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Engineering Ceramic Fiber Nanostructures Through Polymer-Mediated Electrospinning Read chapter Read first chapter

2017 | OriginalPaper | Chapter

11. Tailoring Performance of Polymer Electrolytes Through Formulation Design

Authors : Wei Wang, Dmitry Bedrov, Paschalis Alexandridis

Published in: Polymer-Engineered Nanostructures for Advanced Energy Applications

Publisher: Springer International Publishing

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Abstract

The flammable organic solvent-based electrolytes used in lithium batteries impose serious safety concerns and temperature restrictions. A switch to solid polymer electrolytes can significantly increase chemical/mechanical stability, improve safety, reduce cost, and advance manufacturability, if only issues such as low conductivity and transference, limited operating temperature range, and insufficient mechanical strength can be overcome. To this end, significant research efforts have been directed to understand the mechanism of lithium ion motion in polymer matrices and to modify the chemistry, architecture, and morphology of the poly(ethylene oxide) polymer typically used in polymer electrolytes. Furthermore, the incorporation of nanoparticles into polymer electrolytes has created new opportunities for simultaneous improvement of conductivity and of mechanical properties. The performance of such composite polymer electrolytes can be modulated by the judicious surface chemical modification of the nanoparticles and/or by the addition of organic solvents or ionic liquids. The examples highlighted here point to the importance of formulation design for the improvement of the performance characteristics of multi-component systems such as polymer electrolytes.

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previous chapter Polymer-Derived Carbon/Inorganic Nanohybrids for Electrochemical Energy Storage and Conversion
next chapter Polymer Nanocomposites Dielectrics for Energy Applications
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Metadata
Title
Tailoring Performance of Polymer Electrolytes Through Formulation Design
Authors
Wei Wang
Dmitry Bedrov
Paschalis Alexandridis
Copyright Year
2017
Book
Polymer-Engineered Nanostructures for Advanced Energy Applications

Print ISBN: 978-3-319-57002-0

Electronic ISBN: 978-3-319-57003-7

Copyright Year: 2017

DOI
https://doi.org/10.1007/978-3-319-57003-7_11

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