Top

Hint

Swipe to navigate through the articles of this issue

Published in:

30-10-2017 | Communication

The role of mechanical action in the process of the thermomechanical isolation of lignin

Authors: A. L. Bychkov, E. M. Podgorbunskikh, E. I. Ryabchikova, O. I. Lomovsky

Published in: Cellulose | Issue 1/2018

Abstract

Transmission electron microscopy of ultrathin sections of reed straw samples subjected to thermomechanical treatment revealed changes in the ultrastructure due to lignin isolation. It is assumed that the lignin in cell walls melts under the influence of high temperature and forms accumulations localized in the depth of the cell walls. Mechanical action exerted on the material presses the lignin with a damaged structure out of the cell walls. Pores 10–20 nm in diameter are observed in cell walls; lignin is localized on the surface of the particles in formations that are approximately 200 nm in size.

next article Novel piezoelectric paper based on SbSI nanowires

To get access to this content you need the following product:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 50.000 Bücher
über 380 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Testen Sie jetzt 15 Tage kostenlos.

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 69.000 Bücher
über 500 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Testen Sie jetzt 15 Tage kostenlos.

inform now

Barbier J, Bataille F, Briand A, Soum S (2011) Method for producing intermediate material intended for ethanol production, and resulting intermediate material US Patent 2011/0236944 A1. Accessed 29 Sept 2011

Bychkov AL, Ryabchikova EI, Korolev KG, Lomovsky OI (2012) Ultrastructural changes of cell walls under intense mechanical treatment of selective plant raw material. Biomass Bioenergy 47:260–267. https://doi.org/10.1016/j.biombioe.2012.09.035 CrossRef

European Parliament and Council Directive 2009/28/EC Promotion of the use of energy from renewable sources. Accessed 23 April 2009

Gaurav N, Sivasankari S, Kiran GS, Ninawe A, Selvin J (2017) Utilization of bioresources for sustainable biofuels: a review. Renew Sustain Energy Rev 73:205–214. https://doi.org/10.1016/j.rser.2017.01.070 CrossRef

Goring DAI (1977) A speculative picture of the delignification process. In: Arthur JC Jr (ed) Cellulose chemistry and technology. American Chemical Society, Washington, pp 273–277 CrossRef

Irvine GM (1985) The significance of the glass transition of lignin in thermomechanical pulping. Wood Sci Technol 19:139–149. https://doi.org/10.1007/BF00353074 CrossRef

Larsen J, Petersen MO, Thirup L, Li HW, Iversen FK (2008) The IBUS process—lignocellulosic bioethanol close to a commercial reality. Chem Eng Technol 31:765–772. https://doi.org/10.1002/ceat.200800048 CrossRef

Li J, Phoenix A, Macleod JM (1997) Diffusion of lignin macromolecules within the fibre walls of kraft pulp. Part I: determination of the diffusion coefficient under alkaline conditions. Can J Chem Eng 75:16–22. https://doi.org/10.1002/cjce.5450750105 CrossRef

Ma J, Zhang X, Zhou X, Xu F (2014) Revealing the changes in topochemical characteristics of poplar cell wall during hydrothermal pretreatment. BioEnergy Res 7:1358–1368. https://doi.org/10.1007/s12155-014-9472-2 CrossRef

Maryandyshev P, Chernov A, Lyubov V, Trouve G, Brillard A, Brilhac J-F (2015) Investigation of thermal degradation of different wood-based biofuels of the northwest region of the Russian Federation. J Therm Anal Calorim 122:963–973. https://doi.org/10.1007/s10973-015-4798-3 CrossRef

Meng X, Ragauskas AJ (2017) Pseudo-lignin formation during dilute acid pretreatment for cellulosic ethanol. Recent Adv Petrochem Sci 1:555551

Myasoedova VV (2012) Environmentally friendly fuel briquettes and pellets based on renewable lignocellulosic raw material and recycling thereof. Polym Sci Ser D 5:213–218. https://doi.org/10.1134/S1995421212030173 CrossRef

Pacesila M, Burcea SG, Colesca SE (2016) Analysis of renewable energies in European Union. Renew Sustain Energy Rev 56:156–170. https://doi.org/10.1016/j.rser.2015.10.152 CrossRef

Roadmap EU-Russia Energy Cooperation until 2050 (2017) March 2013. http://ec.europa.eu/energy/sites/ener/files/documents/2013_03_eu_russia_roadmap_2050_signed.pdf. Accessed 10 March 2017

Sannigrahi P, Kim DH, Jung S, Ragauskas A (2011) Pseudo-lignin and pretreatment chemistry. Energy Environ Sci 4:1306–1310. https://doi.org/10.1039/C0EE00378F CrossRef

Su Y, Zhang P, Su Y (2015) An overview of biofuels policies and industrialization in the major biofuel producing countries. Renew Sustain Energy Rev 50:991–1003. https://doi.org/10.1016/j.rser.2015.04.032 CrossRef

Tynkkynen VP (2014) Russian bioenergy and the EU’s renewable energy goals: perspectives of security. In: Oxenstierna S, Tynkkynen VP (eds) Russian Energy and Security up to 2030. Routledge, London, pp 95–113

Vandenbossche V, Brault J, Vilarem G, Hernandez-Melendez O, Vivaldo-Lima E (2014) A new lignocellulosic biomass deconstruction process combining thermos-mechano chemical and bio-catalytic hydrolysis in a twin-screw extruder. Ind Crops Prod 55:258–266 CrossRef

Zheng J, Rehmann L (2014) Extrusion pretreatment of lignocellulosic biomass: a review. Int J Mol Sci 15:18967–18984. https://doi.org/10.3390/ijms151018967 CrossRefPubMedPubMedCentral

Zhou X, Ding D, Ma J, Ji Z, Zhang X, Xu F (2015) Ultrastructure and topochemistry of plant cell wall by transmission electron microscopy. In: Maaz K (ed) The transmission electron microscope—theory and applications. InTech, Rijeka, pp 285–306. https://doi.org/10.5772/60752 CrossRef

Title: The role of mechanical action in the process of the thermomechanical isolation of lignin
Authors: A. L. Bychkov
E. M. Podgorbunskikh
E. I. Ryabchikova
O. I. Lomovsky
Publication date: 30-10-2017
Publisher: Springer Netherlands
Published in: Cellulose / Issue 1/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1536-y

Springer Professional

Hint

Swipe to navigate through the articles of this issue

Abstract

Please log in to get access to this content

To get access to this content you need the following product:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Other articles of this Issue 1/2018

Hydroxyalkylation of xylan using propylene carbonate: comparison of products from homo- and heterogeneous synthesis by HRMAS NMR and rheology

Modification of cellulose thin films with lysine moieties: a promising approach to achieve antifouling performance

Enhanced swelling and multiple-responsive properties of gelatin/sodium alginate hydrogels by the addition of carboxymethyl cellulose isolated from pineapple peel

Self-healing and injectable polysaccharide hydrogels with tunable mechanical properties

Structure and properties of graphene oxide/cellulose hybrid fibers via divalent metal ions treatment

Cellulose nanofibres as biomaterial for nano-reinforcement of poly[styrene-(ethylene-co-butylene)-styrene] triblock copolymer