadav AA, Lokhande AC, Kim JH, Lokhande CD (2017) Enhanced sensitivity and selectivity of CO2 gas sensor based on modified La2O3 nanorods. J Alloys Comp 723:880–886CrossRef Yadav AA, Lokhande AC, Kim JH, Lokhande CD (2017) Enhanced sensitivity and selectivity of CO2 gas sensor based on modified La2O3 nanorods. J Alloys Comp 723:880–886CrossRef
10.
go back to reference Huyen DN, Tung NT, Thien ND, Thanh LH (2011) Effect of TiO2 on the gas sensing seatures of TiO2/PANi. Nanocomposites Sens 11:1924–1930 Huyen DN, Tung NT, Thien ND, Thanh LH (2011) Effect of TiO2 on the gas sensing seatures of TiO2/PANi. Nanocomposites Sens 11:1924–1930
11.
go back to reference Hunge YM, Yadav AA, Mahadik MA, Bulakhe RN, Shim JJ, Mathe VL, Bhosale CH (2018) Degradation of organic dyes using spray deposited nanocrystalline stratified WO3/TiO2 photoelectrodes under sunlight illumination. Opt Mater 76:260–262CrossRef Hunge YM, Yadav AA, Mahadik MA, Bulakhe RN, Shim JJ, Mathe VL, Bhosale CH (2018) Degradation of organic dyes using spray deposited nanocrystalline stratified WO3/TiO2 photoelectrodes under sunlight illumination. Opt Mater 76:260–262CrossRef
12.
go back to reference Kim YS, Ha SC, Kim K, Yang H, Park JT, Lee CH, Choi J, Paek J, Lee K (2005) Effect room-temperature semiconductor gas sensor based on nonstoichiometric tungsten oxide nanorod film. Appl Phys Lett 86:213–215 Kim YS, Ha SC, Kim K, Yang H, Park JT, Lee CH, Choi J, Paek J, Lee K (2005) Effect room-temperature semiconductor gas sensor based on nonstoichiometric tungsten oxide nanorod film. Appl Phys Lett 86:213–215
13.
go back to reference Yadav AA, Lokhande AC, Kim JH, Lokhande CD (2016) Highly sensitive CO2 sensor based on microrods-like La2O3 thin film electrode. RSC Adv 6:106074–106080CrossRef Yadav AA, Lokhande AC, Kim JH, Lokhande CD (2016) Highly sensitive CO2 sensor based on microrods-like La2O3 thin film electrode. RSC Adv 6:106074–106080CrossRef
14.
go back to reference Hunge YM (2017) Photoelectrocatalytic degradation of 4-chlorophenol using nanostructured α-Fe2O3 thin films under sunlight illumination. J Mater Sci Mater Electron 28:11260–11263CrossRef Hunge YM (2017) Photoelectrocatalytic degradation of 4-chlorophenol using nanostructured α-Fe2O3 thin films under sunlight illumination. J Mater Sci Mater Electron 28:11260–11263CrossRef
15.
go back to reference Chougule MA, Sen S, Patil VB (2012) Effects of CuO on the morphology and conducting properties of PANI nanofibers. Synth Met 162:1598–1603CrossRef Chougule MA, Sen S, Patil VB (2012) Effects of CuO on the morphology and conducting properties of PANI nanofibers. Synth Met 162:1598–1603CrossRef
16.
go back to reference Yadav AA, Lokhande AC, Kim JH, Lokhande CD (2016) The synthesis of multifunctional porous honey comb-like La2O3 thin film for supercapacitor and gas sensor applications. J Colloid Interface Sci 484:51–59CrossRefPubMed Yadav AA, Lokhande AC, Kim JH, Lokhande CD (2016) The synthesis of multifunctional porous honey comb-like La2O3 thin film for supercapacitor and gas sensor applications. J Colloid Interface Sci 484:51–59CrossRefPubMed
17.
go back to reference Yadav AA, Lokhande AC, Kim JH, Lokhande CD (2017) Improvement in CO2 sensing characteristics using Pd nanoparticles decorated La2O3 thin films. J Ind Eng Chem 49:76–81CrossRef Yadav AA, Lokhande AC, Kim JH, Lokhande CD (2017) Improvement in CO2 sensing characteristics using Pd nanoparticles decorated La2O3 thin films. J Ind Eng Chem 49:76–81CrossRef
18.
go back to reference Hunge YM (2017) Sunlight assisted photoelectrocatalytic degradation of benzoic acid using stratified WO3/TiO2 thin films. Ceram Int 43:10089–10090CrossRef Hunge YM (2017) Sunlight assisted photoelectrocatalytic degradation of benzoic acid using stratified WO3/TiO2 thin films. Ceram Int 43:10089–10090CrossRef
19.
go back to reference Chougule MA, Pawar SG, Godse PR, Mulik RN, Sen S, Patil VB (2011) Synthesis and characterization of polypyrrole (PPy) thin films. Soft Nanosci Lett 1:1–6CrossRef Chougule MA, Pawar SG, Godse PR, Mulik RN, Sen S, Patil VB (2011) Synthesis and characterization of polypyrrole (PPy) thin films. Soft Nanosci Lett 1:1–6CrossRef
20.
go back to reference Gangopadhyay R, De A (2011) Transport properties of polypyrrole–ferric oxide conducting nanocomposites. Sens Actuator B 77:326–329CrossRef Gangopadhyay R, De A (2011) Transport properties of polypyrrole–ferric oxide conducting nanocomposites. Sens Actuator B 77:326–329CrossRef
21.
go back to reference Dubal DP, Lee SH, Kim JG, Kim WB, Lokhande CD (2012) Porous polypyrrole clusters prepared by electropolymerization for a high performance supercapacitor. J Mater Chem 22:3044–3052CrossRef Dubal DP, Lee SH, Kim JG, Kim WB, Lokhande CD (2012) Porous polypyrrole clusters prepared by electropolymerization for a high performance supercapacitor. J Mater Chem 22:3044–3052CrossRef
22.
go back to reference Romero AJ, Cascales JJ, Otero TF (2005) perchlorate interchange during the redox process of PPy/PVS Films in an acetonitrile medium. J Phys Chem B 109:21078–21085CrossRef Romero AJ, Cascales JJ, Otero TF (2005) perchlorate interchange during the redox process of PPy/PVS Films in an acetonitrile medium. J Phys Chem B 109:21078–21085CrossRef
23.
go back to reference Zhang XT, Zhang J, Song WH, Liu ZF (2006) Controllable synthesis of conducting polypyrrole nanostructures. J Phy Chem B 110:1158–1165CrossRef Zhang XT, Zhang J, Song WH, Liu ZF (2006) Controllable synthesis of conducting polypyrrole nanostructures. J Phy Chem B 110:1158–1165CrossRef
24.
go back to reference Xin L, Xiao C, Zhong L (2010) Adsorption equilibrium and desorption activation energy of water vapor on activated carbon modified by an oxidation and reduction treatment. J Chem Eng Data 55:3164–3169CrossRef Xin L, Xiao C, Zhong L (2010) Adsorption equilibrium and desorption activation energy of water vapor on activated carbon modified by an oxidation and reduction treatment. J Chem Eng Data 55:3164–3169CrossRef
Metadata
Title
Synthesis and characterization of polypyrrole thin film by MW-CBD method for NH3 gas sensor
Authors
A. A. Yadav
S. B. Kulkarni
C. D. Lokhande
Publication date
07-02-2018
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 10/2018
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2282-5

Other articles of this Issue 10/2018

Polymer Bulletin 10/2018 Go to the issue

Premium Partners