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Published in:

17-06-2020

The effect of bicarbonate additive on corrosion resistance and microstructure characteristics of the zirconium-based conversion coating on carbon steel

Authors: Linqing Niu, Ruiguang Guo, Qingmin Si, Hongyan Guan

Published in: Journal of Coatings Technology and Research | Issue 5/2020

Abstract

Zirconium-based conversion coating (ZrCC) with modification has been studied for improving the corrosion resistance of carbon steel in this paper. Ammonium bicarbonate (NH₄HCO₃) and sodium bicarbonate (NaHCO₃) were used as additives to investigate their roles on the conversion coating properties. The surface of the modified coating was characterized by scanning electron microscope, X-ray photoelectron spectroscopy, and electron probe micro-analyzer. In addition, the corrosion resistance was studied by Tafel polarization, electrochemical impedance spectroscopy, and the neutral salt spray test (NSST). The results indicated that both NH₄HCO₃ and NaHCO₃ as additives could promote the precipitation of ZrO₂, ZrF₄, K₂ZrF₆, Fe₂O₃, and FeOOH on carbon steel and NaHCO₃ as the additive could make the surface thicker and more uniform. According to the electrochemical and NSST results, NH₄HCO₃- and NaHCO₃-modified zirconium-based conversion coating (ZrCC–NH₄, ZrCC–Na) exhibited more effective corrosion protection property compared with ZrCC, among which ZrCC–Na sample showed the highest corrosion resistance.

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Title: The effect of bicarbonate additive on corrosion resistance and microstructure characteristics of the zirconium-based conversion coating on carbon steel
Authors: Linqing Niu
Ruiguang Guo
Qingmin Si
Hongyan Guan
Publication date: 17-06-2020
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 5/2020
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-020-00349-w

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