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2017 | OriginalPaper | Chapter

23. Systematic Design of Biorefinery Downstream Processes

Authors : Michele Corbetta, Ignacio E. Grossmann, Carlo Pirola, Flavio Manenti

Published in: Advances in Energy Systems Engineering

Publisher: Springer International Publishing

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Abstract

Downstream processing of biofuels and bio-based chemicals often represents the bottleneck for the economic sustainable development of new processes. It is also a challenging problem for process synthesis and optimization, due to the intrinsic nonideal thermodynamics of the liquid mixtures derived from the (bio)chemical conversion of biomass. In this Chapter, a recent mathematical framework is outlined for the structural and parameter optimization of process flowsheets with rigorous and detailed models. The optimization problem is formulated within the Generalized Disjunctive Programming (GDP) framework and the solution of the reformulated MINLP problem is approached with a decomposition strategy based on the Outer-Approximation algorithm. At first, the mathematical formulation and the numerical implementation are outlined. In the second portion of the Chapter, several validation examples in the field of biorefineries are proposed spanning from the economic optimization of single distillation columns, the dewatering task of diluted bio-mixtures, up to the distillation sequencing with simultaneous mixed-integer design of each distillation column for a quaternary mixture in the presence of azeotropes.

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Literature
go back to reference Ahmetovic, E., Martin, M., & Grossmann, I. E. (2010). Optimization of energy and water consumption in corn-based ethanol plants. Industrial and Engineering Chemistry Research, 49, 7972–7982.CrossRef Ahmetovic, E., Martin, M., & Grossmann, I. E. (2010). Optimization of energy and water consumption in corn-based ethanol plants. Industrial and Engineering Chemistry Research, 49, 7972–7982.CrossRef
go back to reference Barttfield, M., Aguirre, P. A., & Grossmann, I. E. (2004). A decomposition method for synthesizing complex column configurations using tray-by-tray GDP models. Computers and Chemical Engineering, 28, 2165–2188.CrossRef Barttfield, M., Aguirre, P. A., & Grossmann, I. E. (2004). A decomposition method for synthesizing complex column configurations using tray-by-tray GDP models. Computers and Chemical Engineering, 28, 2165–2188.CrossRef
go back to reference Biegler, L. T. (1985). Improved infeasible path optimization for sequential modular simulators. 1. The interface. Computers & Chemical Engineering, 9, 245–256.CrossRef Biegler, L. T. (1985). Improved infeasible path optimization for sequential modular simulators. 1. The interface. Computers & Chemical Engineering, 9, 245–256.CrossRef
go back to reference Bondy, R. W. (1991). A new distillation algorithm for non-ideal system. In AIChE Annual Meeting. Bondy, R. W. (1991). A new distillation algorithm for non-ideal system. In AIChE Annual Meeting.
go back to reference Bravo-Bravo, C., Segovia-Hernandez, J. G., Gutierrez-Antonio, C., Duran, A. L., Bonilla-Petriciolet, A., & Briones-Ramirez, A. (2010). Extractive dividing wall column: Design and optimization. Industrial and Engineering Chemistry Research, 49, 3672–3688.CrossRef Bravo-Bravo, C., Segovia-Hernandez, J. G., Gutierrez-Antonio, C., Duran, A. L., Bonilla-Petriciolet, A., & Briones-Ramirez, A. (2010). Extractive dividing wall column: Design and optimization. Industrial and Engineering Chemistry Research, 49, 3672–3688.CrossRef
go back to reference Brunet, R., Reyes-Labarta, J. A., Guillen-Gosalbez, G., Jimenez, L., & Boer, D. (2012). Combined simulation-optimization methodology for the design of environmental conscious absorption systems. Computers and Chemical Engineering, 46, 205–216.CrossRef Brunet, R., Reyes-Labarta, J. A., Guillen-Gosalbez, G., Jimenez, L., & Boer, D. (2012). Combined simulation-optimization methodology for the design of environmental conscious absorption systems. Computers and Chemical Engineering, 46, 205–216.CrossRef
go back to reference Buzzi-Ferraris, G. (1967). Ottimizzazione di funzioni a più variabili. Nota I. Variabili non vincolate. Ing. Chim. It., 3, 101. Buzzi-Ferraris, G. (1967). Ottimizzazione di funzioni a più variabili. Nota I. Variabili non vincolate. Ing. Chim. It., 3, 101.
go back to reference Buzzi-Ferraris, G., & Manenti, F. (2009). Kinetic models analysis. Chemical Engineering Science, 64, 1061–1074.CrossRef Buzzi-Ferraris, G., & Manenti, F. (2009). Kinetic models analysis. Chemical Engineering Science, 64, 1061–1074.CrossRef
go back to reference Buzzi-Ferraris, G., & Manenti, F. (2010a). A combination of parallel computing and object-oriented programming to improve optimizer robustness and efficiency. Computer Aided Chemical Engineering, 28, 337–342. Buzzi-Ferraris, G., & Manenti, F. (2010a). A combination of parallel computing and object-oriented programming to improve optimizer robustness and efficiency. Computer Aided Chemical Engineering, 28, 337–342.
go back to reference Buzzi-Ferraris, G., & Manenti, F. (2010b). Interpolation and regression models for the chemical engineer: Solving numerical problems. Buzzi-Ferraris, G., & Manenti, F. (2010b). Interpolation and regression models for the chemical engineer: Solving numerical problems.
go back to reference Buzzi-Ferraris, G., & Manenti, F. (2012). BzzMath: Library overview and recent advances in numerical methods. Computer-Aided Chemical Engineering, 30, 1312–1316.CrossRef Buzzi-Ferraris, G., & Manenti, F. (2012). BzzMath: Library overview and recent advances in numerical methods. Computer-Aided Chemical Engineering, 30, 1312–1316.CrossRef
go back to reference Caballero, J. A., Milan-Yanez, D., & Grossmann, I. E. (2005). Rigorous design of distillation columns: Integration of disjunctive programming and process simulators. Industrial and Engineering Chemistry Research, 44, 6760–6775.CrossRef Caballero, J. A., Milan-Yanez, D., & Grossmann, I. E. (2005). Rigorous design of distillation columns: Integration of disjunctive programming and process simulators. Industrial and Engineering Chemistry Research, 44, 6760–6775.CrossRef
go back to reference Chen, G. Q. (2009). A microbial polyhydroxyalkanoates (PHA) based bio- and materials industry. Chemical Society Reviews, 38, 2434–2446.CrossRef Chen, G. Q. (2009). A microbial polyhydroxyalkanoates (PHA) based bio- and materials industry. Chemical Society Reviews, 38, 2434–2446.CrossRef
go back to reference Chen, Y., Eslick, J. C., Grossmann, I. E., & Miller, D. C. (2015). Simultaneous process optimization and heat integration based on rigorous process simulations. Computers and Chemical Engineering. Chen, Y., Eslick, J. C., Grossmann, I. E., & Miller, D. C. (2015). Simultaneous process optimization and heat integration based on rigorous process simulations. Computers and Chemical Engineering.
go back to reference Chien, I., Zeng, K. L., Chao, H. Y., & Hong Liu, J. (2004). Design and control of acetic acid dehydration system via heterogeneous azeotropic distillation. Chemical Engineering Science, 59, 4547–4567. Chien, I., Zeng, K. L., Chao, H. Y., & Hong Liu, J. (2004). Design and control of acetic acid dehydration system via heterogeneous azeotropic distillation. Chemical Engineering Science, 59, 4547–4567.
go back to reference Corbetta, M. (2015). Green ethylene glycol. MINLP downstream process optimization and multi-scale simulation of gasification processes. Doctoral Dissertation, Politecnico di Milano. Corbetta, M. (2015). Green ethylene glycol. MINLP downstream process optimization and multi-scale simulation of gasification processes. Doctoral Dissertation, Politecnico di Milano.
go back to reference Corbetta, M., Manenti, F., Pirola, C., Tsodikov, M. V., & Chistyakov, A. V. (2014). Aromatization of propane: Techno-economic analysis by multiscale “kinetics-to-process” simulation. Computers and Chemical Engineering, 71, 457–466.CrossRef Corbetta, M., Manenti, F., Pirola, C., Tsodikov, M. V., & Chistyakov, A. V. (2014). Aromatization of propane: Techno-economic analysis by multiscale “kinetics-to-process” simulation. Computers and Chemical Engineering, 71, 457–466.CrossRef
go back to reference Corbetta, M., Grossmann, I. E., & Manenti, F. (2016). Process simulator-based optimization of biorefinery downstream processes under the generalized disjunctive programming framework. Computers and Chemical Engineering, 88, 73–85.CrossRef Corbetta, M., Grossmann, I. E., & Manenti, F. (2016). Process simulator-based optimization of biorefinery downstream processes under the generalized disjunctive programming framework. Computers and Chemical Engineering, 88, 73–85.CrossRef
go back to reference Correia, A., Matias, J., Mestre, P., & Serôdio, C. (2010). Direct-search penalty/barrier methods. Proceedings of The World Congress on Engineering, 2010(3), 1729–1734.MATH Correia, A., Matias, J., Mestre, P., & Serôdio, C. (2010). Direct-search penalty/barrier methods. Proceedings of The World Congress on Engineering, 2010(3), 1729–1734.MATH
go back to reference Dias, M. O. S., Ensinas, A. V., Nebra, S. A., Maciel, R., Rossell, C. E. V., & Maciel, M. R. W. (2009). Production of bioethanol and other bio-based materials from sugarcane bagasse: Integration to conventional bioethanol production process. Chemical Engineering Research and Design, 87, 1206–1216.CrossRef Dias, M. O. S., Ensinas, A. V., Nebra, S. A., Maciel, R., Rossell, C. E. V., & Maciel, M. R. W. (2009). Production of bioethanol and other bio-based materials from sugarcane bagasse: Integration to conventional bioethanol production process. Chemical Engineering Research and Design, 87, 1206–1216.CrossRef
go back to reference Diaz, M. S., & Bandoni, J. A. (1996). A mixed integer optimization strategy for a large scale chemical plant in operation. Computers and Chemical Engineering, 20, 531–545.CrossRef Diaz, M. S., & Bandoni, J. A. (1996). A mixed integer optimization strategy for a large scale chemical plant in operation. Computers and Chemical Engineering, 20, 531–545.CrossRef
go back to reference Douglas, J. M. (1988). Conceptual design of chemical processes. New York. Douglas, J. M. (1988). Conceptual design of chemical processes. New York.
go back to reference Duran, M. A., & Grossmann, I. E. (1986). An outer-approximation algorithm for a class of mixed-integer nonlinear programs. Mathematical programming, 36(3), 307–339 Duran, M. A., & Grossmann, I. E. (1986). An outer-approximation algorithm for a class of mixed-integer nonlinear programs. Mathematical programming, 36(3), 307–339
go back to reference Eslick, J. C., & Miller, D. C. (2011). A multi-objective analysis for the retrofit of a pulverized coal power plant with a CO2 capture and compression process. Computers and Chemical Engineering, 35, 1488–1500.CrossRef Eslick, J. C., & Miller, D. C. (2011). A multi-objective analysis for the retrofit of a pulverized coal power plant with a CO2 capture and compression process. Computers and Chemical Engineering, 35, 1488–1500.CrossRef
go back to reference Garcia, N., Fernandez-Torres, M. J., & Caballero, J. A. (2014). Simultaneous environmental and economic process synthesis of isobutane alkylation. Journal of Cleaner Production, 81, 270–280.CrossRef Garcia, N., Fernandez-Torres, M. J., & Caballero, J. A. (2014). Simultaneous environmental and economic process synthesis of isobutane alkylation. Journal of Cleaner Production, 81, 270–280.CrossRef
go back to reference Gross, B., & Roosen, P. (1998). Total process optimization in chemical engineering with evolutionary algorithms. Computers and Chemical Engineering, 22, S229–S236.CrossRef Gross, B., & Roosen, P. (1998). Total process optimization in chemical engineering with evolutionary algorithms. Computers and Chemical Engineering, 22, S229–S236.CrossRef
go back to reference Grossmann, I. E. (2002). Review of nonlinear mixed-integer and disjunctive programming techniques. Optimization and engineering, 3(3), 227–252. Grossmann, I. E. (2002). Review of nonlinear mixed-integer and disjunctive programming techniques. Optimization and engineering, 3(3), 227–252.
go back to reference Grossmann, I. E., & Kravanja, Z. (1995). Mixed-integer nonlinear programming techniques for process systems engineering. Computers & Chemical Engineering, 19, S189–S204. Grossmann, I. E., & Kravanja, Z. (1995). Mixed-integer nonlinear programming techniques for process systems engineering. Computers & Chemical Engineering, 19, S189–S204.
go back to reference Grossmann, I. E., & Trespalacios, F. (2013). Systematic modeling of discrete-continuous optimization models through generalized disjunctive programming. AIChE Journal, 59, 3276–3295.CrossRef Grossmann, I. E., & Trespalacios, F. (2013). Systematic modeling of discrete-continuous optimization models through generalized disjunctive programming. AIChE Journal, 59, 3276–3295.CrossRef
go back to reference Gutierrez-Antonio, C., & Briones-Ramirez, A. (2009). Pareto front of ideal Petlyuk sequences using a multiobjective genetic algorithm with constraints. Computers and Chemical Engineering, 33, 454–464.CrossRef Gutierrez-Antonio, C., & Briones-Ramirez, A. (2009). Pareto front of ideal Petlyuk sequences using a multiobjective genetic algorithm with constraints. Computers and Chemical Engineering, 33, 454–464.CrossRef
go back to reference Harsh, M. G., Saderne, P., & Biegler, L. T. (1989). A mixed integer flowsheet optimization strategy for process retrofits—the debottlenecking problem. Computers and Chemical Engineering, 13, 947–957.CrossRef Harsh, M. G., Saderne, P., & Biegler, L. T. (1989). A mixed integer flowsheet optimization strategy for process retrofits—the debottlenecking problem. Computers and Chemical Engineering, 13, 947–957.CrossRef
go back to reference Hermann, B. G., & Patel, M. (2007). Today’s and tomorrow’s bio-based bulk chemicals from white biotechnology—a techno-economic analysis. Applied Biochemistry and Biotechnology, 136, 361–388.CrossRef Hermann, B. G., & Patel, M. (2007). Today’s and tomorrow’s bio-based bulk chemicals from white biotechnology—a techno-economic analysis. Applied Biochemistry and Biotechnology, 136, 361–388.CrossRef
go back to reference Kallrath, J., (2000). Mixed integer optimization in the chemical process industry experience, potential and future perspectives. Chemical Engineering Research & Design, 78(A6), 809–822. Kallrath, J., (2000). Mixed integer optimization in the chemical process industry experience, potential and future perspectives. Chemical Engineering Research & Design, 78(A6), 809–822.
go back to reference Karuppiah, R., & Grossmann, I. E. (2006). Global optimization for the synthesis of integrated water systems in chemical processes. Computers & Chemical Engineering, 30(4), 650–673. Karuppiah, R., & Grossmann, I. E. (2006). Global optimization for the synthesis of integrated water systems in chemical processes. Computers & Chemical Engineering, 30(4), 650–673.
go back to reference Karuppiah, R., Peschel, A., Grossmann, I. E., Martín, M., Martinson, W., & Zullo, L. (2008). Energy optimization for the design of corn-based ethanol plants. AIChE Journal, 54, 1499–1525.CrossRef Karuppiah, R., Peschel, A., Grossmann, I. E., Martín, M., Martinson, W., & Zullo, L. (2008). Energy optimization for the design of corn-based ethanol plants. AIChE Journal, 54, 1499–1525.CrossRef
go back to reference Leboreiro, J., & Acevedo, J. (2004). Processes synthesis and design of distillation sequences using modular simulators: A genetic algorithm framework. Computers and Chemical Engineering, 28, 1223–1236.CrossRef Leboreiro, J., & Acevedo, J. (2004). Processes synthesis and design of distillation sequences using modular simulators: A genetic algorithm framework. Computers and Chemical Engineering, 28, 1223–1236.CrossRef
go back to reference Lee, S., & Grossmann, I. E. (2001). A global optimization algorithm for nonconvex generalized disjunctive programming and applications to process systems. Computers & Chemical Engineering, 25(11–12), 1675–1697. Lee, S., & Grossmann, I. E. (2001). A global optimization algorithm for nonconvex generalized disjunctive programming and applications to process systems. Computers & Chemical Engineering, 25(11–12), 1675–1697.
go back to reference Navarro-Amoros, M. A., Caballero, J. A., Ruiz-Femenia, R., & Grossmann, I. E. (2013). An alternative disjunctive optimization model for heat integration with variable temperatures. Computers and Chemical Engineering, 56, 12–26.CrossRef Navarro-Amoros, M. A., Caballero, J. A., Ruiz-Femenia, R., & Grossmann, I. E. (2013). An alternative disjunctive optimization model for heat integration with variable temperatures. Computers and Chemical Engineering, 56, 12–26.CrossRef
go back to reference Navarro-Amoros, M. A., Ruiz-Femenia, R., & Caballero, J. A. (2014). Integration of modular process simulators under the generalized disjunctive programming framework for the structural flowsheet optimization. Computers and Chemical Engineering, 67, 13–25.CrossRef Navarro-Amoros, M. A., Ruiz-Femenia, R., & Caballero, J. A. (2014). Integration of modular process simulators under the generalized disjunctive programming framework for the structural flowsheet optimization. Computers and Chemical Engineering, 67, 13–25.CrossRef
go back to reference Nemhauser, G. L., & Wolsey, L. A. (1988). Integer and combinatorial optimization. New York: John Wiley & Sons, Inc. Nemhauser, G. L., & Wolsey, L. A. (1988). Integer and combinatorial optimization. New York: John Wiley & Sons, Inc.
go back to reference Pirola, C., Galli, F., Manenti, F., Corbetta, M., & Bianchi, C. L. (2014). Simulation and related experimental validation of acetic acid/water distillation using p-xylene as entrainer. Industrial and Engineering Chemistry Research, 53, 18063–18070.CrossRef Pirola, C., Galli, F., Manenti, F., Corbetta, M., & Bianchi, C. L. (2014). Simulation and related experimental validation of acetic acid/water distillation using p-xylene as entrainer. Industrial and Engineering Chemistry Research, 53, 18063–18070.CrossRef
go back to reference Rios, L. M., & Sahinidis, N. V. (2013). Derivative-free optimization: A review of algorithms and comparison of software implementations. Journal of Global Optimization, 56, 1247–1293.MathSciNetCrossRefMATH Rios, L. M., & Sahinidis, N. V. (2013). Derivative-free optimization: A review of algorithms and comparison of software implementations. Journal of Global Optimization, 56, 1247–1293.MathSciNetCrossRefMATH
go back to reference Russell, R. A. (1983). A flexible and reliable method solves single-tower and crude-distillation-column problems. Chemical Engineering, 90, 53–59. Russell, R. A. (1983). A flexible and reliable method solves single-tower and crude-distillation-column problems. Chemical Engineering, 90, 53–59.
go back to reference Sauer, M., Porro, D., Mattanovich, D., & Branduardi, P. (2008). Microbial production of organic acids: expanding the markets. Trends in Biotechnology, 26, 100–108.CrossRef Sauer, M., Porro, D., Mattanovich, D., & Branduardi, P. (2008). Microbial production of organic acids: expanding the markets. Trends in Biotechnology, 26, 100–108.CrossRef
go back to reference Turkay, M., & Grossmann, I. E. (1996). Logic-based MINLP algorithms for the optimal synthesis of process networks. Computers and Chemical Engineering, 20, 959–978.CrossRef Turkay, M., & Grossmann, I. E. (1996). Logic-based MINLP algorithms for the optimal synthesis of process networks. Computers and Chemical Engineering, 20, 959–978.CrossRef
go back to reference Vazquez-Castillo, J. A., Venegas-Sanchez, J. A., Segovia-Hernandez, J. G., Hernandez-Escoto, H., Hernandez, S., Gutierrez-Antonio, C., et al. (2009). Design and optimization, using genetic algorithms, of intensified distillation systems for a class of quaternary mixtures. Computers and Chemical Engineering, 33, 1841–1850.CrossRef Vazquez-Castillo, J. A., Venegas-Sanchez, J. A., Segovia-Hernandez, J. G., Hernandez-Escoto, H., Hernandez, S., Gutierrez-Antonio, C., et al. (2009). Design and optimization, using genetic algorithms, of intensified distillation systems for a class of quaternary mixtures. Computers and Chemical Engineering, 33, 1841–1850.CrossRef
go back to reference Viswanathan, J., & Grossmann, I. E. (1990). A combined penalty-function and outer-approximation method for MINLP optimization. Computers and Chemical Engineering, 14, 769–782.CrossRef Viswanathan, J., & Grossmann, I. E. (1990). A combined penalty-function and outer-approximation method for MINLP optimization. Computers and Chemical Engineering, 14, 769–782.CrossRef
go back to reference Xiu, Z. L., & Zeng, A. P. (2008). Present state and perspective of downstream processing of biologically produced 1, 3-propanediol and 2, 3-butanediol. Applied Microbiology and Biotechnology, 78, 917–926.CrossRef Xiu, Z. L., & Zeng, A. P. (2008). Present state and perspective of downstream processing of biologically produced 1, 3-propanediol and 2, 3-butanediol. Applied Microbiology and Biotechnology, 78, 917–926.CrossRef
go back to reference Yang, Z., Xia, S. Q., Shang, Q. Y., Yan, F. Y., & Ma, P. S. (2014). Isobaric vapor liquid equilibrium for the binary system (ethane-1, 2-diol + butane-1, 2-diol) at (20, 30, and 40) kPa. Journal of Chemical and Engineering Data, 59, 825–831.CrossRef Yang, Z., Xia, S. Q., Shang, Q. Y., Yan, F. Y., & Ma, P. S. (2014). Isobaric vapor liquid equilibrium for the binary system (ethane-1, 2-diol + butane-1, 2-diol) at (20, 30, and 40) kPa. Journal of Chemical and Engineering Data, 59, 825–831.CrossRef
go back to reference Yeomans, H., & Grossmann, I. E. (1999). A systematic modeling framework of superstructure optimization in process synthesis. Computers and Chemical Engineering, 23, 709–731.CrossRef Yeomans, H., & Grossmann, I. E. (1999). A systematic modeling framework of superstructure optimization in process synthesis. Computers and Chemical Engineering, 23, 709–731.CrossRef
go back to reference Zhang, L. H., Wu, W. H., Sun, Y. L., Li, L. Q., Jiang, B., Li, X. G., et al. (2013). Isobaric vapor-liquid equilibria for the binary mixtures composed of ethylene glycol, 1, 2-propylene glycol, 1, 2-butanediol, and 1, 3-butanediol at 10.00 kPa. Journal of Chemical and Engineering Data, 58, 1308–1315.CrossRef Zhang, L. H., Wu, W. H., Sun, Y. L., Li, L. Q., Jiang, B., Li, X. G., et al. (2013). Isobaric vapor-liquid equilibria for the binary mixtures composed of ethylene glycol, 1, 2-propylene glycol, 1, 2-butanediol, and 1, 3-butanediol at 10.00 kPa. Journal of Chemical and Engineering Data, 58, 1308–1315.CrossRef
go back to reference Zhong, Y., Wu, Y. Y., Zhu, J. W., Chen, K., Wu, B., & Ji, L. J. (2014). Thermodynamics in separation for the ternary system 1, 2-ethanediol + 1, 2-propanediol + 2, 3-butanediol. Industrial and Engineering Chemistry Research, 53, 12143–12148.CrossRef Zhong, Y., Wu, Y. Y., Zhu, J. W., Chen, K., Wu, B., & Ji, L. J. (2014). Thermodynamics in separation for the ternary system 1, 2-ethanediol + 1, 2-propanediol + 2, 3-butanediol. Industrial and Engineering Chemistry Research, 53, 12143–12148.CrossRef
Metadata
Title
Systematic Design of Biorefinery Downstream Processes
Authors
Michele Corbetta
Ignacio E. Grossmann
Carlo Pirola
Flavio Manenti
Copyright Year
2017
DOI
https://doi.org/10.1007/978-3-319-42803-1_23