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Journal of Materials Science

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11-03-2021 | Polymers & biopolymers

Tuning the polymerization sequence of alkynyl-functionalized benzoxazine: application as precursor for efficient magnetic EMI shielding materials

Authors: Shuai Zhang, Tiange Lan, Dengxun Ren, Xiaobo Liu, Qichao Ran

Published in: Journal of Materials Science | Issue 17/2021

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Abstract

The polymerization sequence of a benzoxazine monomer (A1) bearing alkynyl functional group is tuned by acetylacetone nickel (AN), and the resultant polybenzoxazines are used as precursors to prepare C/Ni composites with high electromagnetic interference shielding effectiveness (EMI SE). It is found that AN effectively promotes the trimerization of the alkynyl groups and forms more benzene rings in the obtained polybenzoxazines [poly(A1/AN)s], whereas polyA1 is a typical phenolic Mannich-type polybenzoxazine. Comparatively, poly(A1/AN)s possess higher cross-linking density, higher modulus at rubbery state and higher char yield at 800 °C. After carbonization, polyA1 heavily swells and deforms and the corresponding carbonaceous material cannot be used as EMI shielding material. Nevertheless, poly(A1/AN)s show good dimensional stability and the resultant magnetic carbonaceous material [C(A1/AN)s] possesses high electrical conductivity above 6 S/m and EMI SE above 25 dB. Thorough investigations reveal that appropriate amount of AN is beneficial to high graphitization degree, but excess AN lowers the graphitization degree. Therefore, the electrical conductivity decreases, while the magnetic hysteresis loss increases with the increasing of AN. Consequently, the EMI SE of C(A1/AN) increases and then decreases with the addition of AN, with C(A1/10AN) offering the highest EMI SE of 50 dB and showing an absorption-dominant mechanism.

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Chen Y, Zhang HB, Yang Y, Wang M, Cao A, Yu ZZ (2016) High-performance epoxy nanocomposites reinforced with three-dimensional carbon nanotube sponge for electromagnetic interference shielding. Adv Func Mater 26(3):447–455

Nariman Y, Xinying S, Xiuyi L, Xi S, Jingjing J, Biao Z, Benzhong T, Mansun C, Jang-Kyo K (2015) Highly aligned graphene/polymer nanocomposites with excellent dielectric properties for high-performance electromagnetic interference shielding. Adv Mater 26(31):5480–5487

Chen Y, Zhang H-B, Wang M, Qian X, Dasari A, Yu Z-Z (2017) Phenolic resin-enhanced three-dimensional graphene aerogels and their epoxy nanocomposites with high mechanical and electromagnetic interference shielding performances. Compos Sci Technol 152:254–262

Song WL, Cao MS, Fan LZ, Lu MM, Li Y, Wang CY, Ju HF (2014) Highly ordered porous carbon/wax composites for effective electromagnetic attenuation and shielding. Carbon 77:130–142

Song WL, Cao MS, Lu MM, Bi S, Wang CY, Liu J (2014) Flexible graphene/polymer composite films in sandwich structures for effective electromagnetic interference shielding. Carbon 66(1):67–76

Zeng Z, Jin H, Chen M, Li W, Zhou L, Zhang Z (2016) Lightweight and anisotropic porous MWCNT/WPU composites for ultrahigh performance electromagnetic interference shielding. Adv Func Mater 26(2):303–310

Liu Z, Gang B, Yi H, Ma Y, Feng D, Li F, Guo T, Chen Y (2007) Reflection and absorption contributions to the electromagnetic interference shielding of single-walled carbon nanotube/polyurethane composites. Carbon 45(4):821–827

Wang L, Qiu H, Liang C, Song P, Han Y, Han Y, Gu J, Kong J, Pan D, Guo Z (2019) Electromagnetic interference shielding MWCNT-Fe3O4@ Ag/epoxy nanocomposites with satisfactory thermal conductivity and high thermal stability. Carbon 141:506–514

Liang J, Wang Y, Huang Y, Ma Y, Liu Z, Cai J, Zhang C, Gao H, Chen Y (2009) Electromagnetic interference shielding of graphene/epoxy composites. Carbon 47(3):922–925

10.

Min Z, Yang H, Chen F, Kuang T (2018) Scale-up production of lightweight high-strength polystyrene/carbonaceous filler composite foams with high-performance electromagnetic interference shielding. Mater Lett 230:157–160

11.

Yang Y, Gupta MC, Dudley KL, Lawrence RW (2005) Novel carbon nanotube-polystyrene foam composites for electromagnetic interference shielding. Nano Lett 5(11):2131–2134

12.

Eswaraiah V, Sankaranarayanan V, Ramaprabhu S (2011) Functionalized graphene–PVDF foam composites for EMI shielding. Macromol Mater Eng 296(10):894–898

13.

Ma X, Shen B, Zhang L, Liu Y, Zhai W, Zheng W (2018) Porous superhydrophobic polymer/carbon composites for lightweight and self-cleaning EMI shielding application. Compos Sci Technol 158:86–93

14.

Wang G, Zhao G, Wang S, Zhang L, Park CB (2018) Injection-molded microcellular PLA/graphite nanocomposites with dramatically enhanced mechanical and electrical properties for ultra-efficient EMI shielding applications. J Mater Chem C 6(25):6847–6859

15.

Shi Y-D, Yu H-O, Li J, Tan Y-J, Chen Y-F, Wang M, Wu H, Guo S (2018) Low magnetic field-induced alignment of nickel particles in segregated poly(l-lactide)/poly(ε-caprolactone)/multi-walled carbon nanotube nanocomposites: towards remarkable and tunable conductive anisotropy. Chem Eng J 347:472–482

16.

Cheng KB, Ramakrishna S, Lee KC (2000) Electromagnetic shielding effectiveness of copper/glass fiber knitted fabric reinforced polypropylene composites. Compos A 31(10):1039–1045

17.

Tzeng SS, Chang FY (2001) EMI shielding effectiveness of metal-coated carbon fiber-reinforced ABS composites. Mater Sci Eng A 302(2):258–267

18.

Kumaran R, Kumar SD, Balasubramanian N, Alagar M, Subramanian V, Dinakaran K (2016) Enhanced electromagnetic interference shielding in a Au–MWCNT composite nanostructure dispersed PVDF thin films. J Phys Chem C 120(25):13771–13778

19.

Lu Y, Jiang S, Huang Y (2010) Ultrasonic-assisted electroless deposition of Ag on PET fabric with low silver content for EMI shielding. Surf Coat Technol 204(16):2829–2833

20.

Wang C, Zhao M, Li J, Yu J, Sun S, Ge S, Guo X, Xie F, Jiang B, Wujcik EK (2017) Silver nanoparticles/graphene oxide decorated carbon fiber synergistic reinforcement in epoxy-based composites. Polymer 131:263–271

21.

Su CI, Chern JT (2004) Effect of stainless steel-containing fabrics on electromagnetic shielding effectiveness. Text Res J 74(74):51–54

22.

Dong M, Li Q, Liu H, Liu C, Wujcik EK, Shao Q, Ding T, Mai X, Shen C, Guo Z (2018) Thermoplastic polyurethane-carbon black nanocomposite coating: fabrication and solid particle erosion resistance. Polymer 158:381–390

23.

Plengudomkit R, Okhawilai M, Rimdusit S (2014) Highly filled graphene-benzoxazine composites as bipolar plates in fuel cell applications. Polym Compos 37(6):313–325

24.

Guan X, Zheng G, Dai K, Liu C, Yan X, Shen C, Guo Z (2016) Carbon nanotubes-adsorbed electrospun PA66 nanofiber bundles with improved conductivity and robust flexibility. ACS Appl Mater Interfaces 8(22):14150–14159

25.

Sun K, Xie P, Wang Z, Su T, Shao Q, Ryu J, Zhang X, Guo J, Shankar A, Li J (2017) Flexible polydimethylsiloxane/multi-walled carbon nanotubes membranous metacomposites with negative permittivity. Polymer 125:50–57

26.

Saiev S, Bonnaud L, Dumas L, Zhang T, Dubois P, Beljonne D, Lazzaroni R (2018) Do carbon nanotubes improve the thermomechanical properties of benzoxazine thermosets? ACS Appl Mater Interfaces 10(31):26669–26677

27.

Chen Z, Xu C, Ma C, Ren W, Cheng HM (2013) Lightweight and flexible graphene foam composites for high-performance electromagnetic interference shielding. Adv Mater 25(9):1296–1300

28.

Shen B, Zhai W, Zheng W (2014) Ultrathin flexible graphene film: an excellent thermal conducting material with efficient EMI shielding. Adv Func Mater 24(28):4542–4548

29.

Wang Z, Wei R, Gu J, Liu H, Liu C, Luo C, Kong J, Shao Q, Wang N, Guo Z (2018) Ultralight, highly compressible and fire-retardant graphene aerogel with self-adjustable electromagnetic wave absorption. Carbon 139:1126–1135

30.

Zhang S, Ran Q, Fu Q, Gu Y (2019) Carbonized polybenzoxazine for electromagnetic interference shielding. Mater Chem Phys. https://doi.org/10.1016/j.matchemphys.2019.121806CrossRef

31.

Lee YJ, Huang JM, Kuo SW, Chen JK, Chang FC (2005) Synthesis and characterizations of a vinyl-terminated benzoxazine monomer and its blending with polyhedral oligomeric silsesquioxane (POSS). Polymer 46(7):2320–2330

32.

Chernykh A, Agag T, Ishida H (2009) Novel benzoxazine monomer containing diacetylene linkage: an approach to benzoxazine thermosets with low polymerization temperature without added initiators or catalysts. Polymer 50(14):3153–3157

33.

Cao GP, Chen WJ, Liu XB (2008) Synthesis and thermal properties of the thermosetting resin based on cyano functionalized benzoxazine. Polym Degrad Stab 93(3):739–744

34.

Kan Z, Ishida H (2015) Thermally stable polybenzoxazines via ortho -norbornene functional benzoxazine monomers: unique advantages in monomer synthesis, processing and polymer properties. Polymer 66:240–248

35.

Liu YL, Chou CI (2010) High performance benzoxazine monomers and polymers containing furan groups. J Polym Sci Part A Polym Chem 43(21):5267–5282

36.

Zhang S, Yan Y, Li X, Fan H, Ran Q, Fu Q, Gu Y (2018) A novel ultra low-k nanocomposites of benzoxazinyl modified polyhedral oligomeric silsesquioxane and cyanate ester. Eur Polymer J 103:124–132

37.

Wu Y-C, Kuo S-W (2010) Synthesis and characterization of polyhedral oligomeric silsesquioxane (POSS) with multifunctional benzoxazine groups through click chemistry. Polymer 51(17):3948–3955

38.

Tsai C-C, Gan Z, Kuo S-W (2018) Using benzoxazine chemistry and bio-based triblock copolymer to prepare functional porous polypeptide capable of efficient dye adsorption. Polym Chem 9(26):3684–3693

39.

Shen X, Dai J, Liu Y, Liu X, Zhu J (2017) Synthesis of high performance polybenzoxazine networks from bio-based furfurylamine: furan vs benzene ring. Polymer 122:258–269

40.

Zhang K, Yu X (2018) Catalyst-free and low-temperature terpolymerization in a single-component benzoxazine resin containing both norbornene and acetylene functionalities. Macromolecules 51(16):6524–6533

41.

Zhang S, Li X, Fan H, Fu Q, Gu Y (2019) Epoxy nanocomposites: Improved thermal and dielectric properties by benzoxazinyl modified polyhedral oligomeric silsesquioxane. Mater Chem Phys 223:260–267

42.

Wan L, Wang J, Xie L, Sun Y, Li K (2014) Nitrogen-enriched hierarchically porous carbons prepared from polybenzoxazine for high-performance supercapacitors. ACS Appl Mater Interfaces 6(17):15583–15596

43.

Liu W, Jianlong W, Chong F, Yahui S, Kaixi L (2015) Synthesis of polybenzoxazine based nitrogen-rich porous carbons for carbon dioxide capture. Nanoscale 7(15):6534–6544

44.

Zhang M, Chen M, Reddeppa N, Xu D, Jing Q, Zha R (2018) Nitrogen self-doped carbon aerogels derived from trifunctional benzoxazine monomers as ultralight supercapacitor electrodes. Nanoscale 10(14):6549–6557

45.

Huang CY, Wu CC (2000) The EMI shielding effectiveness of PC/ABS/nickel-coated-carbon-fibre composites. Eur Polymer J 36(12):2729–2737

46.

Huang CY, Mo WW, Roan ML (2004) The influence of heat treatment on electroless-nickel coated fibre (ENCF) on the mechanical properties and EMI shielding of ENCF reinforced ABS polymeric composites. Surf Coat Technol 184(2):123–132

47.

Zhang S, Wang Y, Ran Q, Fu Q, Gu Y (2019) Electromagnetic interference shielding property of polybenzoxazine/graphene/nickel composites. React Funct Polym 143:104324

48.

Xu Y, Ran Q, Li C, Zhu R, Gu Y (2015) Study on the catalytic prepolymerization of an acetylene-functional benzoxazine and the thermal degradation of its cured product. RSC Adv 5(100):82429–82437

49.

Xu Y, Dai J, Ran Q, Gu Y (2017) Greatly improved thermal properties of polybenzoxazine via modification by acetylene/aldehyde groups. Polymer 123:232–239

50.

Dogan Demir K, Kiskan B, Yagci Y (2011) Thermally curable acetylene-containing main-chain benzoxazine polymers via sonogashira coupling reaction. Macromolecules 44(7):1801–1807

51.

Shacklette LW, Colaneri NF (1991) EMI shielding measurements of conductive polymer blends, IEEE Instrumentation and Measurement Technology Conference

52.

Treloar RGL (1958) The physics of rubber elasticity, 2nd edn. The Clarendon Press, Oxford

53.

Ishida H, Allen DJ (1996) Mechanical characterization of copolymers based on benzoxazine and epoxy. Polymer 37(20):4487–4495

54.

Ishida H, Sanders DP (2000) Improved thermal and mechanical properties of polybenzoxazines based on alkyl-substituted aromatic amines. J Polym Sci Part B Polym Phys 38(24):3289–3301

55.

Balahmar N, Lowbridge AM, Mokaya R (2016) Templating of carbon in zeolites under pressure: synthesis of pelletized zeolite templated carbons with improved porosity and packing density for superior gas (CO₂ and H₂) uptake properties. J Mater Chem 4(37):14254–14266

56.

Zhan Y, Wang J, Zhang K, Li Y, Meng Y, Yan N, Wei W, Peng F, Xia H (2018) Fabrication of a flexible electromagnetic interference shielding Fe3O4@ reduced graphene oxide/natural rubber composite with segregated network. Chem Eng J 344:184–193

57.

Verma M, Singh AP, Sambyal P, Singh BP, Dhawan SK, Choudhary V (2015) Barium ferrite decorated reduced graphene oxide nanocomposite for effective electromagnetic interference shielding. Phys Chem Chem Phys 17(3):1610–1618

Title: Tuning the polymerization sequence of alkynyl-functionalized benzoxazine: application as precursor for efficient magnetic EMI shielding materials
Authors: Shuai Zhang
Tiange Lan
Dengxun Ren
Xiaobo Liu
Qichao Ran
Publication date: 11-03-2021
Publisher: Springer US
Published in: Journal of Materials Science / Issue 17/2021
Print ISSN: 0022-2461
Electronic ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-021-05977-0

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