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2014 | OriginalPaper | Chapter

24. Topotaxy IN K-MK-AL/SI Spinel-Mullite Reaction Series

Author : Akshoy Kumar Chakraborty

Published in: Phase Transformation of Kaolinite Clay

Publisher: Springer India

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Abstract

Grim (1953) first indicated that high temperature transformation of a material in some cases proceeds in an orderly manner. The structure of the new phase inherits directly from the parent material. It is assumed that oxygen network of the parent material may slightly be modified during heating. Only the cations diffuse and rearrange to develop a new crystal lattice.

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Literature
go back to reference W.F. Bradley, R.E. Grim, High-temperature thermal effects of clay and related materials. Am. Miner. 36(3/4), 182–201 (1951) W.F. Bradley, R.E. Grim, High-temperature thermal effects of clay and related materials. Am. Miner. 36(3/4), 182–201 (1951)
go back to reference G.W. Brindley, M. Nakahira, The kaolinite–mullite reaction series: I, a survey of outstanding problems. J. Am. Ceram. Soc. 42(7), 311–314 (1959a) G.W. Brindley, M. Nakahira, The kaolinite–mullite reaction series: I, a survey of outstanding problems. J. Am. Ceram. Soc. 42(7), 311–314 (1959a)
go back to reference G.W. Brindley, M. Nakahira, The kaolinite–mullite reaction series: II, metakaolin. J. Am. Ceram. Soc. 42(7), 314–318 (1959b) G.W. Brindley, M. Nakahira, The kaolinite–mullite reaction series: II, metakaolin. J. Am. Ceram. Soc. 42(7), 314–318 (1959b)
go back to reference G.W. Brindley, M. Nakahira, The kaolinite–mullite reaction series: III, the high-temperature phases. J. Am. Ceram. Soc. 42(7), 319–324 (1959c) G.W. Brindley, M. Nakahira, The kaolinite–mullite reaction series: III, the high-temperature phases. J. Am. Ceram. Soc. 42(7), 319–324 (1959c)
go back to reference A.K. Chakraborty, D.K. Ghosh, Study of phase transformation of Al2O3–SiO2 gel and kaolinitic clay. Trans. Ind. Ceram. Soc. 37(5), 192–200 (1978a) A.K. Chakraborty, D.K. Ghosh, Study of phase transformation of Al2O3–SiO2 gel and kaolinitic clay. Trans. Ind. Ceram. Soc. 37(5), 192–200 (1978a)
go back to reference A.K. Chakraborty, D.K.Ghosh, Comment on the interpretation of the kaolinite–mullite reaction sequence from infra–red absorption spectra. J. Am. Ceram. Soc. 61(1–2), 90–91 (1978b) (Reply by H.J. Percival. ibid., 61 (1–2) 91 (1978)) A.K. Chakraborty, D.K.Ghosh, Comment on the interpretation of the kaolinite–mullite reaction sequence from infra–red absorption spectra. J. Am. Ceram. Soc. 61(1–2), 90–91 (1978b) (Reply by H.J. Percival. ibid., 61 (1–2) 91 (1978))
go back to reference A.K. Chakraborty, D.K. Ghosh, Re-examination of the kaolinite to mullite reaction series. J. Am. Ceram. Soc. 61(3–4), 170–173 (1978c) A.K. Chakraborty, D.K. Ghosh, Re-examination of the kaolinite to mullite reaction series. J. Am. Ceram. Soc. 61(3–4), 170–173 (1978c)
go back to reference C.Y. Chen, G.S. Lan, W.H. Tuan, Micro structural evolution of mullite during the sintering of kaolinite powder compacts. Ceram. Int. 26(7) 715–720 (2000) C.Y. Chen, G.S. Lan, W.H. Tuan, Micro structural evolution of mullite during the sintering of kaolinite powder compacts. Ceram. Int. 26(7) 715–720 (2000)
go back to reference J.J. Comer, Electron microscope studies of mullite development in fired kaolinite. J. Am. Ceram. Soc. 43(7), 378–384 (1960) J.J. Comer, Electron microscope studies of mullite development in fired kaolinite. J. Am. Ceram. Soc. 43(7), 378–384 (1960)
go back to reference J.J. Comer, New Electron-optical data on the kaolinite–mullite transformation. J. Am. Ceram. Soc. 44(11), 561–563 (1961) J.J. Comer, New Electron-optical data on the kaolinite–mullite transformation. J. Am. Ceram. Soc. 44(11), 561–563 (1961)
go back to reference J.E. Comeforo, R.B. Fischer, W.F. Brandley, Mullitization of kaolinite. J. Am. Ceram. Soc. 31(9), 254–259 (1948) J.E. Comeforo, R.B. Fischer, W.F. Brandley, Mullitization of kaolinite. J. Am. Ceram. Soc. 31(9), 254–259 (1948)
go back to reference D.R. Dasgupta, Topotactic transformations. Ind. J. Earth Sci. 1(1), 60–72 (1974) D.R. Dasgupta, Topotactic transformations. Ind. J. Earth Sci. 1(1), 60–72 (1974)
go back to reference R.E. Grim, Clay Mineralogy. (McGraw-Hill Book Co., New York, 1953) R.E. Grim, Clay Mineralogy. (McGraw-Hill Book Co., New York, 1953)
go back to reference W.D. Johns, High-temperature phase changes in kaolinites. Mineral. Mag. 30(222), 186–198 (1953) W.D. Johns, High-temperature phase changes in kaolinites. Mineral. Mag. 30(222), 186–198 (1953)
go back to reference S. Lee, Y.J. Kim, H-S. Moon, Phase transformation sequence from kaolinite to mullite investigated by an energy-filtering transmission electron microscope. J. Am. Ceram. Soc. 82(10), 2841–2848 (1999) S. Lee, Y.J. Kim, H-S. Moon, Phase transformation sequence from kaolinite to mullite investigated by an energy-filtering transmission electron microscope. J. Am. Ceram. Soc. 82(10), 2841–2848 (1999)
go back to reference S. Lee, Y.J. Kim, H.J. Lee, H-S. Moon, Electron-beam-induced phase transformations from metakaolinite to mullite investigated by EF-TEM and HRTEM. J. Am. Ceram. Soc. 84(9), 2096–2098 (2001) S. Lee, Y.J. Kim, H.J. Lee, H-S. Moon, Electron-beam-induced phase transformations from metakaolinite to mullite investigated by EF-TEM and HRTEM. J. Am. Ceram. Soc. 84(9), 2096–2098 (2001)
go back to reference F.K. Lotgering, J. Inorg. Nucl. Chem. 9, 113 (1959) (in J.D. Bernal; Topotaxi. Schw. Archiv. Jharb., 26, 69) F.K. Lotgering, J. Inorg. Nucl. Chem. 9, 113 (1959) (in J.D. Bernal; Topotaxi. Schw. Archiv. Jharb., 26, 69)
go back to reference J.D.C. McConnell, S.G. Fleet, Electron optical study of the thermal decomposition of kaolinite. Clay Miner. 8, 279–290 (1970)CrossRef J.D.C. McConnell, S.G. Fleet, Electron optical study of the thermal decomposition of kaolinite. Clay Miner. 8, 279–290 (1970)CrossRef
go back to reference C.J. McConville, W.E. Lee, J.H. Sharp, Micro structural evolution in fired kaolinite. Br. Ceram. Trans. 97(4), 162–168 (1998a) C.J. McConville, W.E. Lee, J.H. Sharp, Micro structural evolution in fired kaolinite. Br. Ceram. Trans. 97(4), 162–168 (1998a)
go back to reference C. McConville, W.E. Lee, J.H. Sharp, Comparison of micro structural evolution in kaolinite powders and dense clay bodies. Br. Ceram. Proc. 58, 75–92 (1998b) C. McConville, W.E. Lee, J.H. Sharp, Comparison of micro structural evolution in kaolinite powders and dense clay bodies. Br. Ceram. Proc. 58, 75–92 (1998b)
go back to reference J.S. Moya, C.J. Serna, J.E. Igesias, On the formation of mullite from kandites. J. Mater. Sci. 20, 32–36 (1985) J.S. Moya, C.J. Serna, J.E. Igesias, On the formation of mullite from kandites. J. Mater. Sci. 20, 32–36 (1985)
go back to reference K. Okada, N. Ostuka, J. Ossaka, Characterization of spinel phase formed in the kaolin–mullite thermal sequence. J. Am. Ceram. Soc. 69(10), C-251–C-253 (1986) K. Okada, N. Ostuka, J. Ossaka, Characterization of spinel phase formed in the kaolin–mullite thermal sequence. J. Am. Ceram. Soc. 69(10), C-251–C-253 (1986)
go back to reference F. Onike, G.D. Martin, A.C. Dunham, Time–temperature–transformation curves for kaolinite. Mater. Sci. Forum 7, 73–82 (1986)CrossRef F. Onike, G.D. Martin, A.C. Dunham, Time–temperature–transformation curves for kaolinite. Mater. Sci. Forum 7, 73–82 (1986)CrossRef
go back to reference J.M.A. Rincon, G. Thomas, J.S. Moya, Micro structural study of sintered mullet. J. Am. Ceram. Soc. 69(2), C-29-C-31 (1986) J.M.A. Rincon, G. Thomas, J.S. Moya, Micro structural study of sintered mullet. J. Am. Ceram. Soc. 69(2), C-29-C-31 (1986)
go back to reference K.H. Schuller and H. Kromer, Primary mullite as a pseudomorph after kaolinite. in Proceedings of the International Clay Conference (Mexico City, 1975). ed. by S. W. Bailey, (Applied Publishing, Wilmette, IL, 1976) p. 533–538 K.H. Schuller and H. Kromer, Primary mullite as a pseudomorph after kaolinite. in Proceedings of the International Clay Conference (Mexico City, 1975). ed. by S. W. Bailey, (Applied Publishing, Wilmette, IL, 1976) p. 533–538
go back to reference K. Srikrishna, G. Thomas, R. Martinez, M.P. Corral, S. Aza, J.S. Moya, Kaolinite–mullite reaction series: A TEM study. J. Mater. Sci. 25, 607–612 (1990)CrossRef K. Srikrishna, G. Thomas, R. Martinez, M.P. Corral, S. Aza, J.S. Moya, Kaolinite–mullite reaction series: A TEM study. J. Mater. Sci. 25, 607–612 (1990)CrossRef
go back to reference Y. Tsuzuki, K. Nagasawa, A transitional stage to 980ºC exotherm of kaolin minerals. Clay Sci. 3(5), 87–102 (1969) (Kaolin Minerals) Y. Tsuzuki, K. Nagasawa, A transitional stage to 980ºC exotherm of kaolin minerals. Clay Sci. 3(5), 87–102 (1969) (Kaolin Minerals)
go back to reference S. Udagawa, T. Nakada, M. Nakahira, Molecular structure of allophane as revealed by its thermal transformationin, in Proceedings of the International Clay Conference, ed. by Editor-in-chief Lisa Heller bisa Heller, vol. 1 (Israil University Press, Gerusalem, 1969), p. 151 S. Udagawa, T. Nakada, M. Nakahira, Molecular structure of allophane as revealed by its thermal transformationin, in Proceedings of the International Clay Conference, ed. by Editor-in-chief Lisa Heller bisa Heller, vol. 1 (Israil University Press, Gerusalem, 1969), p. 151
go back to reference K. Von Gehlen, Oriented Formation of Mullite from Al–Si spinel in the transformation series Kaolinite–Mullite. Ber. Deut. Keram. Ges. 39(6), 315–320 (1962) K. Von Gehlen, Oriented Formation of Mullite from Al–Si spinel in the transformation series Kaolinite–Mullite. Ber. Deut. Keram. Ges. 39(6), 315–320 (1962)
go back to reference A. Weiss, K.J. Range, J. Russow, The Al,Si-Spinel Phase from Kaoinite ( Isolation, Chemical Analysis, Orientation and Reactions to Its Low-Temperature Precursors), In Proceedings of the International Clay Conference, Tokyo, 1969, vol. 2 (Israel Universities Press, 1970), pp. 34–37 A. Weiss, K.J. Range, J. Russow, The Al,Si-Spinel Phase from Kaoinite ( Isolation, Chemical Analysis, Orientation and Reactions to Its Low-Temperature Precursors), In Proceedings of the International Clay Conference, Tokyo, 1969, vol. 2 (Israel Universities Press, 1970), pp. 34–37
go back to reference A. Weiss, K.J. Range, J. Russow, The Al,Si-Spinel phase from kaoinite ( Isolation, chemical analysis, orientation and reactions to its low-temperature precursors), In Proceedings of the International Clay Conference, Tokyo, 1969, vol. 2 (Israel Universities Press, 1970), pp. 34–37 A. Weiss, K.J. Range, J. Russow, The Al,Si-Spinel phase from kaoinite ( Isolation, chemical analysis, orientation and reactions to its low-temperature precursors), In Proceedings of the International Clay Conference, Tokyo, 1969, vol. 2 (Israel Universities Press, 1970), pp. 34–37
Metadata
Title
Topotaxy IN K-MK-AL/SI Spinel-Mullite Reaction Series
Author
Akshoy Kumar Chakraborty
Copyright Year
2014
Publisher
Springer India
DOI
https://doi.org/10.1007/978-81-322-1154-9_24

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