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12-06-2017 | Original Paper

Synthesis of N-vinylformamide and 1-vinyl-(1-methacryloyl)-3,5-dimethylpyrazole copolymers and their extraction ability in relation to histidine in water-salt media

Authors: Vyacheslav A. Kuznetsov, Maria S. Lavlinskaya, Irina V. Ostankova, Gennadiy V. Shatalov, Khidmet S. Shikhaliev, Elena A. Ryzhkova

Published in: Polymer Bulletin | Issue 3/2018

Abstract

Copolymers of N-vinylformamide (VF) with 1-vinyl-3,5-dimethylpyrazole (VDMP) and 1-methacryloyl-3,5-dimethylpyrazole (MDMP) are synthesized by free radical copolymerization in dioxane. The compositions of copolymers are determined by means of UV-spectroscopy and FTIR, and copolymerization constants r ₁ and r ₂ are calculated. N-vinylformamide demonstrates higher reactivity than pyrazole-containing monomers in both cases. Solubility of the synthesized copolymers in water was studied. VF–VDMP copolymers are water soluble at VF content higher than 0.65 molar fractions, and VF–MDMP copolymers—at VF content over 0.8 molar fractions. The formation of complexes between water-soluble copolymers and essential α-amino acid histidine in aqueous solutions is confirmed by UV-spectroscopy, FTIR, dynamic light scattering (DLS), and transition electron microscopy. It is found via DLS that the interactions between the amino acid with copolymer macromolecules lead to conformation changes in macromolecular coils. It is shown that VF–VDMP and VF–MDMP copolymers are effective extragents for histidine. Extraction is carried out at different pH values. The highest extraction degree (98%) is achieved in an acidic medium.

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Title: Synthesis of N-vinylformamide and 1-vinyl-(1-methacryloyl)-3,5-dimethylpyrazole copolymers and their extraction ability in relation to histidine in water-salt media
Authors: Vyacheslav A. Kuznetsov
Maria S. Lavlinskaya
Irina V. Ostankova
Gennadiy V. Shatalov
Khidmet S. Shikhaliev
Elena A. Ryzhkova
Publication date: 12-06-2017
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 3/2018
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-017-2091-2

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