1 Introduction
2 Methodology
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the implementation of RWH systems in Europe and reasons why these solutions have become attractive to society (Chap. 3.1),
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meteorological conditions that predispose European countries to effectively use rainwater and the impact of climate change on the RWH potential (Chap. 3.2),
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water supply purposes in which tap water is replaced with rainwater, requirements and limitations on its use (Chap. 3.3),
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characteristics and legislation regulating the rainwater quality (Chap. 3.4),
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rainwater treatment processes (Chap. 3.5).
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Section 3.1: alternative water sources; rainwater purposes; water saving solutions; RWH: advantages, funding programs, implementation, RWH in Europe; RWH systems;
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Section 3.2: atmospheric circulation; climate change; hydrological factors; meteorological conditions; meteorological elements; precipitation patterns; water cycle;
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Section 3.3: rainwater in: cities, households, urban agriculture; rainwater outdoor uses; rainwater potable and non-potable uses; rainwater quality requirements; rainwater usage and limitations; RWH in airports; water consumption structure;
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Is the article consistent with the topic of the work?
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Does the publication cover Europe?
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Do the methods described have practical applications?
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Is the article consistent with current trends?
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Is the data presented in the work up to date?
3 Review of the Current Knowledge State
3.1 RWH Advantages, Implementation Stage, and Funding Programs in Europe
3.2 Meteorological Conditions in Europe – RWH Efficiency Potential
3.3 RWH as an Alternative Water Source, Requirements, and Limitations
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effective dissolution effects (perfect for laundry, washing floors, cleaning),
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no minerals (suitable for window cleaning or car washing – leaving no white patches),
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no aggressive chlorine,
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warmer (suitable for watering plants),
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soft (does not form limescale),
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behaves similarly to distilled water.
3.4 Rainwater Quality
3.4.1 Factors Influencing the Quality of Rainwater and Sources of Pollution
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characteristics of atmospheric phenomena (intensity, duration, wind speed),
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meteorological factors (seasons, duration of no-rainfall period, weather characteristics),
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pollutants concentration in the atmosphere,
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roof material, location, geometry, substances present on the surface (polarity, solubility, Henry’s constant), and maintenance works.
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dust and ash – surrounding dirt and vegetation, volcanic activity;
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pathogenic bacteria – bird and other animal droppings on the roof and attached to dust;
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heavy metals – dust, particularly in urban and industrialized areas, roof materials;
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other inorganic contaminants – seaspray, industrial discharges to air, tank/roof materials;
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mosquito larvae – mosquitos laying eggs in guttering and/or tank.
3.4.2 Research Conducted on the Quality of Rainwater in Europe
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the worst quality was observed for asphalt promenades and parking lots (the highest values of chemical oxygen demand (COD), \({\text{N}\text{O}}_{3}^{-}\), \({\text{H}\text{C}\text{O}}_{3}^{-}\), \({\text{P}\text{O}}_{4}^{3-}\) and \({\text{S}\text{O}}_{4}^{2-});\)
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for concrete surfaces high concentrations of chlorine and iron were found (related to the use of salt in winter and the corrosion of metal parts);
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a higher concentration of organic matter and lower concentration of ammonia was detected in rainwater from ground level than from roofs;
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the microbiological rainwater quality did not differ between surfaces and is comparable to the quality of surface- and groundwater;
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rainwater had similar total suspended solids for different materials (only metal roofs with slightly lower values);
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the highest TOC values were found for a gravel roof (up to 53.6 mgC/L), and the lowest values (< 10 mgC/L) for sheet metal and polycarbonate;
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clay and gravel roof samples demonstrated higher conductivity than metal and polycarbonate roof samples, ranging from 15.4 to 456 µS/cm;
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the highest or significantly higher concentrations of ions (\({\text{S}\text{O}}_{4}^{2-}\), NO2-, NO3-, \({\text{N}\text{H}}_{4}^{+}\), PO43-, Cl-, and total carbonates), in almost all cases were found for water collected from a gravel roof, apart from NH4+, for which a gravel roof showed the lowest concentration and sheet metal and polycarbonate – the highest.
3.5 Rainwater Treatment Technologies
3.5.1 Rainwater Treatment Processes
Method | Function | Additional remarks |
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Chlorination | Inactivation and destruction of bacteria. | • Physicochemical parameters of rainwater (particularly turbidity) determine disinfection effectiveness. |
UV radiation | Interference with microorganisms’ DNA leading to destruction and multiplication inhibition. | |
Membrane filtration | Dissolved solids removal. | • High energy consumption. • Fouling lowers membrane hydraulic performance. • Preliminary water treatment is required. • Specific membrane materials may improve the process: - metal membranes – resistant to pressure, temperature, chemical oxidants, better durability than polymeric membranes, effective in bacteria removal; expensive, - hydrophilic ceramic membranes – high purification effectiveness, good chemical oxidant resistance, antifouling properties; expensive. • Gravity flow membranes may reduce energy usage. |
Pasteurization by solar radiation | Killing bacteria present in water (high effectiveness for E. coli). | • A highly effective method. • Allows to purify a small volume of water. • Increases the effectiveness of chlorination. • Depends on the intensity of solar radiation. • High water turbidity reduces the process effectiveness. • When PET tanks are used, toxic substances may be released. • Exposure to 500 W/m2 sun light for 6 h eliminates almost all coli bacteria (De Kwaadsteniet et al. 2013). |
Filtration through a granular bed | Removal of dissolved solids and solid particles by physical interaction of water with granular bed. It lowers water turbidity, color, and microbes. | • Rainwater filters must meet certain criteria (Abbasi-Garravand and Mulligan 2014): - easy to clean or self-cleaning, - not easily blocked by pollutants, - no leaching of other compounds. • Filter size, shape, and porosity affect process efficiency. |
Activated carbon filtration | Effective removal of inorganic impurities (e.g. chlorine, mercury). | • Granulated activated carbon (GAC) mixed with zeolites or sand may remove over 90% of lead and ammonium nitrogen, 59–85% of turbidity, and > 20% of COD and TOC. |
Slow filtration through the sand bed | Water turbidity decrease and microorganisms removal. | • An economically rational technique. • Not effective in turbidity and microorganisms removal. • Simple structure. • Low operating costs. • Easy scalability for rural and small communities. • May reduce turbidity by 95%. • High turbidity reduces efficiency and shortens filter life. |
Oxidation | Introduction of a strongly oxidizing factor, e.g. free radicals to rainwater. | • Advanced oxidation eliminates water germs (e.g. Klebsiella pneumonia) by 51–100% by direct sun exposure. • Radiation may increase hydroxyl radical generation, which causes cell lysis (Morales-Figueroa et al. 2023). |
Electro- coagulation | Utilizing a chamber and a pair of electrodes to destabilize molecules with an electric field. Removes solutes, suspensions, and emulsions. | • Easy to conduct. • Solar panels can power the process. • Suspended solids can be removed by precipitation or flotation. • The technology allows to control of the volume of the formed sediments. |
Membrane bioreactor | Production of water with good quality. | • High risk of fouling and high aeration costs. • Usage in rainwater purification is limited. |
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microfiltration (MF) – mostly used; removes only big organic compounds and pathogens; demands low transmembrane pressure;
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ultrafiltration (UF) – removes colloids, suspended contaminants, and microorganisms; low separation efficiency of oily substances and heavy metals and fouling are main drawbacks;
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nanofiltration (NF) – removes 99% organic matter and sulfates;
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reverse osmosis (RO) – removes 99.9% of pathogens, dissolved and colloidal contaminants; the installation requires frequent cleaning; fouling reduces filtration effectiveness, raises operating pressure, and shortens membrane life;
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forward osmosis (FO) – mentioned in literature, but rarely used.