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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 24/2019

13-11-2019

Ultra-low remanence and weak magnetic agglomeration of superparamagnetic magnetite nanoparticles caused by high magnetic moment Tb3+ doping

Authors: Pengyu Gong, Qingyun Chen, Kaimin Shih, Changzhong Liao, Lielin Wang, Hua Xie, Sihao Deng

Published in: Journal of Materials Science: Materials in Electronics | Issue 24/2019

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Abstract

The structure and magnetic properties of the magnetite can be substantial corrected by incorporating foreign cations. In this work, Tb3+ was successfully incorporated into magnetite and superparamagnetic magnetite nanoparticles were obtained, using solvothermal method. The doping of Tb3+ greatly reduces the Mr and Hc values of the magnetite. Due to the doping of high magnetic moment Tb3+, the original magnetic moment of the magnetite is destroyed and magnetic domain are decomposed, resulting in a significant reduction in remanence and magnetic agglomeration. The remarkable effect of Tb3+ doping degaussing will provide new prospects for the application of magnetite materials in the superparamagnetic direction.
previous article ZnO thick films for NO2 detection: effect of different nanostructures on the sensors’ performances
next article Effect of the Eu3+ (x = 0, 1, 2 and 3 mol%) doped Zn2−xTiO4 and Zn2Ti1−xO4 obtained by complex polymerization method: photoluminescent and photocatalytic properties

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Literature
1.
E.J. Verwey, P.W. Haayman, F.C. Romeijn, Physical properties and cation arrangement of oxides with spinel structures II. Electronic conductivity. J. Chem. Phys. 15, 181–187 (1947)
2.
Q.A. Pankhurst, J. Connolly, S.K. Jones, Applications of magnetic nanoparticles in biomedicine. J. Phys. D 36, R167 (2003)
3.
Y.P. Fu, Electrical conductivity and magnetic properties of Li0.5Fe2.5-xCrxO4 ferrite. Mater. Chem. Phys. 115, 334–338 (2009)
4.
R. Hergt, S. Dutz, R. Müller, Magnetic particle hyperthermia: nanoparticle magnetism and materials development for cancer therapy. J. Phys.-Condes. Matter 18, S2919 (2006)
5.
M. Mahmoudi, S. Sant, B. Wang, Superparamagnetic iron oxide nanoparticles (SPIONs): development, surface modification and applications in chemotherapy. Adv. Drug Deliv. Rev. 63, 24–46 (2011)
6.
A.F. Ngomsik, A. Bee, M. Draye, Magnetic nano-and microparticles for metal removal and environmental applications: a review. C. R. Chim. 8, 963–970 (2005)
7.
S. Rajput, C.U. Pittman, D. Mohan, Magnetic magnetite (Fe3O4) nanoparticle synthesis and applications for lead (Pb2+) and chromium (Cr6+) removal from water. J. Colloid Interface Sci. 468, 334–346 (2015)
8.
L. Wang, Z. Yang, J. Gao, A biocompatible method of decorporation: bisphosphonate-modified magnetite nanoparticles to remove uranyl ions from blood. J. Am. Chem. Soc. 128, 13358–13359 (2006)
9.
M. Liong, J. Lu, M. Kovochich, Multifunctional inorganic nanoparticles for imaging, targeting, and drug delivery. ACS Nano 2, 889–896 (2008)
10.
O.E. Polozhentsev, S.P. Kubrin, V.V. Butova, Structure and magnetic properties of pure and samarium doped magnetite nanoparticles. J. Struct. Chem. 57, 1459–1468 (2016)
11.
A. Lv, C. Hu, Y. Nie, Catalytic ozonation of toxic pollutants over magnetic cobalt-doped Fe3O4 suspensions. Appl. Catal. B 117, 246–252 (2012)
12.
T.A. Lastovina, A.P. Budnyk, E.A. Kudryavtsev, Solvothermal synthesis of Sm3+-doped Fe3O4 nanoparticles. Mater. Sci. Eng., C 80, 110–116 (2017)
13.
J. Choi, J.C. Kim, Y.B. Lee, Fabrication of silica-coated magnetic nanoparticles with highly photoluminescent lanthanide probes. Chem. Commun. 16, 1644–1646 (2007)
14.
G.K. Das, Y. Zhang, L. D’Silva, Single-phase Dy2O3: Tb3+ nanocrystals as dual-modal contrast agent for high field magnetic resonance and optical imaging. Chem. Mater. 23, 2439–2446 (2011)
15.
B.P. Jacob, S. Thankachan, S. Xavier, Effect of Tb3+ substitution on structural, electrical and magnetic properties of sol–gel synthesized nanocrystalline nickel ferrite. J. Alloys Compd. 578, 314–319 (2013)
16.
J. Guo, C. Cui, W. Yang, Microstructures and magnetic properties of Tb-Fe-Co magnetic nanowire arrays prepared by electrochemical deposition. Superlattices Microstruct. 128, 298–306 (2019)
17.
K.P. Rice, S.E. Russek, R.H. Geiss, Temperature-dependent structure of Tb-doped magnetite nanoparticles. Appl. Phys. Lett. 106, 062409 (2015)
18.
H. Peng, G. Liu, X. Dong, Magnetic, luminescent and core-shell structured Fe3O4@YF3: Ce3+, Tb3+ bifunctional nanocomposites. Powder Technol. 215, 242–246 (2012)
19.
Z. Qi, T.P. Joshi, R. Liu, Synthesis of Ce(III)-doped Fe3O4 magnetic particles for efficient removal of antimony from aqueous solution. J. Hazard. Mater. 329, 193–204 (2017)
20.
M. Abareshi, E.K. Goharshadi, S.M. Zebarjad, Fabrication, characterization and measurement of thermal conductivity of Fe3O4 nanofluids. J. Magn. Magn. Mater. 322, 3895–3901 (2010)
21.
J.F.W. Bowles, The iron oxides: structure, properties reactions occurrence and uses. Mineral. Mag. 61, 740–741 (1997)
22.
G. Huang, H. Li, J. Chen, Tunable T1 and T2 contrast abilities of manganese-engineered iron oxide nanoparticles through size control. Nanoscale 6, 10404–10412 (2014)
23.
J. Liu, Y. Bin, M. Matsuo, Magnetic behavior of Zn-doped Fe3O4 nanoparticles estimated in terms of crystal domain size. J. Phys. Chem. C 116, 134–143 (2011)
24.
D. Li, X. Zhang, J. Yao, Stimuli-responsive polymer hydrogels as a new class of draw agent for forward osmosis desalination. Chem. Commun. 47, 1710–1712 (2011)
25.
W. Zhao, Y. Wu, J. Xu, Retraction: effect of ethylene glycol on hydrothermal formation of calcium sulfate hemihydrate whiskers with high aspect ratios. RSC Adv. 6, 99639 (2016)
26.
N. Agasti, N.K. Kaushik, One pot synthesis of crystalline silver nanoparticles. Am. J. Nanomater. 2, 4–7 (2014)
27.
J. Mohapatra, A. Mitra, D. Bahadur, Surface controlled synthesis of MFe2O4 (M = Mn, Fe Co, Ni and Zn) nanoparticles and their magnetic characteristics. CrystEngComm 15, 524–532 (2013)
28.
K.N. Harish, H.S.B. Naik, P.N.P. Kumar, Optical and photocatalytic properties of CdFe2O4 nanocatalysts: potential application in water treatment under solar light irradiation. Arch. Appl. Sci. Res. 5, 42–51 (2013)
29.
C.A. Quinto, P. Mohindra, S. Tong, Multifunctional superparamagnetic iron oxide nanoparticles for combined chemotherapy and hyperthermia cancer treatment. Nanoscale 7, 12728–12736 (2015)
30.
I. Karimzadeh, M. Aghazadeh, T. Doroudi, Amino acid coated superparamagnetic iron oxide nanoparticles for biomedical applications through a novel efficient preparation method. J. Clust. Sci. 28, 1259–1271 (2017)
31.
S. Anjum, R. Tufail, H. Saleem, Investigation of stability and magnetic properties of Ni-and Co-doped iron oxide nano-particles. J. Supercond. Nov. Magn. 30, 2291–2301 (2017)
32.
W. Huan, G. Ji, C. Cheng, Preparation, characterization of high-luminescent and magnetic Eu3+, Dy3+ doped superparamagnetic nano-Fe3O4. J. Nanosci. Nanotechnol. 15, 1780–1788 (2015)
33.
K. Haneda, A.H. Morrish, Noncollinear magnetic structure of CoFe2O4 small particles. J. Appl. Phys. 63, 4258–4260 (1988)
34.
M.X. Xu, Study of magnetic properties in ZnxFe3-xO4 composite magnetic fluids. Acta Phys.-Chim. Sin. 15, 619–623 (1999)
35.
E. Talik, Magnetic and transport properties of the R3Ni system (R = Y, Gd, Tb, Dy, Ho, Er). Phys. B 193, 213–220 (1994)
36.
L. Guo, X. Shen, X. Meng, Effect of Sm3+ ions doping on structure and magnetic properties of nanocrystalline NiFe2O4 fibers. J. Alloys Compd. 490, 301–306 (2010)
37.
Q. Song, Z.J. Zhang, Shape control and associated magnetic properties of spinel cobalt ferrite nanocrystals. J. Am. Chem. Soc. 126, 6164–6168 (2004)
38.
J. C. Bonner, R. C. Ohandley, J. F. Janak, Annual Conference on Magnetism and Magnetic Materials, 26th, Dallas, Tex. November 11-14, 1980, Proceedings. J. Appl. Phys. 52, (1981)
39.
E.C. Stoner, E.P. Wohlfarth, A mechanism of magnetic hysteresis in heterogeneous alloys. Philos. Trans. R. Soc. A 240, 599–642 (1948)
40.
X. Zhang, Y. Niu, X. Meng, Structural evolution and characteristics of the phase transformations between α-Fe2O3, Fe3O4 and γ-Fe2O3 nanoparticles under reducing and oxidizing atmospheres. CrystEngComm 15, 8166–8172 (2013)
41.
B. Zhai, Q. Ma, Y.M. Huang, Instability of the characteristic emissions of dopant Tb in ZnO hexagonal pyramids. J. Electron. Mater. 46, 947–954 (2017)
42.
Y. Zhang, G.K. Das, R. Xu, Tb-doped iron oxide: bifunctional fluorescent and magnetic nanocrystals. J. Mater. Chem. 19, 3696–3703 (2009)
Metadata
Title
Ultra-low remanence and weak magnetic agglomeration of superparamagnetic magnetite nanoparticles caused by high magnetic moment Tb3+ doping
Authors
Pengyu Gong
Qingyun Chen
Kaimin Shih
Changzhong Liao
Lielin Wang
Hua Xie
Sihao Deng
Publication date
13-11-2019
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 24/2019
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-02465-9

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