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Journal of Sol-Gel Science and Technology
Published in: Journal of Sol-Gel Science and Technology 2/2018

21-07-2018 | Original Paper: Sol-gel and hybrid materials with surface modification for applications

Synthesis of superhydrophobic fluoro-containing silica sol coatings for cotton textile by one-step sol–gel process

Authors: Chi Jiang, Weiqu Liu, Maiping Yang, Sha He, Yankun Xie, Zhengfang Wang

Published in: Journal of Sol-Gel Science and Technology | Issue 2/2018

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Abstract

Superhydrophobic coatings were successfully fabricated on cotton textiles through a simple one-step sol–gel process. A fluorinated copolymer (PHFA-MPS), as a precursor in the sol–gel reaction, was prepared by copolymerization of hexafluorobutyl methacrylate (HFA) and 3-methacryloxypropyltrimethoxysilane (MPS) as monomers. Then, the fluoro-containing silica sols were formed by alkaline hydrolysis of tetraethylorthosilicate (TEOS) and PHFA-MPS solution in an ethanol solution, which was used to impart the cotton textiles with excellent superhydrophobicity via a facile dip-coating method. The effects of ammonium hydroxide solution (NH4OH) and PHFA-MPS concentration on the structure of the fluoro-containing silica sols, as well as the wetting behavior, surface morphology, and surface composition of the as-prepared cotton textiles were characterized. The results show that the resultant cotton textiles exhibited excellent superhydrophobicity with a WCA of 153.4° and satisfied stability, which offers a simple procedure to generate the superhydrophobicity on cotton textiles for use in a wide range of fields.
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Metadata
Title
Synthesis of superhydrophobic fluoro-containing silica sol coatings for cotton textile by one-step sol–gel process
Authors
Chi Jiang
Weiqu Liu
Maiping Yang
Sha He
Yankun Xie
Zhengfang Wang
Publication date
21-07-2018
Publisher
Springer US
Published in
Journal of Sol-Gel Science and Technology / Issue 2/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4750-7

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