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2019 | OriginalPaper | Chapter

1. Tacticity, Regio and Stereoregularity

Authors : Giovanni Talarico, Claudio De Rosa, Finizia Auriemma

Published in: Polypropylene Handbook

Publisher: Springer International Publishing

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Abstract

This chapter focus on the polypropylene tacticity. The stereoregularity and regioregularity of the processes catalyzed by heterogeneous and homogeneous Ziegler-Natta catalysts are discussed. The amazing variety of molecular architectures available for polypropylene-based materials are summarized together with the catalytic mechanisms for tacticity control. The main techniques applied for the determination of PP tacticity are reported as well as the outstanding development of new catalyst systems able to achieve unprecedented PP microstructures.

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Footnotes
1
In this chapter the nomenclature si, re is used instead of the nomenclature R, S as suggested in Corradini and Guerra [27].
 
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Metadata
Title
Tacticity, Regio and Stereoregularity
Authors
Giovanni Talarico
Claudio De Rosa
Finizia Auriemma
Copyright Year
2019
DOI
https://doi.org/10.1007/978-3-030-12903-3_1

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