Top

Published in:

2020 | OriginalPaper | Chapter

1. Synthesis of Perovskite Nanocrystals

Author : He Huang

Published in: Perovskite Quantum Dots

Publisher: Springer Singapore

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

This chapter gives an overview of the synthesis of perovskite nanocrystals. The most commonly used methods are the precipitation method and the injection. Other methods are also mentioned briefly with a few examples.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

next chapter Strongly Quantum Confined Metal Halide Perovskite Nanocrystals

J. Burschka, N. Pellet, S.J. Moon, R. Humphry-Baker, P. Gao, M.K. Nazeeruddin, M. Gratzel, Sequential deposition as a route to high-performance perovskite-sensitized solar cells. Nature 499(7458), 316–319 (2013). https://doi.org/10.1038/nature12340CrossRef

Y. Li, X. Zhang, H. Huang, S.V. Kershaw, A.L. Rogach, Advances in metal halide perovskite nanocrystals: Synthetic strategies, growth mechanisms, and optoelectronic applications. Mater. Today 32, 204–221 (2020). https://doi.org/10.1016/j.mattod.2019.06.007CrossRef

M.V. Kovalenko, L. Protesescu, M.I. Bodnarchuk, Properties and potential optoelectronic applications of lead halide perovskite nanocrystals. Science 358(6364), 745–750 (2017). https://doi.org/10.1126/science.aam7093CrossRef

H. Huang, L. Polavarapu, J.A. Sichert, A.S. Susha, A.S. Urban, A.L. Rogach, Colloidal lead halide perovskite nanocrystals: synthesis, optical properties and applications. NPG. Asia. Mater 8(11), e328 (2016). https://doi.org/10.1038/am.2016.167CrossRef

A. Kojima, K. Teshima, Y. Shirai, T. Miyasaka, Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J. Am. Chem. Soc 131(17), 6050–6051 (2009). https://doi.org/10.1021/ja809598rCrossRef

M.M. Lee, J. Teuscher, T. Miyasaka, T.N. Murakami, H.J. Snaith, Efficient hybrid solar cells based on meso-superstructured organometal halide perovskites. Science 338(6107), 643–647 (2012). https://doi.org/10.1126/science.1228604CrossRef

M. Liu, M.B. Johnston, H.J. Snaith, Efficient planar heterojunction perovskite solar cells by vapour deposition. Nature 501(7467), 395–398 (2013). https://doi.org/10.1038/nature12509CrossRef

Z.K. Tan, R.S. Moghaddam, M.L. Lai, P. Docampo, R. Higler, F. Deschler, M. Price, A. Sadhanala, L.M. Pazos, D. Credgington, F. Hanusch, T. Bein, H.J. Snaith, R.H. Friend, Bright light-emitting diodes based on organometal halide perovskite. Nat. Nanotechnol. 9(9), 687–692 (2014). https://doi.org/10.1038/nnano.2014.149CrossRef

G. Xing, N. Mathews, S.S. Lim, N. Yantara, X. Liu, D. Sabba, M. Gratzel, S. Mhaisalkar, T.C. Sum, Low-temperature solution-processed wavelength-tunable perovskites for lasing. Nat. Mater. 13(5), 476–480 (2014). https://doi.org/10.1038/nmat3911CrossRef

10.

H. Zhou, Q. Chen, G. Li, S. Luo, T.B. Song, H.S. Duan, Z. Hong, J. You, Y. Liu, Y. Yang, Interface engineering of highly efficient perovskite solar cells. Science 345(6196), 542–546 (2014). https://doi.org/10.1126/science.1254050CrossRef

11.

National Renewable Energy Laboratory (2020) Best Research-Cell Efficiencies. https://www.nrel.gov/ncpv/images/efficiency_chart.jpg. Accessed 11 Mar 2020

12.

D. Weber, The perovskite system CH₃NH₃[Pb_n, S_n1-n_X3] (X=Cl, Br, I). Z. Naturforsch. B. 34(7), 939–941 (1979)CrossRef

13.

D. Weber, CH₃NH₃SnBr_xI_3-x (X = 0–3)—Sn(II)-System with cubic perovskite structure. Z. Naturforsch. B. 33(8), 862–865 (1978)CrossRef

14.

D. Weber, CH₃NH₃PbX₃, a Pb(II)-System with cubic perovskite structure. Z. Naturforsch. B. 33(12), 1443–1445 (1978)CrossRef

15.

D.B. Mitzi, C.A. Feild, W.T.A. Harrison, A.M. Guloy, Conducting tin halides with a layered organic-based perovskite structure. Nature 369(6480), 467–469 (1994). https://doi.org/10.1038/369467a0CrossRef

16.

D.B. Mitzi, K. Chondroudis, C.R. Kagan, Organic-inorganic electronics. IBM. J. Res. Dev. 45(1), 29–45 (2001)CrossRef

17.

D.B. Mitzi, C.D. Dimitrakopoulos, L.L. Kosbar, Structurally tailored organic-inorganic perovskites: optical properties and solution-processed channel materials for thin-film transistors. Chem. Mater. 13(10), 3728–3740 (2001)CrossRef

18.

A. Kojima, M. Ikegami, K. Teshima, T. Miyasaka, Highly luminescent lead bromide perovskite nanoparticles synthesized with porous alumina media. Chem. Lett 41(4), 397–399 (2012). https://doi.org/10.1246/cl.2012.397CrossRef

19.

J.A. Christians, P.A. Miranda Herrera, P.V. Kamat, Transformation of the excited state and photovoltaic efficiency of CH₃NH₃PbI₃ perovskite upon controlled exposure to humidified air. J. Am. Chem. Soc. 137(4), 1530–1538 (2015). https://doi.org/10.1021/ja511132aCrossRef

20.

G.E. Eperon, S.D. Stranks, C. Menelaou, M.B. Johnston, L.M. Herz, H.J. Snaith, Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells. Energ. Environ. Sci. 7(3), 982 (2014). https://doi.org/10.1039/c3ee43822hCrossRef

21.

F. Zhang, H. Zhong, C. Chen, X.G. Wu, X. Hu, H. Huang, J. Han, B. Zou, Y. Dong, Brightly luminescent and color-tunable colloidal CH₃NH₃PbX₃ (X = Br, I, Cl) quantum dots: potential alternatives for display technology. ACS Nano 9(4), 4533–4542 (2015). https://doi.org/10.1021/acsnano.5b01154CrossRef

22.

L. Protesescu, S. Yakunin, M.I. Bodnarchuk, F. Krieg, R. Caputo, C.H. Hendon, R.X. Yang, A. Walsh, M.V. Kovalenko, Nanocrystals of cesium lead halide perovskites (CsPbX₃, X = Cl, Br, and I): novel optoelectronic materials showing bright emission with wide color gamut. Nano. Lett. 15(6), 3692–3696 (2015). https://doi.org/10.1021/nl5048779CrossRef

23.

J.A. Sichert, Y. Tong, N. Mutz, M. Vollmer, S. Fischer, K.Z. Milowska, R. Garcia Cortadella, B. Nickel, C. Cardenas-Daw, J.K. Stolarczyk, A.S. Urban, J. Feldmann, Quantum size effect in organometal halide perovskite nanoplatelets. Nano. Lett. 15(10), 6521–6527 (2015). https://doi.org/10.1021/acs.nanolett.5b02985CrossRef

24.

S. Gonzalez-Carrero, R.E. Galian, J. Pérez-Prieto, Maximizing the emissive properties of CH₃NH₃PbBr 3 perovskite nanoparticles. J. Mater. Chem. A. 3(17), 9187–9193 (2015). https://doi.org/10.1039/c4ta05878jCrossRef

25.

H. Huang, A.S. Susha, S.V. Kershaw, T.F. Hung, A.L. Rogach, Control of Emission Color of High Quantum Yield CH3NH3PbBr 3 Perovskite Quantum Dots by Precipitation Temperature. Adv Sci 2(9), 1500194 (2015). https://doi.org/10.1002/advs.201500194CrossRef

26.

L.C. Schmidt, A. Pertegas, S. Gonzalez-Carrero, O. Malinkiewicz, S. Agouram, G. Minguez Espallargas, H.J. Bolink, R.E. Galian, J. Perez-Prieto, Nontemplate synthesis of CH₃NH₃PbBr 3 perovskite nanoparticles. J. Am. Chem. Soc. 136(3), 850–853 (2014). https://doi.org/10.1021/ja4109209CrossRef

27.

H. Huang, Y. Li, Y. Tong, E.P. Yao, M.W. Feil, A.F. Richter, M. Doblinger, A.L. Rogach, J. Feldmann, L. Polavarapu, Spontaneous crystallization of perovskite nanocrystals in nonpolar organic solvents: a versatile approach for their shape-controlled synthesis. Angew. Chem. Int. Ed. Engl. 58(46), 16558–16562 (2019). https://doi.org/10.1002/anie.201906862CrossRef

28.

S. Sun, D. Yuan, Y. Xu, A. Wang, Z. Deng, Ligand-mediated synthesis of shape-controlled cesium lead halide perovskite nanocrystals via reprecipitation process at room temperature. ACS Nano 10(3), 3648–3657 (2016). https://doi.org/10.1021/acsnano.5b08193CrossRef

29.

C. Muthu, S.R. Nagamma, V.C. Nair, Luminescent hybrid perovskite nanoparticles as a new platform for selective detection of 2,4,6-trinitrophenol. RSC. Adv. 4(99), 55908–55911 (2014). https://doi.org/10.1039/c4ra07884eCrossRef

30.

B. Luo, Y.-C. Pu, Y. Yang, S.A. Lindley, G. Abdelmageed, H. Ashry, Y. Li, X. Li, J.Z. Zhang, Synthesis, optical properties, and exciton dynamics of organolead bromide perovskite nanocrystals. J. Phys. Chem. C. 119(47), 26672–26682 (2015). https://doi.org/10.1021/acs.jpcc.5b08537CrossRef

31.

P. Tyagi, S.M. Arveson, W.A. Tisdale, Colloidal organohalide perovskite nanoplatelets exhibiting quantum confinement. J. Phys. Chem. Lett. 6(10), 1911–1916 (2015). https://doi.org/10.1021/acs.jpclett.5b00664CrossRef

32.

K. Tanaka, T. Takahashi, T. Ban, T. Kondo, K. Uchida, N. Miura, Comparative study on the excitons in lead-halide-based perovskite-type crystals CH₃NH₃PbBr 3 C_H3N_H3Pb_I3. Solid. State. Commun. 127(9–10), 619–623 (2003). https://doi.org/10.1016/s0038-1098(03)00566-0CrossRef

33.

A. Buin, R. Comin, A.H. Ip, E.H. Sargent, Perovskite quantum dots modeled using ab initio and replica exchange molecular dynamics. J. Phys. Chem. C. 119(24), 13965–13971 (2015). https://doi.org/10.1021/acs.jpcc.5b03613CrossRef

34.

X. Li, Y. Wu, S. Zhang, B. Cai, Y. Gu, J. Song, H. Zeng, CsPbX₃ quantum dots for lighting and displays: room-temperature synthesis, photoluminescence superiorities, underlying origins and white light-emitting diodes. Adv. Funct. Mater. 26(15), 2435–2445 (2016). https://doi.org/10.1002/adfm.201600109CrossRef

35.

Y. Ling, Z. Yuan, Y. Tian, X. Wang, J.C. Wang, Y. Xin, K. Hanson, B. Ma, H. Gao, Bright light-emitting diodes based on organometal halide perovskite nanoplatelets. Adv. Mater. 28(2), 305–311 (2016). https://doi.org/10.1002/adma.201503954CrossRef

36.

O. Vybornyi, S. Yakunin, M.V. Kovalenko, Polar-solvent-free colloidal synthesis of highly luminescent alkylammonium lead halide perovskite nanocrystals. Nanoscale 8(12), 6278–6283 (2016). https://doi.org/10.1039/c5nr06890hCrossRef

37.

Z. Yuan, Y. Shu, Y. Tian, Y. Xin, B. Ma, A facile one-pot synthesis of deep blue luminescent lead bromide perovskite microdisks. Chem. Commun. 51(91), 16385–16388 (2015). https://doi.org/10.1039/c5cc06750bCrossRef

38.

S. Pathak, N. Sakai, F.W.R. Rivarola, S.D. Stranks, J.W. Liu, G.E. Eperon, C. Ducati, K. Wojciechowski, J.T. Griffiths, A.A. Haghighirad, A. Pellaroque, R.H. Friend, H.J. Snaith, Perovskite crystals for tunable white light emission. Chem. Mater. 27(23), 8066–8075 (2015). https://doi.org/10.1021/acs.chemmater.5b03769CrossRef

39.

Q.A. Akkerman, S.G. Motti, A.R. Srimath Kandada, E. Mosconi, V. D’Innocenzo, G. Bertoni, S. Marras, B.A. Kamino, L. Miranda, F. De Angelis, A. Petrozza, M. Prato, L. Manna, Solution synthesis approach to colloidal cesium lead halide perovskite nanoplatelets with monolayer-level thickness control. J. Am. Chem. Soc. 138(3), 1010–1016 (2016). https://doi.org/10.1021/jacs.5b12124CrossRef

40.

K.H. Wang, L. Wu, L. Li, H.B. Yao, H.S. Qian, S.H. Yu, Large-scale synthesis of highly luminescent perovskite-related cspb₂br 5 nanoplatelets and their fast anion exchange. Angew. Chem. Int. Ed. 55(29), 8328–8332 (2016). https://doi.org/10.1002/anie.201602787CrossRef

41.

T.C. Jellicoe, J.M. Richter, H.F. Glass, M. Tabachnyk, R. Brady, S.E. Dutton, A. Rao, R.H. Friend, D. Credgington, N.C. Greenham, M.L. Bohm, Synthesis and optical properties of lead-free cesium tin halide perovskite nanocrystals. J. Am. Chem. Soc. 138(9), 2941–2944 (2016). https://doi.org/10.1021/jacs.5b13470CrossRef

42.

Q. Zhong, M. Cao, Y. Xu, P. Li, Y. Zhang, H. Hu, D. Yang, Y. Xu, L. Wang, Y. Li, X. Zhang, Q. Zhang, L-type ligand-assisted acid-free synthesis of cspbbr 3 nanocrystals with near-unity photoluminescence quantum yield and high stability. Nano. Lett. 19(6), 4151–4157 (2019). https://doi.org/10.1021/acs.nanolett.9b01666CrossRef

43.

H. Huang, F. Zhao, L. Liu, F. Zhang, X.G. Wu, L. Shi, B. Zou, Q. Pei, H. Zhong, Emulsion synthesis of size-tunable CH₃NH₃PbBr 3 quantum dots: an alternative route toward efficient light-emitting diodes. ACS. Appl. Mater. Interfaces. 7(51), 28128–28133 (2015). https://doi.org/10.1021/acsami.5b10373CrossRef

44.

R. Naphade, S. Nagane, G.S. Shanker, R. Fernandes, D. Kothari, Y. Zhou, N.P. Padture, S. Ogale, Hybrid perovskite quantum nanostructures synthesized by electrospray antisolvent-solvent extraction and intercalation. ACS. Appl. Mater. Interfaces. 8(1), 854–861 (2016). https://doi.org/10.1021/acsami.5b10208CrossRef

45.

P. Audebert, G. Clavier, A.-R. Vr, E. Deleporte, S. Zhang, J.S. Lauret, G. Lanty, C. Boissière, Synthesis of new perovskite luminescent nanoparticles in the visible range. Chem Mater 21(2), 210–214 (2009). https://doi.org/10.1021/cm8020462CrossRef

46.

G.C. Papavassiliou, G. Pagona, N. Karousis, G.A. Mousdis, I. Koutselas, A. Vassilakopoulou, Nanocrystalline/microcrystalline materials based on lead-halide units. J. Mater. Chem. 22(17), 8271 (2012). https://doi.org/10.1039/c2jm15783gCrossRef

47.

I. Saikumar, S. Ahmad, J.J. Baumberg, G. Vijaya Prakash, Fabrication of excitonic luminescent inorganic-organic hybrid nano- and microcrystals. Scripta. Mater. 67(10), 834–837 (2012). https://doi.org/10.1016/j.scriptamat.2012.07.048CrossRef

48.

F. Zhu, L. Men, Y. Guo, Q. Zhu, U. Bhattacharjee, P.M. Goodwin, J.W. Petrich, E.A. Smith, J. Vela, Shape evolution and single particle luminescence of organometal halide perovskite nanocrystals. ACS Nano 9(3), 2948–2959 (2015). https://doi.org/10.1021/nn507020sCrossRef

49.

L. Protesescu, S. Yakunin, S. Kumar, J. Bar, F. Bertolotti, N. Masciocchi, A. Guagliardi, M. Grotevent, I. Shorubalko, M.I. Bodnarchuk, C.J. Shih, M.V. Kovalenko, Dismantling the “Red Wall” of colloidal perovskites: highly luminescent formamidinium and formamidinium-cesium lead iodide nanocrystals. ACS Nano 11(3), 3119–3134 (2017). https://doi.org/10.1021/acsnano.7b00116CrossRef

50.

I. Lignos, S. Stavrakis, G. Nedelcu, L. Protesescu, A.J. deMello, M.V. Kovalenko, Synthesis of cesium lead halide perovskite nanocrystals in a droplet-based microfluidic platform: fast parametric space mapping. Nano. Lett. 16(3), 1869–1877 (2016). https://doi.org/10.1021/acs.nanolett.5b04981CrossRef

51.

M. Koolyk, D. Amgar, S. Aharon, L. Etgar, Kinetics of cesium lead halide perovskite nanoparticle growth; focusing and de-focusing of size distribution. Nanoscale 8(12), 6403–6409 (2016). https://doi.org/10.1039/c5nr09127fCrossRef

52.

E. Yassitepe, Z. Yang, O. Voznyy, Y. Kim, G. Walters, J.A. Castañeda, P. Kanjanaboos, M. Yuan, X. Gong, F. Fan, J. Pan, S. Hoogland, R. Comin, O.M. Bakr, L.A. Padilha, A.F. Nogueira, E.H. Sargent, Amine-free synthesis of cesium lead halide perovskite quantum dots for efficient light-emitting diodes. Adv. Func. Mater. 26(47), 8757–8763 (2016). https://doi.org/10.1002/adfm.201604580CrossRef

53.

M. Imran, V. Caligiuri, M. Wang, L. Goldoni, M. Prato, R. Krahne, L. De Trizio, L. Manna, Benzoyl halides as alternative precursors for the colloidal synthesis of lead-based halide perovskite nanocrystals. J. Am. Chem. Soc. 140(7), 2656–2664 (2018). https://doi.org/10.1021/jacs.7b13477CrossRef

54.

D. Zhang, S.W. Eaton, Y. Yu, L. Dou, P. Yang, Solution-phase synthesis of cesium lead halide perovskite nanowires. J. Am. Chem. Soc 137(29), 9230–9233 (2015). https://doi.org/10.1021/jacs.5b05404CrossRef

55.

D. Zhang, Y. Yu, Y. Bekenstein, A.B. Wong, A.P. Alivisatos, P. Yang, Ultrathin colloidal cesium lead halide perovskite nanowires. J. Am. Chem. Soc. 138(40), 13155–13158 (2016). https://doi.org/10.1021/jacs.6b08373CrossRef

56.

M. Imran, F. Di Stasio, Z. Dang, C. Canale, A.H. Khan, J. Shamsi, R. Brescia, M. Prato, L. Manna, Colloidal synthesis of strongly fluorescent cspbbr 3 nanowires with width tunable down to the quantum confinement regime. Chem. Mater. 28(18), 6450–6454 (2016). https://doi.org/10.1021/acs.chemmater.6b03081CrossRef

57.

J. Song, L. Xu, J. Li, J. Xue, Y. Dong, X. Li, H. Zeng, Monolayer and few-layer all-inorganic perovskites as a new family of two-dimensional semiconductors for printable optoelectronic devices. Adv. Mater. 28(24), 4861–4869 (2016). https://doi.org/10.1002/adma.201600225CrossRef

58.

Y. Bekenstein, B.A. Koscher, S.W. Eaton, P. Yang, A.P. Alivisatos, Highly luminescent colloidal nanoplates of perovskite cesium lead halide and their oriented assemblies. J. Am. Chem. Soc. 137(51), 16008–16011 (2015). https://doi.org/10.1021/jacs.5b11199CrossRef

59.

W. Liu, Q. Lin, H. Li, K. Wu, I. Robel, J.M. Pietryga, V.I. Klimov, Mn2+-doped lead halide perovskite nanocrystals with dual-color emission controlled by halide content. J. Am. Chem. Soc. 138(45), 14954–14961 (2016). https://doi.org/10.1021/jacs.6b08085CrossRef

60.

D. Parobek, B.J. Roman, Y. Dong, H. Jin, E. Lee, M. Sheldon, D.H. Son, Exciton-to-dopant energy transfer in mn-doped cesium lead halide perovskite nanocrystals. Nano. Lett. 16(12), 7376–7380 (2016). https://doi.org/10.1021/acs.nanolett.6b02772CrossRef

61.

G. Pan, X. Bai, D. Yang, X. Chen, P. Jing, S. Qu, L. Zhang, D. Zhou, J. Zhu, W. Xu, B. Dong, H. Song, Doping lanthanide into perovskite nanocrystals: highly improved and expanded optical properties. Nano. Lett. 17(12), 8005–8011 (2017). https://doi.org/10.1021/acs.nanolett.7b04575CrossRef

62.

A. Wang, Y. Guo, F. Muhammad, Z. Deng, Controlled synthesis of lead-free cesium tin halide perovskite cubic nanocages with high stability. Chem. Mater. 29(15), 6493–6501 (2017). https://doi.org/10.1021/acs.chemmater.7b02089CrossRef

63.

J. Pal, S. Manna, A. Mondal, S. Das, K.V. Adarsh, A. Nag, Colloidal synthesis and photophysics of M3 Sb2 I9 (M=Cs and Rb) nanocrystals: lead-free perovskites. Angew. Chem. Int. Ed. Engl. 56(45), 14187–14191 (2017). https://doi.org/10.1002/anie.201709040CrossRef

64.

B. Pradhan, G.S. Kumar, S. Sain, A. Dalui, U.K. Ghorai, S.K. Pradhan, S. Acharya, Size tunable cesium antimony chloride perovskite nanowires and nanorods. Chem. Mater. 30(6), 2135–2142 (2018). https://doi.org/10.1021/acs.chemmater.8b00427CrossRef

65.

L. Zhou, Y.F. Xu, B.X. Chen, D.B. Kuang, C.Y. Su, Synthesis and photocatalytic application of stable lead-free cs2 agbibr 6 perovskite nanocrystals. Small 14(11), e1703762 (2018). https://doi.org/10.1002/smll.201703762CrossRef

66.

S.E. Creutz, E.N. Crites, M.C. De Siena, D.R. Gamelin, Colloidal nanocrystals of lead-free double-perovskite (elpasolite) semiconductors: synthesis and anion exchange to access new materials. Nano. Lett. 18(2), 1118–1123 (2018). https://doi.org/10.1021/acs.nanolett.7b04659CrossRef

67.

M. Imran, P. Ijaz, L. Goldoni, D. Maggioni, U. Petralanda, M. Prato, G. Almeida, I. Infante, L. Manna, Simultaneous cationic and anionic ligand exchange for colloidally stable CsPbBr 3 nanocrystals. ACS. Energy. Lett. 4(4), 819–824 (2019). https://doi.org/10.1021/acsenergylett.9b00140CrossRef

68.

H. Huang, Y. Li, Y. Tong, E.-P. Yao, M.W. Feil, A.F. Richter, M. Döblinger, A.L. Rogach, J. Feldmann, L. Polavarapu, Spontaneous crystallization of perovskite nanocrystals in nonpolar organic solvents: a versatile approach for their shape-controlled synthesis. Angew. Chem. Int. Ed. (2019). https://doi.org/10.1002/anie.201906862CrossRef

69.

H. Huang, L. Wu, Y. Wan, A.F. Richter, M. Doblinger, J. Feldmann, Facile synthesis of FAPbI3 nanorods. Nanomaterials 10(1) (2019). doi:10.3390/nano10010072

70.

Y. Tong, E. Bladt, M.F. Ayguler, A. Manzi, K.Z. Milowska, V.A. Hintermayr, P. Docampo, S. Bals, A.S. Urban, L. Polavarapu, J. Feldmann, Highly luminescent cesium lead halide perovskite nanocrystals with tunable composition and thickness by ultrasonication. Angew. Chem. Int. Ed. 55(44), 13887–13892 (2016). https://doi.org/10.1002/anie.201605909CrossRef

71.

Y. Tong, B.J. Bohn, E. Bladt, K. Wang, P. Muller-Buschbaum, S. Bals, A.S. Urban, L. Polavarapu, J. Feldmann, From precursor powders to CsPbX3 perovskite nanowires: one-pot synthesis, growth mechanism, and oriented self-assembly. Angew. Chem. Int. Ed. 56(44), 13887–13892 (2017). https://doi.org/10.1002/anie.201707224CrossRef

72.

Y. Tong, M. Fu, E. Bladt, H. Huang, A.F. Richter, K. Wang, P. Muller-Buschbaum, S. Bals, P. Tamarat, B. Lounis, J. Feldmann, L. Polavarapu, Chemical cutting of perovskite nanowires into single-photon emissive low-aspect-ratio CsPbX3 (X=Cl, Br, I) nanorods. Angew. Chem. Int. Ed. 57(49), 16094–16098 (2018). https://doi.org/10.1002/anie.201810110CrossRef

73.

H. Huang, Q. Xue, B. Chen, Y. Xiong, J. Schneider, C. Zhi, H. Zhong, A.L. Rogach, Top-down fabrication of stable methylammonium lead halide perovskite nanocrystals by employing a mixture of ligands as coordinating solvents. Angew. Chem. Int. Ed. 56(32), 9571–9576 (2017). https://doi.org/10.1002/anie.201705595CrossRef

74.

M. Chen, Y. Zou, L. Wu, Q. Pa, D. Yang, H. Hu, Y. Ta, Q. Zhon, Y. Xu, H. Liu, B. Sun, Q. Zhang (2017) Solvothermal synthesis of high-quality all-inorganic cesium lead halide perovskite nanocrystals: from nanocube to ultrathin nanowire. Adv. Funct. Mater. 1701121. doi:10.1002/adfm.201701121

75.

D. Chen, G. Fang, X. Chen, L. Lei, J. Zhong, Q. Mao, S. Zhou, J. Li (2018) Mn-doped CsPbCl3 perovskite nanocrystals: solvothermal synthesis, dual-color luminescence and improved stability. doi:10.1039/C8TC03139H

76.

Q. Pan, H. Hu, Y. Zou, M. Chen, L. Wu, D. Yang, X. Yuan, J. Fan, B. Sun, Q. Zhang, Microwave-assisted synthesis of high-quality “all-inorganic” CsPbX3 (X = Cl, Br, I) perovskite nanocrystals and their application in light emitting diodes. J. Mater. Chem. C. 5(42), 10947–10954 (2017). https://doi.org/10.1039/c7tc03774kCrossRef

77.

Y. Li, H. Huang, Y. Xiong, S.V. Kershaw, A.L. Rogach, Revealing the formation mechanism of cspbbr 3 perovskite nanocrystals produced via a slowed-down microwave-assisted synthesis. Angew. Chem. Int. Ed. 57(20), 5833–5837 (2018). https://doi.org/10.1002/anie.201713332CrossRef

78.

L. Protesescu, S. Yakunin, O. Nazarenko, D.N. Dirin, M.V. Kovalenko, Low-cost synthesis of highly luminescent colloidal lead halide perovskite nanocrystals by wet ball milling. ACS. Appl. Nano. Mater. 1(3), 1300–1308 (2018). https://doi.org/10.1021/acsanm.8b00038CrossRef

79.

F. Palazon, Y. El Ajjouri, P. Sebastia-Luna, S. Lauciello, L. Manna, H.J. Bolink, Mechanochemical synthesis of inorganic halide perovskites: evolution of phase-purity, morphology, and photoluminescence. J. Mater. Chem. C. 7(37), 11406–11410 (2019). https://doi.org/10.1039/c9tc03778kCrossRef

Title: Synthesis of Perovskite Nanocrystals
Author: He Huang
Publisher: Springer Singapore
Book: Perovskite Quantum Dots
Print ISBN: 978-981-15-6636-3

Electronic ISBN: 978-981-15-6637-0

Copyright Year: 2020
DOI: https://doi.org/10.1007/978-981-15-6637-0_1