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Published in: Polymer Science, Series C 1/2019

01-09-2019

Synthesis, Structure and Properties of Poly(1-trimethylsilyl-1-propyne) Obtained with NbBr5- and TaBr5-Based Catalytic Systems

Authors: S. M. Matson, A. A. Kossov, V. P. Makrushin, I. S. Levin, N. A. Zhilyaeva, E. G. Litvinova, V. S. Khotimskiy

Published in: Polymer Science, Series C | Issue 1/2019

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Abstract

In this work, the polymerization of 1-trimethylsilyl-1-propyne [TMSP] using catalytic systems based on pentabromide Nb(V) and Ta(V) with organometallic cocatalysts Ph3Bi, Ph4Sn, Bu4Sn, Ph3SiH, and Et3SiH was investigated. The use of NbBr5-based catalytic systems has strongly marked cis-stereospecificity and gives highly cis-enriched poly(1-trimethylsilyl-1-propyne) [PTMSP] (content of cis-units above 70%), whereas the use of TaBr5-based catalytic systems leads to the formation of PTMSP with mixed cis-/trans-composition (content of cis-units from 50 to 65%).With increasing cis-content, solvent resistance of PTMSP increases significantly. PTMSP with a content of cis-units above 70% obtained on NbBr5-containing systems in cyclohexane acquires resistance to aliphatic and aromatic hydrocarbons, and cis-regular PTMSP obtained on NbBr5-based systems in toluene is totally insoluble in any of the organic solvents. The results of wide-angle X-ray diffraction indicate an increase in the packing density of the polymer during the transition from a mixed configuration to a cis-regular one. Durable PTMSP film membranes exhibit ultra-high permeability coefficients for individual gases (e.g., \({{P}_{{{{{\text{O}}}_{{\text{2}}}}}}}\) = 8500–11000 barrer, \({{\alpha }_{{{{{\text{O}}}_{{\text{2}}}}{\text{/}}{{{\text{N}}}_{{\text{2}}}}}}}\) = 1.5–1.9). According to the low-temperature Ar sorption, PTMSP synthesized with NbBr5- and TaBr5-based catalytic systems has high BET surface areas in the range of 870–1050 m2/g, high intrinsic microporosity, and higher gas permeability coefficients of PTMSP correlate with BET surface area growth.

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Literature
4.
go back to reference K. Nagai, T. Masuda, T. Nakagawa, B. D. Freeman, and I. Pinnau, Prog. Polym. Sci. 26, 721 (2001).CrossRef K. Nagai, T. Masuda, T. Nakagawa, B. D. Freeman, and I. Pinnau, Prog. Polym. Sci. 26, 721 (2001).CrossRef
5.
go back to reference T. Masuda, B. Z. Tang, A. Tanaka, and T. Higashimura, Macromolecules 19, 1459 (1986).CrossRef T. Masuda, B. Z. Tang, A. Tanaka, and T. Higashimura, Macromolecules 19, 1459 (1986).CrossRef
6.
7.
go back to reference R. Srinivasan, S. R. Auvil, and P. M. Burban, J. Membr. Sci. 86, 67 (1994).CrossRef R. Srinivasan, S. R. Auvil, and P. M. Burban, J. Membr. Sci. 86, 67 (1994).CrossRef
8.
go back to reference D. Hoffmann, M. Heuchel, Yu. Yampolskii, V. Khotimskii, and V. Shantarovich, Macromolecules 35, 2129 (2002).CrossRef D. Hoffmann, M. Heuchel, Yu. Yampolskii, V. Khotimskii, and V. Shantarovich, Macromolecules 35, 2129 (2002).CrossRef
9.
go back to reference S. Thomas, I. Pinnau, N. Du, and M. D. Guiver, J. Membr. Sci. 333, 125 (2009).CrossRef S. Thomas, I. Pinnau, N. Du, and M. D. Guiver, J. Membr. Sci. 333, 125 (2009).CrossRef
10.
go back to reference D. S. Pope, W. J. Koros, and H. B. Hopfenberg, Macromolecules 27, 5839 (1994).CrossRef D. S. Pope, W. J. Koros, and H. B. Hopfenberg, Macromolecules 27, 5839 (1994).CrossRef
11.
go back to reference L. G. Toy, K. Nagai, B. D. Freeman, I. Pinnau, Z. He, T. Masuda, M. Teraguchi, and Yu. P. Yampolskii, Macromolecules 33, 2516 (2000).CrossRef L. G. Toy, K. Nagai, B. D. Freeman, I. Pinnau, Z. He, T. Masuda, M. Teraguchi, and Yu. P. Yampolskii, Macromolecules 33, 2516 (2000).CrossRef
12.
go back to reference A. Morisato, H. C. Shen, S. S. Sankar, B. D. Freeman, I. Pinnau, and C. G. Casillas, J. Polym. Sci., Part B: Polym. Phys. 34, 2209 (1996).CrossRef A. Morisato, H. C. Shen, S. S. Sankar, B. D. Freeman, I. Pinnau, and C. G. Casillas, J. Polym. Sci., Part B: Polym. Phys. 34, 2209 (1996).CrossRef
15.
go back to reference T. C. Merkel, B. D. Freeman, R. J. Spontak, Z. He, I. Pinnau, P. Meakin, and A. J. Hill, Chem. Mater.15,109 (2003).CrossRef T. C. Merkel, B. D. Freeman, R. J. Spontak, Z. He, I. Pinnau, P. Meakin, and A. J. Hill, Chem. Mater.15,109 (2003).CrossRef
16.
go back to reference K. Takada, H. Matsuya, T. Masuda, and T. Higashimura, J. Appl. Polym. Sci. 30, 1605 (1985). K. Takada, H. Matsuya, T. Masuda, and T. Higashimura, J. Appl. Polym. Sci. 30, 1605 (1985).
17.
go back to reference T. Masuda, E. Isobe, T. Higashimura, and T. Takada, J. Am. Chem. Soc. 105, 7473 (1983).CrossRef T. Masuda, E. Isobe, T. Higashimura, and T. Takada, J. Am. Chem. Soc. 105, 7473 (1983).CrossRef
18.
go back to reference N. A. Plate, A. K. Bokarev, N. E. Kaliuzhnyi, E. G. Litvinova, V. S. Khotimskii, V. V. Volkov, and Yu. P. Yampolskii, J. Membr. Sci. 60, 13 (1991).CrossRef N. A. Plate, A. K. Bokarev, N. E. Kaliuzhnyi, E. G. Litvinova, V. S. Khotimskii, V. V. Volkov, and Yu. P. Yampolskii, J. Membr. Sci. 60, 13 (1991).CrossRef
19.
20.
go back to reference T. Masuda, E. Isobe, T. Hamano, and T. Higashimura, Macromolecules 19, 2448 (1986).CrossRef T. Masuda, E. Isobe, T. Hamano, and T. Higashimura, Macromolecules 19, 2448 (1986).CrossRef
21.
go back to reference J. Fujimori, T. Masuda, and T. Higashimura, Polym. Bull. 19, 1 (1988). J. Fujimori, T. Masuda, and T. Higashimura, Polym. Bull. 19, 1 (1988).
22.
go back to reference V. S. Khotimsky, M. V. Tchirkova, E. G. Litvinova, A. I. Rebrov, and G. N. Bondarenko, J. Polym. Sci., Part A: Polym. Chem. 41, 2133 (2003).CrossRef V. S. Khotimsky, M. V. Tchirkova, E. G. Litvinova, A. I. Rebrov, and G. N. Bondarenko, J. Polym. Sci., Part A: Polym. Chem. 41, 2133 (2003).CrossRef
23.
go back to reference W. Yave, K.-V.Peinemann, S. Shishatskiy, V. Khotimskiy, M. Chirkova, S. Matson, E. Litvinova, and N. Lecerf, Macromolecules 40, 8991 (2007).CrossRef W. Yave, K.-V.Peinemann, S. Shishatskiy, V. Khotimskiy, M. Chirkova, S. Matson, E. Litvinova, and N. Lecerf, Macromolecules 40, 8991 (2007).CrossRef
24.
26.
27.
go back to reference J. F. Kunzler and V. Percec, J. Polym. Sci., Part A: Polym. Chem. 28, 1221 (1990). J. F. Kunzler and V. Percec, J. Polym. Sci., Part A: Polym. Chem. 28, 1221 (1990).
28.
go back to reference E. G. Litvinova, V. M. Melekhov, N. V. Petrushanskaya, G. V. Rosheva, V. B. Fedotov, V. Sh. Feldblum, and V. S. Khotimskiy, RF Patent No. 1823457 (1993). E. G. Litvinova, V. M. Melekhov, N. V. Petrushanskaya, G. V. Rosheva, V. B. Fedotov, V. Sh. Feldblum, and V. S. Khotimskiy, RF Patent No. 1823457 (1993).
29.
go back to reference A. M. Shishatskii, Yu. P. Yampolskii, and K.-V. Peinemann, J. Membr. Sci. 112, 275 (1996).CrossRef A. M. Shishatskii, Yu. P. Yampolskii, and K.-V. Peinemann, J. Membr. Sci. 112, 275 (1996).CrossRef
30.
go back to reference F. Fairbrother, J. F. Nixon, and H. Prophet, J. Less-Common Met. 9, 434 (1965).CrossRef F. Fairbrother, J. F. Nixon, and H. Prophet, J. Less-Common Met. 9, 434 (1965).CrossRef
31.
go back to reference F. Fairbrother, The Chemistry of Niobium and Tantalum (Elsevier, Amsterdam, 1967). F. Fairbrother, The Chemistry of Niobium and Tantalum (Elsevier, Amsterdam, 1967).
32.
go back to reference Yu. K. Ovchinnikov, E. M. Antipov, G. S. Markova, and N. F. Bakeev, Macromol. Chem. 177, 1567 (1976).CrossRef Yu. K. Ovchinnikov, E. M. Antipov, G. S. Markova, and N. F. Bakeev, Macromol. Chem. 177, 1567 (1976).CrossRef
33.
go back to reference V. M. Polikarpov, E. M. Antipov, I. V. Razumovskaya, I. S. Bryantseva, E. G. Litvinova, M. V. Chirkova, Yu. M. Korolev, V. S. Khotimskii, and E. E. Antipov, Polym. Sci., Ser. A 44, 343 (2002). V. M. Polikarpov, E. M. Antipov, I. V. Razumovskaya, I. S. Bryantseva, E. G. Litvinova, M. V. Chirkova, Yu. M. Korolev, V. S. Khotimskii, and E. E. Antipov, Polym. Sci., Ser. A 44, 343 (2002).
34.
go back to reference S. Lowell, J. E. Shields, M. A. Thomas, and M. Thommes, Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density (Springer, New York, 2004).CrossRef S. Lowell, J. E. Shields, M. A. Thomas, and M. Thommes, Characterization of Porous Solids and Powders: Surface Area, Pore Size and Density (Springer, New York, 2004).CrossRef
35.
go back to reference K. S. W. Sing, D. H. Everett, R. A. W. Haul, L. Moscou, R. A. Pierotti, J. Rouqerol, and T. Siemieniewska, Pure Appl. Chem. 57, 603 (1985).CrossRef K. S. W. Sing, D. H. Everett, R. A. W. Haul, L. Moscou, R. A. Pierotti, J. Rouqerol, and T. Siemieniewska, Pure Appl. Chem. 57, 603 (1985).CrossRef
Metadata
Title
Synthesis, Structure and Properties of Poly(1-trimethylsilyl-1-propyne) Obtained with NbBr5- and TaBr5-Based Catalytic Systems
Authors
S. M. Matson
A. A. Kossov
V. P. Makrushin
I. S. Levin
N. A. Zhilyaeva
E. G. Litvinova
V. S. Khotimskiy
Publication date
01-09-2019
Publisher
Pleiades Publishing
Published in
Polymer Science, Series C / Issue 1/2019
Print ISSN: 1811-2382
Electronic ISSN: 1555-614X
DOI
https://doi.org/10.1134/S1811238219010120

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