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Physics of Metals and Metallography
Published in: Physics of Metals and Metallography 14/2021

18-08-2021 | STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

Thermodynamical Analysis of the Thermal Stability of Zr–Ti–Ni–Cu–Be and Pd–Ni–Cu–P BMGs

Authors: Ailong Zhang, Changsheng Li, Lei Ma, Shenghui Wang, Jingping Zhang

Published in: Physics of Metals and Metallography | Issue 14/2021

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Abstract

The thermal stability of Zr–Ti–Ni–Cu–Be and Pd–Ni–Cu–P multicomponent bulk metallic glasses (BMGs) has been evaluated by their Gibbs free energy of formation, ∆Ga. We found that the tight bonding solute-centred clusters (in which a solute atom is surrounded by many solvent atoms in the first coordination shell with strong solute-solvent interaction), and chemical short-range orders (chemical SRO) have a much more important effect on the thermal stability of multicomponent BMGs, than other clusters and short-range orders. The quasi-linear correlation between crystallization temperature, Tx, and ∆Ga is only valid for multicomponent BMGs with similar chemical SRO, in a narrow composition region. This study could be of importance in understanding the thermal stability and the underlying mechanism of crystallization of multicomponent BMGs.
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Metadata
Title
Thermodynamical Analysis of the Thermal Stability of Zr–Ti–Ni–Cu–Be and Pd–Ni–Cu–P BMGs
Authors
Ailong Zhang
Changsheng Li
Lei Ma
Shenghui Wang
Jingping Zhang
Publication date
18-08-2021
Publisher
Pleiades Publishing
Published in
Physics of Metals and Metallography / Issue 14/2021
Print ISSN: 0031-918X
Electronic ISSN: 1555-6190
DOI
https://doi.org/10.1134/S0031918X21140192

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